Organic Letters,
Journal Year:
2020,
Volume and Issue:
23(1), P. 195 - 201
Published: Dec. 23, 2020
Herein,
a
novel
method
for
the
gram-scale
synthesis
of
(E)-quinoxalinone
oximes
through
multicomponent
reaction
under
mild
conditions
is
described.
Such
transformation
was
performed
transition-metal-free
conditions,
affording
(E)-oximes
in
moderate-to-good
yield
recrystallization.
Our
methodology
demonstrates
successful
combination
Mannich-type
and
radical
coupling,
providing
green
practical
approach
potentially
bioactive
quinoxalinone-containing
molecules.
Chemical Reviews,
Journal Year:
2021,
Volume and Issue:
122(2), P. 1925 - 2016
Published: Sept. 29, 2021
The
fields
of
C–H
functionalization
and
photoredox
catalysis
have
garnered
enormous
interest
utility
in
the
past
several
decades.
Many
different
scientific
disciplines
relied
on
strategies
including
natural
product
synthesis,
drug
discovery,
radiolabeling,
bioconjugation,
materials,
fine
chemical
synthesis.
In
this
Review,
we
highlight
use
reactions.
We
separate
review
into
inorganic/organometallic
catalysts
organic-based
catalytic
systems.
Further
subdivision
by
reaction
class─either
sp2
or
sp3
functionalization─lends
perspective
tactical
for
these
methods
synthetic
applications.
Organic Letters,
Journal Year:
2021,
Volume and Issue:
23(8), P. 2976 - 2980
Published: March 29, 2021
A
general
and
metal-free
visible-light-induced
decarboxylative
arylation
procedure
at
room
temperature
was
described
for
the
construction
of
acylated
heterocyclic
derivatives,
such
as
benzimidazo/indolo[2,1-a]isoquinolin-6(5H)-ones,
aroylazaspiro[4.5]trienones,
thioflavones,
so
on.
This
practical
conducted
by
using
2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile
(4CzIPN)
a
photocatalyst
under
mild
conditions,
which
avoided
use
an
additional
base,
traditional
heating,
metal
reagents.
Green Chemistry,
Journal Year:
2020,
Volume and Issue:
23(1), P. 374 - 378
Published: Oct. 23, 2020
Aryl
radicals
were
generated
for
the
first
time
from
aryl
acyl
peroxides
in
ethyl
acetate
under
ambient
conditions
and
visible-light
illumination
absence
of
any
additive,
metal
catalyst,
or
external
photosensitizer.
Green Chemistry,
Journal Year:
2020,
Volume and Issue:
23(1), P. 496 - 500
Published: Nov. 26, 2020
A
practical
method
for
the
switchable
synthesis
of
sulfoxides
and
sulfones
through
visible-light-initiated
CF3SO2Na/2-butoxyethyl
ether
synergistic
catalyzed
oxygenation
sulfides
was
developed.
