2‐Benzamide Tellurenyl Iodides: Synthesis and Their Catalytic Role in CO2 Mitigation DOI
Saket Jain, Monojit Batabyal, Raviraj Ananda Thorat

et al.

Chemistry - A European Journal, Journal Year: 2023, Volume and Issue: 29(49)

Published: June 20, 2023

Benzamide-derived organochalcogens (chalcogen=S, Se, and Te) have shown promising interest in biological synthetic chemistry. Ebselen molecule derived from benzamide moiety is the most studied organoselenium. However, its heavier congener organotellurium under-explored. Here, an efficient copper-catalyzed atom economical method has been developed to synthesize 2-phenyl-benzamide tellurenyl iodides by inserting a tellurium into carbon-iodine bond of 2-iodobenzamides one pot with 78-95 % yields. Further, Lewis acidic nature Te center basic nitrogen synthesized 2-Iodo-N-(quinolin-8-yl)benzamide enabled them as pre-catalyst for activation epoxide CO2 at 1 atm preparation cyclic carbonates TOF TON values 1447 h-1 4343, respectively, under solvent-free conditions. In addition, 2-iodo-N-(quinolin-8-yl)benzamide also used activating anilines form variety 1,3-diaryl ureas up 95 yield. The mechanistic investigation mitigation done 125 NMR HRMS studies. It seems that reaction proceeds via formation catalytically active Te-N heterocycle, ebtellur intermediate which isolated structurally characterized.

Language: Английский

Transesterification of dimethyl carbonate with glycerol by perovskite-based mixed metal oxide nanoparticles for the atom-efficient production of glycerol carbonate DOI

Jitpisut Poolwong,

Silvano Del Gobbo, Valerio D’Elia

et al.

Journal of Industrial and Engineering Chemistry, Journal Year: 2021, Volume and Issue: 104, P. 43 - 60

Published: Aug. 13, 2021

Language: Английский

Citations

41
Direct synthesis of polycarbonate diols from atmospheric flow CO2 and diols without using dehydrating agents DOI Creative Commons
Yu Gu, Masazumi Tamura, Yoshinao Nakagawa

et al.

Green Chemistry, Journal Year: 2021, Volume and Issue: 23(16), P. 5786 - 5796

Published: Jan. 1, 2021

The direct synthesis of polycarbonate diols from atmospheric pressure CO 2 and α,ω-diols was achieved by using a heterogeneous CeO catalyst flow semi-bath reactor.

Language: Английский

Citations

34
Biomass- and calcium carbide-based recyclable polymers DOI

Svetlana A. Metlyaeva,

Konstantin S. Rodygin, Кристина А. Лоцман

et al.

Green Chemistry, Journal Year: 2021, Volume and Issue: 23(6), P. 2487 - 2495

Published: Jan. 1, 2021

A series of biomass-derived alcohols were successfully vinylated with calcium carbide followed by the polymerization. The polymers tested as materials and disassembled back to monomers through pyrolysis.

Language: Английский

Citations

33
Atmospheric-pressure synthesis of glycerol carbonate from CO2 and glycerol catalyzed by protic ionic liquids DOI
Cong Luo, Jiayi Wang, Houfang Lu

et al.

Green Chemistry, Journal Year: 2022, Volume and Issue: 24(21), P. 8292 - 8301

Published: Jan. 1, 2022

Under atmospheric pressure, a synthesis of glycerol carbonate was achieved in the one-pot reaction CO 2 , glycerol, and styrene oxide with 94% yield.

Language: Английский

Citations

26
Simple Halogen‐Free, Biobased Organic Salts Convert Glycidol to Glycerol Carbonate under Atmospheric CO2 Pressure DOI

Jitpisut Poolwong,

Vatcharaporn Aomchad, Silvano Del Gobbo

et al.

ChemSusChem, Journal Year: 2022, Volume and Issue: 15(17)

Published: June 21, 2022

Glycerol carbonate (GC) has emerged as an attractive synthetic target due to various promising technological applications. Among several viable strategies produce GC from CO2 and glycerol its derivatives, the cycloaddition of glycidol represents atom-economic efficient strategy that can proceed via a halide-free manifold through proton-shuttling mechanism. Here, it was shown synthesis be promoted by bio-based readily available organic salts leading quantitative formation under atmospheric pressure moderate temperatures. Comparative mechanistic experiments using sodium citrate most catalyst highlighted role both hydrogen bond donor weakly basic sites in salt towards formation. The also used for conversion other epoxy alcohols. Importantly, discovery homogeneous catalyze reaction inspired us use metal alginates heterogeneous recoverable catalysts same process.

Language: Английский

Citations

23
Glycerol Carbonate as a Versatile Alkylating Agent for the Synthesis of β-Aryloxy Alcohols DOI Creative Commons

Gabriele Galletti,

Prisco Prete,

Simone Vanzini

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2022, Volume and Issue: 10(33), P. 10922 - 10933

Published: Aug. 11, 2022

The possibility to use glycerol carbonate (GlyC) as an innovative alkylating agent for phenolic compounds in solventless conditions and the presence of a catalytic amount both homogeneous heterogeneous bases is herein described. In particular, peculiar, polyfunctional structure GlyC allows one obtain formation not only mono-phenoxy-1,2-propanediol (MPP) analogue but also 1,3-diphenoxy-2-propanol (DPP), latter being elusive using more traditional, toxic, carcinogenic reagents such glycidol and/or 3-chloro-1,2-propandiol. production DPP indeed possible due situ reactive intermediate, 4-(phenoxy)methyl-1,3-dioxolane-2-one (PhOGlyC), which may undergo consecutive nucleophilic attack phenolate, leading selective disubstituted product. This reaction nonetheless competition with PhOGlyC decarboxylation that finally limits yield up 20%, MPP roughly 60% optimized (atmospheric pressure, 140 °C, 5 h Cs2CO3 basic catalyst) starting directly from GlyC/phenolic mixture. For this reason, multistep synthetic strategy has been developed, first by obtaining quantitative isolation intermediate then promoting phenol, way 66% after 1 at 170 °C. obtained phenyl glyceryl ethers are interesting drugs scaffolds (i.e., guaifenesin, mephenesin), intermediates preparation active pharmaceutical ingredients (e.g., chlorphenesin carbamate, methocarbamol), hydrotropic solvents; preliminary evaluations biodegradability alternative surfactants have described paper.

Language: Английский

Citations

23
A halogen-free hyper-crosslinked ionic polymer for efficient multi-conversion of CO2 into carbonates under mild conditions, with a combination of theoretical study DOI
Bowen Jiang, Jia Liu, Wenjie Xiong

et al.

Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 476, P. 146873 - 146873

Published: Oct. 24, 2023

Language: Английский

Citations

16
Synergy of Photo- and Photothermal-catalytic Synthesis of Methyl Propionate from Ethylene and Carbon Dioxide over B–TiO2/Ru DOI

Xinpei Zhou,

Jincheng Dong,

Yi Zhao

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2023, Volume and Issue: 11(24), P. 9255 - 9263

Published: June 6, 2023

Using greenhouse gas CO2 as the carbonyl source, preparation of methyl propionate (MP) via synergistic effect photo- and photothermal-catalysis instead traditional thermal catalysis ethylene hydroesterification was first proposed. Ru-loaded black TiO2 (B–TiO2/Ru) selected a photothermal-catalyst since Ru has been used an excellent catalyst for hydroesterification, with high photothermal can reduce to more active CO in reaction under light irradiation. The effects from B–TiO2/Ru improve yield MP. A series were successfully prepared characterized by X-ray photoelectron spectroscopy, transmission electron microscopy, Fourier transform infrared, Raman diffraction. For carbonylation, higher oxygen vacancy density lead efficiency. mechanism full-spectrum Xe lamp illumination over is discussed.

Language: Английский

Citations

14
Sustainable valorisation of renewables through dialkyl carbonates and isopropenyl esters DOI Creative Commons
Giulia Fiorani, Alvise Perosa, Maurizio Selva

et al.

Green Chemistry, Journal Year: 2023, Volume and Issue: 25(13), P. 4878 - 4911

Published: Jan. 1, 2023

This review showcases the most recent application of commercially relevant linear and alkylene organic carbonates a representative enol ester, isopropenyl acetate (iPAc), for chemical upgrading renewable-based compounds biopolymers.

Language: Английский

Citations

13
How To Get Isocyanate? DOI Creative Commons

Zhuhua Guo,

Xiaoshu Ding, Yanji Wang

et al.

ACS Omega, Journal Year: 2024, Volume and Issue: 9(10), P. 11168 - 11180

Published: Feb. 28, 2024

Isocyanate, a pivotal chemical intermediate to synthesize polyurethane with widespread applications in household appliances, automobiles, and construction, is predominantly produced via the phosgene process, which currently holds paramount status industrial isocyanate production. Nonetheless, concerns arise from toxicity of corrosiveness hydrogen chloride, posing safety hazards. The synthesis using nonphosgene methods represents promising avenue for future development. This article primarily focuses on approach, involves formation carbamate through reaction nitro-amino compounds carbon monoxide, dimethyl carbonate, urea, among other reagents, subsequently leading thermal decomposition get isocyanate. paper emphasizes progress catalyst development during process. Single-component metal catalysts, particularly zinc, exhibit advantages such as high activity, cost-effectiveness, compatibility wide range substrates. Composite catalysts enhance yield by introducing second component adjust active composition. central research direction aims optimize adaptation conditions, including temperature, pressure, time, solvent, achieve raw material conversion product yield.

Language: Английский

Citations

5