Synthesis and potential applications of cyclodextrin-based metal–organic frameworks: a review DOI Creative Commons
Xu Yang, Ahmed K. Rashwan, Ahmed I. Osman

et al.

Environmental Chemistry Letters, Journal Year: 2022, Volume and Issue: 21(1), P. 447 - 477

Published: Sept. 19, 2022

Abstract Metal–organic frameworks are porous polymeric materials formed by linking metal ions with organic bridging ligands. used as sensors, catalysts for transformations, biomass conversion, photovoltaics, electrochemical applications, gas storage and separation, photocatalysis. Nonetheless, many actual metal–organic present limitations such toxicity of preparation reagents components, which make unusable food pharmaceutical applications. Here, we review the structure, synthesis properties cyclodextrin-based that could be in bioapplications. Synthetic methods include vapor diffusion, microwave-assisted, hydro/solvothermal, ultrasound techniques. The diffusion method can produce framework crystals particle sizes ranging from 200 nm to 400 μm. Applications comprise packaging, drug delivery, adsorbents, membranes. Cyclodextrin-based showed loading efficacy bioactive compounds 3.29 97.80%.

Language: Английский

Two-dimensional metal-organic framework nanosheet composites: Preparations and applications DOI

Yutian Qin,

Yue Wan,

Jun Guo

et al.

Chinese Chemical Letters, Journal Year: 2021, Volume and Issue: 33(2), P. 693 - 702

Published: July 11, 2021

Language: Английский

Citations

79
Silver nanoparticle-decorated 2D Co-TCPP MOF nanosheets for synergistic photodynamic and silver ion antibacterial DOI
Xiangqian Li,

Xinshuo Zhao,

Dandan Chu

et al.

Surfaces and Interfaces, Journal Year: 2022, Volume and Issue: 33, P. 102247 - 102247

Published: July 28, 2022

Language: Английский

Citations

69
Two‐Dimensional Metal–Organic Framework Nanosheets: Synthesis and Applications in Electrocatalysis and Photocatalysis DOI

Ya‐Long Liu,

Xiang‐Yue Liu,

Li Feng

et al.

ChemSusChem, Journal Year: 2022, Volume and Issue: 15(10)

Published: Jan. 29, 2022

Two-dimensional metal-organic nanosheets (2D MONs) are an emerging class of ultrathin, porous, and crystalline materials. The organic/inorganic hybrid nature offers MONs distinct advantages over other inorganic in terms diversity organic ligands metal notes. Compared to bulk three-dimensional frameworks, 2D possess merits high density readily accessible catalytic sites, reduced diffusion pathways for reactants/products, fast electron transport. These features endow with enhanced physical/chemical properties ideal heterogeneous catalysis. In this Review, state-of-the-art synthetic methods the fabrication were summarized. advances MONs-based materials electrocatalysis photocatalysis, including hydrogen evolution reaction (HER), oxygen (OER), reduction (ORR), carbon dioxide (CO2 RR), electro-/photocatalytic transformations systematically discussed. Finally, challenges perspectives regarding future design synthesis high-performance photocatalysis provided.

Language: Английский

Citations

67
A versatile route to fabricate Metal/UiO-66 (Metal = Pt, Pd, Ru) with high activity and stability for the catalytic oxidation of various volatile organic compounds DOI

Juntian Li,

Zhiling Xu, Teng Wang

et al.

Chemical Engineering Journal, Journal Year: 2022, Volume and Issue: 448, P. 136900 - 136900

Published: May 10, 2022

Language: Английский

Citations

65
Synthesis and potential applications of cyclodextrin-based metal–organic frameworks: a review DOI Creative Commons
Xu Yang, Ahmed K. Rashwan, Ahmed I. Osman

et al.

Environmental Chemistry Letters, Journal Year: 2022, Volume and Issue: 21(1), P. 447 - 477

Published: Sept. 19, 2022

Abstract Metal–organic frameworks are porous polymeric materials formed by linking metal ions with organic bridging ligands. used as sensors, catalysts for transformations, biomass conversion, photovoltaics, electrochemical applications, gas storage and separation, photocatalysis. Nonetheless, many actual metal–organic present limitations such toxicity of preparation reagents components, which make unusable food pharmaceutical applications. Here, we review the structure, synthesis properties cyclodextrin-based that could be in bioapplications. Synthetic methods include vapor diffusion, microwave-assisted, hydro/solvothermal, ultrasound techniques. The diffusion method can produce framework crystals particle sizes ranging from 200 nm to 400 μm. Applications comprise packaging, drug delivery, adsorbents, membranes. Cyclodextrin-based showed loading efficacy bioactive compounds 3.29 97.80%.

Language: Английский

Citations

65