Green Chemistry, Journal Year: 2022, Volume and Issue: 24(12), P. 4680 - 4702
Published: Jan. 1, 2022
Pyrolysis oil from lignocellulosic biomass can be fractionated into a lignin and sugar fraction. We here provide review on the structure, properties, depolymerisation strategies applications for pyrolytic in framework of biorefinery.
Language: Английский
ACS Sustainable Chemistry & Engineering, Journal Year: 2021, Volume and Issue: 9(4), P. 1427 - 1442
Published: Jan. 21, 2021
Lignin is a promising UV-shielding material to substitute the synthetic absorbers in composite due its excellent property. The chromophores group of lignin responsible for property composites, but it brings an undesirable dark color. This perspective first review recent progress on fabricating light-colored composites that contain lignin; we provide clear picture concept UV-absorbing materials can be used food packaging, healthcare products, and solar panel protection. photostability mechanisms are introduced by correlating UV absorption with intrinsic factors, like phenolic substructures molecular weight lignin. Extrinsic factors affect properties color lignin, such as extraction process, chemical modification method, obtained size also systematically discussed this perspective. By summarizing studies synergetic effect between second constitute materials, discusses benefits composite's overall properties, stability under radiation, mechanical property, dispersity, water permeability.
Language: Английский
Citations
314
Biotechnology Advances, Journal Year: 2020, Volume and Issue: 47, P. 107685 - 107685
Published: Dec. 29, 2020
Language: Английский
Citations
228
Renewable and Sustainable Energy Reviews, Journal Year: 2020, Volume and Issue: 130, P. 109977 - 109977
Published: June 30, 2020
Language: Английский
Citations
209
Green Chemistry, Journal Year: 2021, Volume and Issue: 23(11), P. 3790 - 3817
Published: Jan. 1, 2021
This review summarizes the recent advances in fabrication strategies and versatile applications of lignin-derived biodegradable film materials from viewpoint sustainable development.
Language: Английский
Citations
204
Green Chemistry, Journal Year: 2021, Volume and Issue: 23(13), P. 4633 - 4646
Published: Jan. 1, 2021
Lignin is a natural UV-blocking material owing to its aromatic structure with numerous phenolic, ketone, and intramolecular hydrogen bonds. To produce high-performance applicable sunscreen from lignin, various modification methods can be applied.
Language: Английский
Citations
192
Green Chemistry, Journal Year: 2021, Volume and Issue: 23(18), P. 6698 - 6760
Published: Jan. 1, 2021
Significant progress has been achieved in recent years relation to lignin valorization and development of high-performance sustainable materials.
Language: Английский
Citations
175
Materials Horizons, Journal Year: 2020, Volume and Issue: 7(9), P. 2237 - 2257
Published: Jan. 1, 2020
Lignin-based smart materials are emerging into advanced material applications as stimuli-responsive actuators, sensors, controlled release systems, and more.
Language: Английский
Citations
171
Chemical Reviews, Journal Year: 2021, Volume and Issue: 121(22), P. 14088 - 14188
Published: Aug. 20, 2021
This review considers the most recent developments in supramolecular and supraparticle structures obtained from natural, renewable biopolymers as well their disassembly reassembly into engineered materials. We introduce main interactions that control bottom-up synthesis top-down design at different length scales, highlighting promise of natural associated building blocks. The latter have become actors surge scientific patent literature related to subject. Such make prominent use multicomponent hierarchical polymeric assemblies contain polysaccharides (cellulose, chitin, others), polyphenols (lignins, tannins), proteins (soy, whey, silk, other proteins). offer a comprehensive discussion about exist native architectures (including composite forms), chemical modification deconstruction high axial aspect nanofibers nanorods. reflect on availability suitability types blocks enable superstructures colloidal associations. As far processing, we describe relevant transitions, solution gel state routes can be used arrive consolidated materials with prescribed properties. highlight implementation technological fields exploit synergies exhibited by polymers biocolloids integrated structured
Language: Английский
Citations
166
ChemSusChem, Journal Year: 2020, Volume and Issue: 14(4), P. 1016 - 1036
Published: Dec. 7, 2020
Sugar-based biorefineries have faced significant economic challenges. Biorefinery lignins are often classified as low-value products (fuel or low-cost chemical feedstock) mainly due to low lignin purities in the crude material. However, recent research has shown that biorefinery a great chance of being successfully used high-value products, which turn should result an economy renaissance whole idea. This critical review summarizes developments from our groups, along with state-of-the-art valorization technical lignins, focus on lignins. A beneficial synergistic effect and cellulose mixtures different applications (wood adhesives, carbon fiber nanofibers, thermoplastics) been demonstrated. phenomenon causes contain amount residual crystalline cellulose, perform superior high-purity certain applications. Where previously specific required and/or functionalized narrow molecular weight distributions, simple green processes for upgrading suggested here alternative. These approaches can be easily combined micro-/nanoparticles (LMNP) production. The also cost-efficient compared traditional modifications. allow much greater flexibility optimizing characteristics desirable than pulping processes. Such engineering, at same time, requires efficient strategy capable handling large datasets find correlations between process variables, structures properties finally their performance
Language: Английский
Citations
144
Nanomaterials, Journal Year: 2021, Volume and Issue: 11(5), P. 1336 - 1336
Published: May 19, 2021
Lignin nanomaterials have emerged as a promising alternative to fossil-based chemicals and products for some potential added-value applications, which benefits from their structural diversity biodegradability. This review elucidates perspective in recent research on nanolignins nanocomposites. It summarizes the different nanolignin preparation methods, emphasizing anti-solvent precipitation, self-assembly interfacial crosslinking. Also described are of various nanocomposites by chemical modification compounds with inorganic materials or polymers. Additionally, advances numerous high-value such use food packaging, biomedical, engineering biorefineries, described.
Language: Английский
Citations
136