Cooperative multifunctional nanocarbon as efficient electro-catalysts for CO2 fixation to value-added cyclic carbonates under mild conditions DOI

Xueya Dai,

Ke Qi, Chuangwei Liu

et al.

Carbon, Journal Year: 2022, Volume and Issue: 202, P. 51 - 58

Published: Oct. 19, 2022

Language: Английский

A copper-functionalized zirconium metal–organic framework for catalytic oxidative carboxylation of olefins and CO2 DOI
Y. B. N. Tran, Phuong T. K. Nguyen, Vinh Ai Dao

et al.

New Journal of Chemistry, Journal Year: 2024, Volume and Issue: 48(12), P. 5300 - 5310

Published: Jan. 1, 2024

A Cu incorporation by post-metalation of a Zr-based metal–organic framework (MOF) produces robustly bimetallic MOF that is suitable for selective CO 2 adsorption and efficient conversion olefins into cyclic carbonates.

Language: Английский

Citations

4
2D Co-Based Metal–Organic Framework Nanosheets for the One-Pot Synthesis of Cyclic Carbonates from Olefins and CO2 DOI

Xiaofei Chen,

Shujun Liu, Chongxiong Duan

et al.

Industrial & Engineering Chemistry Research, Journal Year: 2024, Volume and Issue: 63(13), P. 5629 - 5636

Published: March 22, 2024

One-pot catalysis of olefins and CO2 provides an economical energy-efficient way for the fixation production cyclic carbonates. In this work, a two-dimensional Co-1,4-benzenedicarboxylate MOF (2D CoBDC) was synthesized via facile solvothermal reflux method further examined in one-pot synthesis The results activity evaluations detailed kinetics showed that 2D CoBDC exhibited enhanced catalytic performance (92% styrene conversion 85% carbonate yield) under cocatalyst-free conditions 100 °C, 1 bar, 12 h, compared with 3D counterpart. from effectiveness factors Thiele modulus revealed full utilization negligible mass transfer limitations catalyst. A recycle experiment confirmed excellent reusability little loss after at least 5 runs. Finally, possible mechanism reaction catalyzed by proposed.

Language: Английский

Citations

4
Multiple-site activation induced by guanidine ionic liquid decorated chromium (III) terephthalate for coupling of carbon dioxide with epoxides DOI
Nengjie Feng,

Linyan Cheng,

Yukun Zhang

et al.

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 687, P. 561 - 572

Published: Feb. 16, 2025

Language: Английский

Citations

0
Unveiling the Dichotomy Between Cobalt(II)-Exchanged X and Y Faujasite Zeolites via Oxidative Carboxylation of Alkene to Cyclic Carbonate DOI
Sakshi Bajaj, Saumi Ray

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 2, 2025

Cobalt(II)-exchanged X and Y zeolites with varying metal loadings were employed to convert CO2 cyclic carbonates starting from alkenes. The transformation was carried out using O2 as an oxidant in a mixture of under atmospheric pressure, maximum yield 35.7% carbonate achieved. Studies revealed stark difference among both the zeolites, primarily arising their ion exchange behaviors. Their catalytic recyclability properties differed result this variation.

Language: Английский

Citations

0
Cooperative multifunctional nanocarbon as efficient electro-catalysts for CO2 fixation to value-added cyclic carbonates under mild conditions DOI

Xueya Dai,

Ke Qi, Chuangwei Liu

et al.

Carbon, Journal Year: 2022, Volume and Issue: 202, P. 51 - 58

Published: Oct. 19, 2022

Language: Английский

Citations

18