Missing‐linker Defects in Covalent Organic Framework Membranes for Efficient CO2 Separation DOI
Zheyuan Guo, Hong Wu, Yu Chen

et al.

Angewandte Chemie International Edition, Journal Year: 2022, Volume and Issue: 61(41)

Published: Aug. 18, 2022

Covalent organic framework (COF) membranes with tunable ordered channels and free groups hold great promise in molecular separations owing to the synergy of physical chemical microenvironments. Herein, we develop a defect engineering strategy fabricate COF for efficient CO2 separation. Abundant amino are situ generated on nanosheets arising from missing-linker defects during reactive assembly amine monomer mixed aldehyde monomers. The assembled membranes. Amino groups, as facilitated transport carriers, along endow membrane high permeances exceeding 300 GPU excellent separation selectivity 80 /N2 , 54 /CH4 gas under humidified state. Our offers facile approach generating functional other diverse separations.

Language: Английский

Progress of CCUS technology in the iron and steel industry and the suggestion of the integrated application schemes for China DOI
Yang Yang, Wenqing Xu, Yan Wang

et al.

Chemical Engineering Journal, Journal Year: 2022, Volume and Issue: 450, P. 138438 - 138438

Published: Aug. 3, 2022

Language: Английский

Citations

98
Photothermal functional material and structure for photothermal catalytic CO2 reduction: Recent advance, application and prospect DOI
Ziqi Wang, Zhongqing Yang, Zukhra C. Kadirova

et al.

Coordination Chemistry Reviews, Journal Year: 2022, Volume and Issue: 473, P. 214794 - 214794

Published: Sept. 13, 2022

Language: Английский

Citations

96
Binuclear Cu complex catalysis enabling Li–CO2 battery with a high discharge voltage above 3.0 V DOI Creative Commons
Xinyi Sun, Xiaowei Mu, Wei Zheng

et al.

Nature Communications, Journal Year: 2023, Volume and Issue: 14(1)

Published: Feb. 1, 2023

Li-CO2 batteries possess exceptional advantages in using greenhouse gases to provide electrical energy. However, these following Li2CO3-product route usually deliver low output voltage (<2.5 V) and energy efficiency. Besides, Li2CO3-related parasitic reactions can further degrade battery performance. Herein, we introduce a soluble binuclear copper(I) complex as the liquid catalyst achieve Li2C2O4 products batteries. The exhibits high electromotive up 3.38 V, an increased of 3.04 enlarged discharge capacity 5846 mAh g-1. And it shows robust cyclability over 400 cycles with additional help Ru catalyst. We reveal that easily capture CO2 form bridged Cu(II)-oxalate adduct. Subsequently reduction adduct occurs during discharge. This work innovatively increases higher than 3.0 paving promising avenue for design regulation conversion reactions.

Language: Английский

Citations

96
Electrocatalytic Refinery of Biomass-Based 5-Hydroxymethylfurfural to Fine Chemicals DOI
Yingjie Gao, Lei Ge, Haolan Xu

et al.

ACS Catalysis, Journal Year: 2023, Volume and Issue: 13(17), P. 11204 - 11231

Published: Aug. 10, 2023

Because of depleting fossil-fuel reserves, together with the impacts climate change, alternative eco-friendly production high-value chemicals and renewables is needed. Biomass feedstock particular research interest. 5-Hydroxymethylfural (HMF) a versatile precursor that can be converted to via electrolysis. Reduction generates precursors for ethers, ketones, polyurethanes, polyesters, polyethers, e.g., 2,5-dihydroxymethylfuran (DHMF) 2,5-dimethyletrahydrofuran (DHMTHF), high-energy-density premium biofuels, 2,5-dimethylfuran (DMF), 2,5-hexanedione (HD) 5,5′-bis(hydroxymethyl) hydrofuroin (BHH). Oxidation HMF yields valuable chemical products, including 2,5-diformyl furan (DFF), 5-hydroxymethyl-2-furan carboxylic acid (HMFCA), 2,5-furan dicarboxylic (FDCA), maleic (MA) are precursors/intermediates polymer industry chemical/pharmaceutical production(s). In this review, we 1) report comparative summary electrocatalytic refinery HMF, both electro-oxidation electroreduction pathways, 2) appraise advances in reaction (HRR) (HOR), 3) assess pathways mechanisms, 4) establish design electrocatalysts selection metal materials, geometric structure, electronic structural modifications boost HRR HOR activity selectivity, 5) evaluate impact parameters pH, electrolyte composition, applied potential, initial substrate concentration on HOR, 6) provide prospect future electrochemical refinement HMF. We conclude an improved understanding conditions needed practically selectivity Findings will benefit electrochemistry chemistry generating fine and, therefore, interest researchers manufacturers.

Language: Английский

Citations

94
Missing‐linker Defects in Covalent Organic Framework Membranes for Efficient CO2 Separation DOI
Zheyuan Guo, Hong Wu, Yu Chen

et al.

Angewandte Chemie International Edition, Journal Year: 2022, Volume and Issue: 61(41)

Published: Aug. 18, 2022

Covalent organic framework (COF) membranes with tunable ordered channels and free groups hold great promise in molecular separations owing to the synergy of physical chemical microenvironments. Herein, we develop a defect engineering strategy fabricate COF for efficient CO2 separation. Abundant amino are situ generated on nanosheets arising from missing-linker defects during reactive assembly amine monomer mixed aldehyde monomers. The assembled membranes. Amino groups, as facilitated transport carriers, along endow membrane high permeances exceeding 300 GPU excellent separation selectivity 80 /N2 , 54 /CH4 gas under humidified state. Our offers facile approach generating functional other diverse separations.

Language: Английский

Citations

91