Advanced Synthesis & Catalysis,
Journal Year:
2023,
Volume and Issue:
365(6), P. 900 - 905
Published: Feb. 20, 2023
Herein,
we
report
the
development
of
transition-metal-catalyst-
and
external-oxidant-free
electrochemical
cross-coupling
hydrogen-evolution
chemistry
involving
glycine
amides
diarylphosphine
oxides.
A
broad
range
biologically
active
α-aminophosphonates
was
obtained
in
moderate
to
good
yields
a
clean
sustainable
manner.
Moreover,
TBAB
(tetrabutylammonium
bromide)
electrolyte
recycled
four
times
without
obvious
loss
reaction
activity.
this
protocol
performed
on
gram
scale
under
slightly
modified
electrolytic
conditions
or
combination
with
continuous
flow
microreactor
technology.
Control
experiments
were
used
disclose
possible
free-radical
mechanism.
As
service
our
authors
readers,
journal
provides
supporting
information
supplied
by
authors.
Such
materials
are
peer
reviewed
may
be
re-organized
for
online
delivery,
but
not
copy-edited
typeset.
Technical
support
issues
arising
from
(other
than
missing
files)
should
addressed
Please
note:
The
publisher
is
responsible
content
functionality
any
Any
queries
content)
directed
corresponding
author
article.
Russian Chemical Reviews,
Journal Year:
2023,
Volume and Issue:
92(12), P. RCR5104 - RCR5104
Published: Dec. 1, 2023
After
the
appearance
of
green
chemistry
concept,
which
was
introduced
in
vocabulary
early
1990s,
its
main
statements
have
been
continuously
developed
and
modified.
Currently,
there
are
10–12
cornerstones
that
should
form
basis
for
an
ideal
chemical
process.
This
review
analyzes
accumulated
experience
achievements
towards
design
products
processes
reduce
or
eliminate
use
generation
hazardous
substances.
The
presents
views
leading
Russian
scientists
specializing
various
fields
this
subject,
including
homogeneous
heterogeneous
catalysis,
fine
basic
organic
synthesis,
electrochemistry,
polymer
chemistry,
based
on
bio-renewable
feedstocks
energetic
compounds
materials.
A
new
approach
to
quantitative
evaluation
environmental
friendliness
by
authors
is
described.
<br>
bibliography
includes
1761.
Nature Communications,
Journal Year:
2023,
Volume and Issue:
14(1)
Published: Jan. 23, 2023
Electricity-driven
asymmetric
catalysis
is
an
emerging
powerful
tool
in
organic
synthesis.
However,
induction
so
far
has
mainly
relied
on
forming
strong
bonds
with
a
chiral
catalyst.
Asymmetry
induced
by
weak
interactions
catalyst
electrochemical
medium
remains
challenging
due
to
compatibility
issues
related
solvent
polarity,
electrolyte
interference,
etc.
Enabled
properly
designed
phase-transfer
strategy,
here
we
have
achieved
two
efficient
electricity-driven
catalytic
bromocyclization
processes
ion-pairing
interaction.
The
combined
use
of
and
phosphate
catalyst,
together
NaBr
as
the
bromine
source,
constitutes
key
advantages
over
conventional
chemical
oxidation
approach.
Synergy
multiple
events,
including
anodic
oxidation,
ion
exchange,
phase
transfer,
bromination,
inhibition
Br2
decomposition
NaHCO3,
proved
critical
success.
Advanced Synthesis & Catalysis,
Journal Year:
2023,
Volume and Issue:
365(13), P. 2183 - 2187
Published: June 15, 2023
Abstract
Carbon
dioxide
is
a
harmful
greenhouse
gas,
as
well
valuable
resource.
Here,
three‐component
cyclization
reaction
was
developed
for
the
synthesis
of
oxazolidine‐2,4‐diones
by
immobilizing
CO
2
under
electrochemistry
and
copper
catalyst.
Propargyl
amide
used
substrate
to
capture
carbon
produce
carboxyl
anion,
while
selenide
produced
electrophilic
receptor
activate
triple
bond
electrochemical
conditions.
Then,
intramolecular
carried
out
obtain
target
product.
Through
this
environmentally
friendly
strategy,
series
important
synthesized.
Journal of the American Chemical Society,
Journal Year:
2024,
Volume and Issue:
146(31), P. 21960 - 21967
Published: July 23, 2024
Oxygen-atom
transfer
reactions
are
a
prominent
class
of
synthetic
redox
that
often
use
high-energy
oxygen-atom
donor
reagents.
Electrochemical
methods
can
bypass
these
reagents
by
using
water
as
the
source
oxygen
atoms
through
pathways
involving
direct
or
indirect
(mediated)
electrolysis.
Here,
manganese
porphyrins
and
related
mediators
shown
to
be
effective
molecular
electrocatalysts
for
selective
oxidation
thioethers
sulfoxides,
without
overoxidation
sulfone.
The
proceed
proton-coupled
Mn
Chemical Communications,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
An
electrochemical
method
for
oxidative
dearomatization
of
electron-deficient
phenols
is
reported,
using
tetrabutylammonium
bromide
as
a
catalytic
mediator
under
aqueous
biphasic
conditions.
The Journal of Organic Chemistry,
Journal Year:
2020,
Volume and Issue:
86(1), P. 917 - 928
Published: Dec. 7, 2020
We
developed
a
green
method
for
the
synthesis
of
spiro[4.5]trienones
through
an
electrochemical
oxidative
halocyclization
with
N-aryl
alkynamides.
This
reaction
was
conducted
under
metal-catalyst-
and
exogenous-oxidant-free
conditions
at
room
temperature.
Using
readily
available
LiCl,
LiBr,
LiI
as
halogen
source,
variety
dearomative
halo-spirocyclization
products
were
obtained
in
good
to
excellent
yields
broad
scope
functional
group
tolerance.
Organic & Biomolecular Chemistry,
Journal Year:
2021,
Volume and Issue:
19(12), P. 2578 - 2602
Published: Jan. 1, 2021
In
this
review
we
target
sp,
sp2and
sp3carbon
fluorination,
chlorination,
bromination
and
iodination
reactions
using
electrolysis
as
a
redox
medium.
Mechanistic
insights
substrate
reactivity
are
also
discussed.
The Journal of Organic Chemistry,
Journal Year:
2021,
Volume and Issue:
86(17), P. 12378 - 12385
Published: Aug. 16, 2021
Without
employing
an
external
oxidant,
the
simple
synthesis
of
3-halochromones
and
various
halogenated
electron-rich
arenes
has
been
realized
with
electrode
oxidation
by
simplest
sodium
halide
(NaX,
X
=
Cl,
Br,
I)
as
halogen
source.
This
electrochemical
method
is
advantageous
for
mild
room
temperature
operation,
environmental
friendliness
well
broad
substrate
scope
in
both
C–H
bond
donor
source
components.
