Metal–Organic Frameworks Meet MXene: New Opportunities for Electrochemical Application

Energy Material Advances, Journal Year: 2023, Volume and Issue: 4

Published: Jan. 1, 2023

Over the past few decades, metal–organic frameworks (MOFs) have been recognized as most attractive energy-involved materials due to their unique features, including ultrahigh specific surface area, superior porous structure, and excellent customizability. Nevertheless, pristine MOFs suffer from low electronic conductivity chemical instability, which severely hindered large-scale applications. Recently, MXene with abundant terminations high metallic suggested a valid substrate improve stability of MOFs. Importantly, MXene/MOF composites enhanced conductivity, rich chemistry, hierarchical structure facilitate rapid electron/ion transfer deliver better electrochemical properties than that original through synergistic effects. Moreover, can be designed into various derivatives desired architecture performance. Therefore, elaborate synthesis hybrids for devices are great interest. Herein, we provided state-of-the-art review on progress in terms strategies Furthermore, put forward current challenges feasible research directions future development.

Language: Английский

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MXene‐Based Functional Platforms for Tumor Therapy

Advanced Materials, Journal Year: 2023, Volume and Issue: 35(51)

Published: May 5, 2023

Abstract Recently, 2D transition metal carbide, nitride, and carbonitrides (MXenes) materials stand out in the field of tumor therapy, particularly construction functional platforms for optimal antitumor therapy due to their high specific surface area, tunable performance, strong absorption near‐infrared light as well preferable plasmon resonance effect. In this review, progress MXene‐mediated is summarized after appropriate modifications or integration procedures. The enhanced treatments directly performed by MXenes, significant improving effect MXenes on different therapies, imaging‐guided strategies are discussed detail. Moreover, existing challenges future development directions presented.

Language: Английский

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Synergistic Densification in Hybrid Organic‐Inorganic MXenes for Optimized Photothermal Conversion

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(29)

Published: March 15, 2024

Abstract Optimizin the efficient light‐trapping in photothermal conversion by enhancing localized surface plasmon resonance (LSPR) is crucial improving light‐heat‐conversion efficiency of Ti 3 C 2 T x MXene. However, its susceptibility to oxidation makes it prone oxides formation, diminishing metallic properties and significantly reducing LSPR effect. This work synthesizes a kind air‐stable hybrid MXenes synergistic densification strategy that incorporates sulfhydryl‐bonding between organic inorganic parts reacting MXene with thiocarboxylic acids. The resultant shortening electron transport pathways, enhanced charge density, generation additional electronic states around Fermi level collectively contribute an augmented Additionally, also demonstrate high‐temperature resistance reduced water interactions. These combined effects substantially elevate through acids modification, reaching evaporation rate 1.77 kg m −2 h −1 94.56% MXenes. approach paves way for design development three‐in‐one conversion.

Language: Английский

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Electrochemistry of 2D-materials for the remediation of environmental pollutants and alternative energy storage/conversion materials and devices, a comprehensive review

Sustainable materials and technologies, Journal Year: 2024, Volume and Issue: 40, P. e00963 - e00963

Published: May 8, 2024

Language: Английский

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Double transition-metal MXenes: Classification, properties, machine learning, artificial intelligence, and energy storage applications

Materials Today Physics, Journal Year: 2024, Volume and Issue: 42, P. 101382 - 101382

Published: Feb. 25, 2024

Language: Английский

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