Chemical Science,
Journal Year:
2022,
Volume and Issue:
13(26), P. 7707 - 7738
Published: Jan. 1, 2022
Two-dimensional
(2D)
transition
metal
dichalcogenides
(TMDs)
and
their
heterostructures
have
attracted
significant
interest
in
both
academia
industry
because
of
unusual
physical
chemical
properties.
They
offer
numerous
applications,
such
as
electronic,
optoelectronic,
spintronic
devices,
addition
to
energy
storage
conversion.
Atomic
structural
modifications
van
der
Waals
layered
materials
are
required
achieve
unique
versatile
properties
for
advanced
applications.
This
review
presents
a
discussion
on
the
atomic-scale
2D
TMDs
ACS Applied Materials & Interfaces,
Journal Year:
2021,
Volume and Issue:
13(24), P. 28721 - 28728
Published: June 9, 2021
Two-dimensional
(2D)
transition
metal
chalcogenides
(TMCs)
become
more
attractive
upon
addition
of
a
third
element
owing
to
their
unique
structure
and
remarkable
physical
chemical
properties,
which
endow
these
materials
with
considerable
potential
for
applications
in
nanoscale
devices.
In
this
work,
RexNb(1–x)S2-based
saturable
absorber
(SA)
device
ultrafast
photonics
is
studied.
The
assembled
by
placing
RexNb(1–x)S2
nanosheets
thickness
1–3
nm
onto
microfiber
increase
compatibility
an
all-fiber
laser
cavity.
prepared
exhibits
modulation
depth
24.3%,
saturation
intensity
10.1
MW/cm2,
nonsaturable
loss
28.5%.
Furthermore,
the
used
generate
ultrashort
pulses
erbium-doped
fiber
(EDF)
At
pump
power
260
mW,
EDF
operates
conventional
soliton
mode-locked
region.
pulse
width
285
fs,
repetition
frequency
61.993
MHz.
particular,
bound-state
mode-locking
operation
successfully
obtained
range
300–900
mW.
are
formed
doubling
identical
solitons
temporal
interval
0.8
ps.
output
as
high
47.9
123.61
These
results
indicate
that
proposed
SAs
have
comparable
properties
currently
2D
provide
basis
application
field
photonics.
We
predict,
through
first-principles
calculations,
a
different
class
of
Janus
two-dimensional
(2D)
materials
$X{\mathrm{Sn}}_{2}Y$
($X,
Y=\mathrm{P}$,
As,
Sb,
and
Bi;
$X\ensuremath{\ne}Y$).
It
has
found
that
these
2D
monolayers
have
intrinsic
polarization
effect
owing
to
presence
mirror-symmetry
breaking.
$\mathrm{Sb}{\mathrm{Sn}}_{2}\mathrm{Bi},
\mathrm{As}{\mathrm{Sn}}_{2}\mathrm{Sb}$,
$\mathrm{P}{\mathrm{Sn}}_{2}\mathrm{As}$
semiconducting
feature,
however
$\mathrm{As}{\mathrm{Sn}}_{2}\mathrm{Bi},
\mathrm{P}{\mathrm{Sn}}_{2}\mathrm{Bi}$,
$\mathrm{P}{\mathrm{Sn}}_{2}\mathrm{Sb}$
metallic
feature
with
inverted
band
structure.
When
the
spin-orbit
coupling
(SOC)
is
considered,
double
Rashba
effects
are
in
$\mathrm{Sb}{\mathrm{Sn}}_{2}\mathrm{Bi}$.
Band
inversion
SOC
leads
unexpected
spin-valley
splitting
characteristics
$\mathrm{P}{\mathrm{Sn}}_{2}\mathrm{Sb}$,
showing
circle-type
Berry
curvature.
The
electronic
spin
properties
tunable
via
applying
external
strain
electric
field,
resulting
Rashba-type
spin-splitting,
${p}_{z}/{p}_{xy}$
inversion,
Dirac
cone.
In
particular,
sombrero
dispersion
Van
Hove
singularity
revealed
by
exerting
tensile
strain.
therefore
investigate
Lifshitz
transition
inverse
Edelstein
(also
referred
as
spin-charge
conversion)
strained
$\mathrm{P}{\mathrm{Sn}}_{2}\mathrm{As}$.
On
basis
k\ifmmode\cdot\else\textperiodcentered\fi{}p
model
clean
limit,
Drude
coefficient
for
conversion
estimated
be
about
0.086
$e$/\AA{}
+3%.
Finally,
synergic
field
considered
manipulate
conversion.
Our
results
provide
effect,
transition,
NPG Asia Materials,
Journal Year:
2022,
Volume and Issue:
14(1)
Published: Feb. 25, 2022
Abstract
Two-dimensional
(2D)
Janus
transition
metal
dichalcogenides
(TMDCs)
are
highly
attractive
as
an
emerging
class
of
2D
materials,
but
only
a
few
methods
available
for
fabricating
them.
These
rely
on
the
initial
growth
TMDCs
in
one
process,
followed
by
additional
plasma
or
high-temperature
(T)
process.
To
overcome
these
drawbacks,
we
employ
new
approach
NaCl-assisted
single-process
chemical
vapor
deposition,
which
consists
three
steps
that
proceed
altering
temperature
situ.
In
first
step,
MoS
2
is
deposited
onto
SiO
/Si
substrate
with
Mo
and
S
atoms
activated
different
zones.
second
vacancies
formed
upper
layer
grown
annealing.
third
filled
Se
atoms.
Throughout
steps,
NaCl
lowers
melting
point
constituent
atoms,
while
T
each
zone
properly
controlled.
The
mechanism
clarified
separate
annealing
experiment
does
not
involve
supply
results
highlight
simple
cost-effective
growing
MoSSe,
more
useful
fundamental
studies
device
applications.
Chemical Science,
Journal Year:
2022,
Volume and Issue:
13(26), P. 7707 - 7738
Published: Jan. 1, 2022
Two-dimensional
(2D)
transition
metal
dichalcogenides
(TMDs)
and
their
heterostructures
have
attracted
significant
interest
in
both
academia
industry
because
of
unusual
physical
chemical
properties.
They
offer
numerous
applications,
such
as
electronic,
optoelectronic,
spintronic
devices,
addition
to
energy
storage
conversion.
Atomic
structural
modifications
van
der
Waals
layered
materials
are
required
achieve
unique
versatile
properties
for
advanced
applications.
This
review
presents
a
discussion
on
the
atomic-scale
2D
TMDs