Light emissions of ratiometric aliphatic redox polymer from canonical, anion, and anion-aggregate: Reduction-associated naked eye detections of Hg(II), Fe(III), and Cu(II) DOI
Joy Sankar Deb Roy, Mousumi Deb, MD Hussain Sanfui

et al.

European Polymer Journal, Journal Year: 2024, Volume and Issue: 206, P. 112754 - 112754

Published: Jan. 10, 2024

Language: Английский

Grouping illuminants by aggregation-induced emission (AIE) mechanisms for designing sensing platforms for food quality and safety inspection DOI Creative Commons

Chenyue Zhou,

Ji Ma, Da‐Wen Sun

et al.

Trends in Food Science & Technology, Journal Year: 2023, Volume and Issue: 134, P. 232 - 246

Published: March 6, 2023

Recently, food quality and safety have emerged as significant global issues. The rapid detection of contaminants spoilage markers has attracted increasing concerns. grouping illuminants based on the principle aggregation-induced emission (AIE) mechanism for designing monitoring analysis sensing platforms can address shortcomings conventional fluorophore aggregation-caused quenching (ACQ), offering benefits superb photoluminescence properties trace-level accuracy. With demand real-time in industry, such a robust platform is becoming progressively important. In current review, luminescence mechanisms structure design AIE are first introduced. elucidated, including noncovalent interaction, solubility viscosity change, specific recognition, photophysical quenching/dequenching processes. Moreover, this review comprehensively summarizes latest representative applications foodborne pathogens, environmental pollutants, biotoxins, agrochemicals, illegal additives, markers. Lastly, outlook challenges discussed. emerging exhibits outstanding advantages rapidity, high sensitivity, good accuracy analytes detection, well predestined capabilities constructing portable solid-state sensors. combination with other technologies, immunosensing techniques, freshness labels, smartphone platforms, further facilitate development commercialized especially portable, real-time, on-site applications. From typical organic molecules to nature-derived nanomaterials, discovery, synthesis different types substances under active exploration provide better solutions inspection.

Language: Английский

Citations

19

Intriguing Optical Properties due to the Intermolecular Interaction between AIE and ACQ Materials DOI
Zhichao Gong,

Xuejiao Rong,

Guomin Sui

et al.

Advanced Optical Materials, Journal Year: 2023, Volume and Issue: 11(14)

Published: April 25, 2023

Abstract To take advantage of the respective strengths aggregation‐induced emission (AIE) and aggregation‐caused quenching (ACQ) materials, in this paper a unique approach is taken which that tetraphenylethene triphenylamine (classical AIEs), borondipyrromethene benzothiadiazole ACQs) are selected to construct AIE@ACQ bimolecular systems by simple compounding method, focusing on effects optical properties such as fluorescence, photothermal therapy, phosphorescence, photodynamic therapy. Above all, mechanisms laws system preliminarily found. First, AIEs ACQs must, respectively, have electron‐acceptor electron‐donors form an intermolecular push–pull structure ensure two molecules close each other, π – stacking interaction separates highest occupied molecular orbitals lowest unoccupied reduce Δ E st , causing intriguing properties. Second, matching degree conjugate between also important factor. Utilizing these systems, it found different structural compositions possess synergy properties, so can be constructed according actual needs, advantages efficiency convenience, providing new idea for united application ACQs.

Language: Английский

Citations

18

Small-molecule fluorogenic probes based on indole scaffold DOI
Pintu Ghosh,

Anirban Karak,

Ajit Kumar Mahapatra

et al.

Organic & Biomolecular Chemistry, Journal Year: 2024, Volume and Issue: 22(14), P. 2690 - 2718

Published: Jan. 1, 2024

Indoles are the most versatile organic N-heterocyclic compounds widely present in bioactive natural products and used different fields such as coordination chemistry, pharmacy, dyes, medicine, well biology polymer industries.

Language: Английский

Citations

8

Dynamic response and discrimination of gaseous sarin using a boron‐difluoride complex film‐based fluorescence sensor DOI Creative Commons

Zhi-Jie Zhou,

Lei Zhang,

Lingya Peng

et al.

Aggregate, Journal Year: 2024, Volume and Issue: unknown

Published: July 3, 2024

Abstract This study presents a novel boron‐difluoride complex‐based fluorescent nanofilm sensor capable of detecting sarin vapors in the environment by reporting an output fluorescence signal. The sensor's evaluation demonstrated exceptionally low detection limit for vapor, even presence various interfering gases, with theoretical and practical limits 0.7 1 ppb, respectively. featured rapid response time (less than 2 s), broad linear range (1 ppb–1000 ppm), superior selectivity vapor over group analytes, outperforming existing sensors. Mechanistic indicates that heightened sensitivity to is due robust affinity nitrogen atoms within core BODIQ unit sarin. Additionally, tetraphenylethylene structure steric hindrance effectively inhibits tight packing derivatives, forms numerous microporous structures self‐assembled nanofilm, which are beneficial mass transfer, enhancing efficiency vapors. Furthermore, we have achieved differentiation sarin, diethyl chlorophosphate, HCl through analysis sensing kinetic. opens new avenues sustainable, low‐cost, environment‐friendly portable devices, as well environmental monitoring tracking applications.

Language: Английский

Citations

8

Light emissions of ratiometric aliphatic redox polymer from canonical, anion, and anion-aggregate: Reduction-associated naked eye detections of Hg(II), Fe(III), and Cu(II) DOI
Joy Sankar Deb Roy, Mousumi Deb, MD Hussain Sanfui

et al.

European Polymer Journal, Journal Year: 2024, Volume and Issue: 206, P. 112754 - 112754

Published: Jan. 10, 2024

Language: Английский

Citations

7