Green Chemistry, Journal Year: 2021, Volume and Issue: 23(6), P. 2329 - 2335
Published: Jan. 1, 2021
Well-defined lignin fillers were synthesized by using a universal approach, that the combination of chemical modification with fractionation. This study paves way towards high-value utilization on broader scale.
Language: Английский
International Journal of Biological Macromolecules, Journal Year: 2022, Volume and Issue: 208, P. 819 - 832
Published: March 29, 2022
Language: Английский
Citations
95
Green Chemistry, Journal Year: 2022, Volume and Issue: 24(20), P. 7705 - 7750
Published: Jan. 1, 2022
The recently developed strategies for the degradation and functionalization of lignin enable it to be converted into a wide variety value-added -chemicals, -and advanced materials.
Language: Английский
Citations
82
International Journal of Biological Macromolecules, Journal Year: 2022, Volume and Issue: 200, P. 303 - 326
Published: Jan. 7, 2022
Language: Английский
Citations
71
Advanced Science, Journal Year: 2023, Volume and Issue: 10(9)
Published: Jan. 19, 2023
Abstract The utilization of lignin, the most abundant aromatic biomass component, is at forefront sustainable engineering, energy, and environment research, where its abundance low‐cost features enable widespread application. Constructing lignin into material parts with controlled desired macro‐ microstructures properties via additive manufacturing has been recognized as a promising technology paves way to practical application lignin. Considering rapid development significant progress recently achieved in this field, comprehensive critical review outlook on three‐dimensional (3D) printing highly desirable. This article fulfils demand an overview structure presents state‐of‐the‐art 3D pristine lignin‐based composites, highlights key challenges. It attempted deliver better fundamental understanding impacts morphology, microstructure, physical, chemical, biological modifications, composition/hybrids rheological behavior lignin/polymer blends, well as, mechanical, chemical performance printed materials. main points toward future developments involve hybrid manufacturing, situ polymerization, surface tension or energy driven molecular segregation are also elaborated discussed promote high‐value
Language: Английский
Citations
71
International Journal of Molecular Sciences, Journal Year: 2023, Volume and Issue: 24(14), P. 11668 - 11668
Published: July 19, 2023
At a time when environmental considerations are increasingly pushing for the application of circular economy concepts in materials science, lignin stands out as an under-used but promising and environmentally benign building block. This review focuses (A) on understanding what we mean with lignin, i.e., where it can be found how is produced plants, devoting particular attention to identity lignols (including ferulates that instrumental integrating cell wall polysaccharides) details their coupling reactions (B) providing overview actually employed component healthcare energy applications, finally paying specific use development organic shape-memory materials.
Language: Английский
Citations
53
Trends in Chemistry, Journal Year: 2024, Volume and Issue: 6(2), P. 62 - 78
Published: Jan. 11, 2024
The mysteries of chemical structures and properties lignin are gradually being unveiled. In parallel, is gaining ground as a versatile resource for the development stimuli-responsive materials with environmentally friendly, high-performance, multifunctional characters. This review focuses on synthesis mechanisms lignin-based materials, highlighting linked to responses various different stimuli, such pH temperature. We also highlight applications these in drug carriers, bioimaging, shape memory, strain sensors, substance detection, objective showcase untapped potential lignin, challenging prevailing notion that merely by-product pulp industry. Finally, we identify challenges propose future directions materials.
Language: Английский
Citations
41
RSC Sustainability, Journal Year: 2024, Volume and Issue: 2(4), P. 804 - 831
Published: Jan. 1, 2024
A comprehensive overview of various physicochemical modification and functionalization routes lignin to produce alternative low carbon footprint feedstock for sustainable polymers advanced material applications is presented.
Language: Английский
Citations
40
Accounts of Chemical Research, Journal Year: 2024, Volume and Issue: 57(14), P. 1918 - 1930
Published: July 4, 2024
ConspectusThe increasing demand for polymeric materials derived from petroleum resources, along with rising concerns about climate change and global plastic pollution, has driven the development of biobased materials. Lignin, which is second most abundant biomacromolecule after cellulose, represents a promising renewable raw material source preparation advanced The lucrative properties lignin include its high carbon content (>60 atom %), thermal stability, biodegradability, antioxidant activity, absorbance ultraviolet radiation, slower biodegradability compared to other wood components. Moreover, advent nanoparticles (LNPs) over last ten years circumvented many well-known shortcomings technical lignins, such as heterogeneity poor compatibility polymers, thereby unlocking great potential functional materials.LNPs stand out owing their well-defined spherical shape excellent colloidal due electrostatic repulsion forces carboxylic acid phenolic hydroxyl groups enriched on surface. These prevent aggregation in aqueous dispersions (pH 3-9) provide surface area mass ratio that been exploited adsorb positively charged compounds enzymes or polymers. Consequently, it not surprising LNPs have become prominent player applied research areas biocatalysis composites, among others. However, like all ventures life, also face certain challenges limit end-uses. Solvent instability remains challenging aspect tendency these particles dissolve aggregate organic solvents basic acidic pH, thus limiting window chemical functionalization applications. In addition, need solvent during preparation, miscibility hydrophobic matrices, nascent phase regarding use smart identified important be addressed.In this Account, we recapitulate our efforts past overcome main limitations mentioned above. We begin brief introduction fundamentals detailed discussion associated challenges. then highlight work on: (i) Preparation lignin-based nanocomposites improved through controlled dispersion within matrix, (ii) Stabilization via covalent (intraparticle cross-linking) noncovalent (hydration barrier) approaches, (iii) an organic-solvent-free method production LNPs, (iv) toward content. Finally, offer perspectives rapidly growing field.
Language: Английский
Citations
21
International Journal of Biological Macromolecules, Journal Year: 2024, Volume and Issue: 261, P. 129877 - 129877
Published: Feb. 1, 2024
Language: Английский
Citations
20
New Journal of Chemistry, Journal Year: 2021, Volume and Issue: 45(16), P. 6986 - 7013
Published: Jan. 1, 2021
A pedagogical overview of the main extraction procedures and structural features, characterization methods state-of-the-art applications.
Language: Английский
Citations
103