“Spring-loaded” mechanism for chemical fixation of carbon dioxide with epoxides DOI Creative Commons

Zengjing Guo,

Yuhang Hu, Shu Dong

et al.

Chem Catalysis, Journal Year: 2022, Volume and Issue: 2(3), P. 519 - 530

Published: Jan. 24, 2022

Language: Английский

Synthesis of porous poly(ionic liquid)s for chemical CO2fixation with epoxides DOI
Guoqing Li, Shu Dong, Ping Fu

et al.

Green Chemistry, Journal Year: 2022, Volume and Issue: 24(9), P. 3433 - 3460

Published: Jan. 1, 2022

Porous poly(ionic liquid)s, combining the features of porous polymers and ionic moieties resembling structures functions liquids, have exhibited promising potential in CO 2 fixation via cycloadditions with epoxides.

Language: Английский

Citations

128
Poly(hydroxyurethane) Adhesives and Coatings: State-of-the-Art and Future Directions DOI Creative Commons
Alvaro Gomez‐Lopez, Satyannarayana Panchireddy, Bruno Grignard

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2021, Volume and Issue: 9(29), P. 9541 - 9562

Published: July 14, 2021

Polyurethane (PU) adhesives and coatings are widely used to fabricate high-quality materials due their excellent properties versatile nature, which stems from the wide range of commercially available polyisocyanate polyol precursors. This polymer family has traditionally been in a adhesive applications including bonding footwear soles, wood (flooring) concrete (subflooring), automotive industry for adhering different car parts, rotor blades, large surfaces required be adhered. Moreover, PUs also frequently applied as coatings/paints finishes can over substrates such wood, metal, plastic, textiles. One major drawbacks this lies use toxic isocyanate-based starting materials. In context REACH regulation, places restrictions on substances containing free isocyanates, it is now urgent find greener routes PUs. While non-isocyanate polyurethanes (NIPUs) based polyaddition poly(cyclic carbonate)s polyamines have emerged past decade alternatives conventional PUs, industrial implementation at an early stage development. review article, recent advances application NIPUs field summarized. The article draws attention opportunities challenges implementing scale.

Language: Английский

Citations

114
Progress in the catalytic reactions of CO2 and epoxides to selectively provide cyclic or polymeric carbonates DOI
Gulzar A. Bhat, Donald J. Darensbourg

Green Chemistry, Journal Year: 2022, Volume and Issue: 24(13), P. 5007 - 5034

Published: Jan. 1, 2022

Sustainability requires that we reuse spent carbon sources from CO2 emissions to generate new products and materials. In this regard, capture is a necessary requirement for avoiding disastrous climate changes. Hence, accompanying technology the need developing low-energy processes dioxide utilization. The coupling of three-membered cycle ethers, aka oxiranes or epoxides, with provide useful cyclic carbonates polymeric materials represents viable approach aid in addressing issue. This results recalcitrant nature being overcome by energy released during epoxide ring opening process, ∼114 kJ mol−1. Noteworthy, instance does not undergo reduction. Consideration origin also importance as epoxides derived renewable resources can be beneficial sustainable process. Consistent concept Green, it value catalysis employed these transformations biocompatible, especially production used biomedical science. review wish present recent developments catalytic chemistry afford either carbonates. Focus will centered on metal catalysis, sequential addition mixtures monomers, use organocatalysts carrying out chemical conversions.

Language: Английский

Citations

100
The order–disorder conundrum: a trade-off between crystalline and amorphous porous organic polymers for task-specific applications DOI
Arkaprabha Giri, Yashna Khakre,

G. Shreeraj

et al.

Journal of Materials Chemistry A, Journal Year: 2022, Volume and Issue: 10(33), P. 17077 - 17121

Published: Jan. 1, 2022

The review unravels the order–disorder conundrum in porous organic polymers view of task-specific applications through a comparative deliberation.

Language: Английский

Citations

76
Metal catalyst for CO2 capture and conversion into cyclic carbonate: Progress and challenges DOI

Payal Tyagi,

Devender Singh,

Neeti Malik

et al.

Materials Today, Journal Year: 2023, Volume and Issue: 65, P. 133 - 165

Published: March 21, 2023

Language: Английский

Citations

67
Economic perspectives and policy insights on carbon capture, storage, and utilization for sustainable development DOI

Sarath C. Gowd,

Prabakaran Ganeshan,

V.S. Vigneswaran

et al.

The Science of The Total Environment, Journal Year: 2023, Volume and Issue: 883, P. 163656 - 163656

Published: April 23, 2023

Language: Английский

Citations

65
Engineering organic polymers as emerging sustainable materials for powerful electrocatalysts DOI
Xun Cui, Mingjie Wu,

Xueqin Liu

et al.

Chemical Society Reviews, Journal Year: 2024, Volume and Issue: 53(3), P. 1447 - 1494

Published: Jan. 1, 2024

A comprehensive overview on organic polymers as electrocatalysts is summarized. By presenting the engineering strategies, insightful understandings, challenges, and perspectives, we hope this review can provide valuable references for readers.

Language: Английский

Citations

45
A dual-ionic hyper-crosslinked polymer for efficient CO2 fixation and conversion DOI

Mengrui Li,

Lan Shi, Yi Liu

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 481, P. 148550 - 148550

Published: Jan. 4, 2024

Language: Английский

Citations

27
Conjugated Microporous Polymers for Catalytic CO2 Conversion DOI Creative Commons
Ulzhalgas Karatayeva, Safa Ali Al Siyabi, Basiram Brahma Narzary

et al.

Advanced Science, Journal Year: 2024, Volume and Issue: 11(14)

Published: Feb. 7, 2024

Abstract Rising carbon dioxide (CO 2 ) levels in the atmosphere are recognized as a threat to atmospheric stability and life. Although this greenhouse gas is being produced on large scale, there solutions reduction indeed utilization of gas. Many these involve costly or unstable technologies, such air‐sensitive metal–organic frameworks (MOFs) for CO capture “non‐green” systems amine scrubbing. Conjugated microporous polymers (CMPs) represent simpler, cheaper, greener solution utilization. They often easy synthesize at scale (a one pot reaction many cases), chemically thermally stable (especially comparison with their MOF covalent organic framework (COF) counterparts, owing amorphous nature), and, result, cheap manufacture. Furthermore, surface areas, tunable porous chemical structures mean they reported highly efficient motifs. In addition, provide dual pathway utilize captured via conversion electrochemical into industrially valuable products. Recent studies show that all attractive properties can be realized metal‐free CMPs, presenting truly green option. The promising results two fields CMP applications reviewed explored here.

Language: Английский

Citations

25
Ionic liquid-based advanced porous organic hyper-crosslinked polymers (ILHCPs) for CO2 capture and conversion DOI
Ruina Zhang, Guokai Cui, Xin’gai Wang

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 489, P. 151102 - 151102

Published: April 15, 2024

Language: Английский

Citations

20