Angewandte Chemie International Edition,
Journal Year:
2022,
Volume and Issue:
61(40)
Published: Aug. 16, 2022
Low
mass-transfer
efficiency
and
reaction-driving
force
make
it
difficult
to
realize
thorough
purification
in
traditional
low-concentration
pollutant
treatments.
Herein,
we
propose
an
"adsorption/catalysis
situ"
perylene
based
bifunctional
micelle
for
efficient,
accurate
rapid
adsorption
catalytic
degradation
of
bisphenol
A
(BPA).
They
show
super-fast
(within
10
s),
high
capacity
(448
mg
g-1
)
selectivity
BPA
adsorption,
due
π-π,
hydrophobic
interactions
hydrogen
bonding.
The
improves
by
up
8
times
after
forming
micelles
compared
with
simple
nanorods,
which
is
primarily
the
superior
from
adsorption.
Moreover,
self-assembly
can
optimize
stacking
moieties
facilitate
charge
transfer
micelle,
regular
π-π
inside
units
enhances
response
visible
light,
resulting
good
cycling
stability.
Beilstein Journal of Organic Chemistry,
Journal Year:
2021,
Volume and Issue:
17, P. 589 - 621
Published: March 2, 2021
Metal-catalysed
depolymerisation
of
plastics
to
reusable
building
blocks,
including
monomers,
oligomers
or
added-value
chemicals,
is
an
attractive
tool
for
the
recycling
and
valorisation
these
materials.
The
present
manuscript
shortly
reviews
most
significant
contributions
that
appeared
in
field
within
period
January
2010–January
2020
describing
selective
methods
plastics.
Achievements
are
broken
down
according
plastic
material,
namely
polyolefins,
polyesters,
polycarbonates
polyamides.
focus
on
recent
advancements
targeting
sustainable
environmentally
friendly
processes.
Biocatalytic
unselective
processes,
acid–base
treatments
as
well
production
fuels
not
discussed,
nor
further
upgrade
products.
Angewandte Chemie International Edition,
Journal Year:
2022,
Volume and Issue:
61(40)
Published: Aug. 16, 2022
Low
mass-transfer
efficiency
and
reaction-driving
force
make
it
difficult
to
realize
thorough
purification
in
traditional
low-concentration
pollutant
treatments.
Herein,
we
propose
an
"adsorption/catalysis
situ"
perylene
based
bifunctional
micelle
for
efficient,
accurate
rapid
adsorption
catalytic
degradation
of
bisphenol
A
(BPA).
They
show
super-fast
(within
10
s),
high
capacity
(448
mg
g-1
)
selectivity
BPA
adsorption,
due
π-π,
hydrophobic
interactions
hydrogen
bonding.
The
improves
by
up
8
times
after
forming
micelles
compared
with
simple
nanorods,
which
is
primarily
the
superior
from
adsorption.
Moreover,
self-assembly
can
optimize
stacking
moieties
facilitate
charge
transfer
micelle,
regular
π-π
inside
units
enhances
response
visible
light,
resulting
good
cycling
stability.
