Chem Catalysis, Journal Year: 2022, Volume and Issue: 2(9), P. 2157 - 2228
Published: July 14, 2022
Language: Английский
Materials Today, Journal Year: 2022, Volume and Issue: 53, P. 106 - 133
Published: Feb. 25, 2022
Language: Английский
Citations
110
Chemical Science, Journal Year: 2022, Volume and Issue: 13(8), P. 2385 - 2390
Published: Jan. 1, 2022
Aqueous rechargeable zinc-ion batteries (ZIBs) provide high theoretical capacity, operational safety, low-cost and environmental friendliness for large-scale energy storage wearable electronic devices, but their future development is plagued by low capacity poor cycle life due to the lack of suitable cathode materials. In this work, a covalent organic framework (Tp-PTO-COF) with multiple carbonyl active sites synthesized successfully introduced in aqueous ZIBs first time. Tp-PTO-COF delivers specific capacities 301.4 192.8 mA h g
Language: Английский
Citations
104
Advanced Functional Materials, Journal Year: 2022, Volume and Issue: 32(16)
Published: Jan. 4, 2022
Abstract It is challenging for polymer photocatalysts to achieve high photocatalytic performance under visible light due their weak absorption in region. Herein, a universal strategy boosting the activity of donor–acceptor (D–A) conjugated upon irradiation by inserting π‐spacer thiophene unit between electron donors and acceptors form D–π–A molecular structure reported. The introduction with narrow band gap can enhance conjugation degree chains extend range. Meanwhile, spacer through ternary copolymerization also enables controllability on chemical resulting polymers altering feed ratio acceptors. optimized copolymer photocatalyst shows an impressive hydrogen evolution rate (HER) 78.4 mmol h –1 g irradiation, HER could be further improved 127.9 UV–vis loading 1 wt% Pt co‐catalyst. More importantly, this extended other polymeric different donor acceptor units, demonstrating universality enhancing photocatalysts.
Language: Английский
Citations
100
RSC Applied Interfaces, Journal Year: 2023, Volume and Issue: 1(1), P. 43 - 69
Published: Sept. 27, 2023
Semiconductor heterojunctions are pivotal in determining the overall photocatalytic efficiency. This review explores recent advances diverse heterojunction types, charge transfer mechanisms and materials.
Language: Английский
Citations
100
Chemical Engineering Journal, Journal Year: 2022, Volume and Issue: 446, P. 137213 - 137213
Published: May 26, 2022
Language: Английский
Citations
99
Advanced Materials, Journal Year: 2022, Volume and Issue: 34(49)
Published: June 28, 2022
Translating the performance of covalent organic frameworks (COFs) from laboratory to macroscopic reality demands specific morphologies. Thus, advancement in morphological modulation has recently gained some momentum. A clear understanding nano- architecture is critical determine, optimize, and improve performances this atomically precise porous material. Along with their chemical compositions molecular frameworks, prospect morphology various applications should be discussed highlighted. thorough insight into versus application will help produce better-engineered COFs for practical implications. 2D 3D can transformed solids such as nanospheres, thin films, membranes, monoliths, foams, etc., numerous adsorption, separation photocatalysis, carbon dioxide reduction, supercapacitors, fuel cells. However, research on COF chemistry mainly focuses correlating structure property, morphology, applications. Here, insights evolution associated are provided. In each case, underlying role unveiled. Toward end, a correlation between provided future development COFs.
Language: Английский
Citations
93
Energy & Environmental Science, Journal Year: 2023, Volume and Issue: 16(3), P. 889 - 951
Published: Jan. 1, 2023
Understanding charge- and mass-transport processes in two-dimensional covalent organic frameworks to design better materials energy storage devices.
Language: Английский
Citations
91
Nanoscale, Journal Year: 2022, Volume and Issue: 14(5), P. 1679 - 1699
Published: Jan. 1, 2022
The fossil-fuel shortage and severe environmental issues have posed ever-increasing demands on clean renewable energy sources, for which the exploration of electrocatalysts has been a big challenge toward transfer storage.
Language: Английский
Citations
88
Nature Chemistry, Journal Year: 2022, Volume and Issue: 14(12), P. 1342 - 1356
Published: Nov. 28, 2022
Language: Английский
Citations
88
Angewandte Chemie International Edition, Journal Year: 2022, Volume and Issue: 61(24)
Published: March 31, 2022
Integrating molecular catalysts into designed frameworks often enables improved catalysis. Compared with porphyrin-based frameworks, metal-corrole-based have been rarely developed, although monomeric metal corroles are usually more efficient than porphyrin counterparts for the electrocatalytic oxygen reduction reaction (ORR) and evolution (OER). We herein report on porous organic polymers (POPs) as ORR OER electrocatalysts. M-POPs (M=Mn, Fe, Co, Cu) were synthesized by coupling 10-phenyl-5,15-(4-iodophenyl)corrole tetrakis(4-ethynylphenyl)methane. corrole monomers, displayed significantly enhanced catalytic activity stability. Co-POP outperformed other achieving four-electron a half-wave potential of 0.87 V vs. RHE reaching 10 mA cm-2 current density at 340 mV overpotential. This work is unparalleled to develop explore POPs
Language: Английский
Citations
86