Recent advances in fluorescence chemosensors for ammonia sensing in the solution and vapor phases DOI Creative Commons

P. Raja Lakshmi,

Binduja Mohan,

Preeti Kang

et al.

Chemical Communications, Journal Year: 2023, Volume and Issue: 59(13), P. 1728 - 1743

Published: Jan. 1, 2023

Developing low-cost and reliable sensor systems for the detection of trace amounts toxic gases is an important area research. Ammonia (NH3) a commonly produced industrial chemical harmful colorless pungent gas released from various manufacturing processing industries. Continuous exposure to NH3 vapor causes serious menace human health, microorganisms, ecosystem. Exposure relatively higher concentrations severely affects respiratory system leads kidney failure, nasal erosion ulcers, gastrointestinal diseases. Excessive accumulation in biosphere can cause metabolic disruptions. As consequence this, therefore, suitable sensing methods selective quantification are utmost need protect environment living systems. Given there have been significant research advances preceding years on development fluorescence chemosensors efficient monitoring concentration both solution phases. This review article highlights several reported until recently quantifying phase or ammonium ions (NH4+) phase. The wide variety discussed this systematically gathered according their structures, functional properties, properties. Finally, usefulness existing challenges using fluorescence-based method future perspective also highlighted.

Language: Английский

Covalent organic frameworks for photocatalysis: Synthesis, structural features, fundamentals and performance DOI
Yun‐Nan Gong, Xinyu Guan, Hai‐Long Jiang

et al.

Coordination Chemistry Reviews, Journal Year: 2022, Volume and Issue: 475, P. 214889 - 214889

Published: Oct. 15, 2022

Language: Английский

Citations

242
Metalated covalent organic frameworks: from synthetic strategies to diverse applications DOI
Qun Guan, Lele Zhou, Yu‐Bin Dong

et al.

Chemical Society Reviews, Journal Year: 2022, Volume and Issue: 51(15), P. 6307 - 6416

Published: Jan. 1, 2022

This review highlights the recent advances of metalated covalent organic frameworks, including synthetic strategies and applications, discusses current challenges future directions.

Language: Английский

Citations

214
Designing covalent organic frameworks with Co-O4 atomic sites for efficient CO2 photoreduction DOI Creative Commons
Qian Zhang, Shuaiqi Gao,

Yingying Guo

et al.

Nature Communications, Journal Year: 2023, Volume and Issue: 14(1)

Published: Feb. 28, 2023

Abstract Cobalt coordinated covalent organic frameworks have attracted increasing interest in the field of CO 2 photoreduction to CO, owing their high electron affinity and predesigned structures. However, achieving conversion efficiency is challenging since most Co related coordination environments facilitate fast recombination photogenerated electron-hole pairs. Here, we design two kinds Co-COF catalysts with oxygen atoms find that after tuning environment, reported framework catalyst Co-O 4 sites exhibits a production rate 18000 µmol g −1 h selectivity as 95.7% under visible light irradiation. From in/ex-situ spectral characterizations theoretical calculations, it revealed significantly carrier migration matrixes inhibit pairs photocatalytic process. This work opens way for high-performance photoreduction.

Language: Английский

Citations

196
Aggregation behaviour of pyrene-based luminescent materials, from molecular design and optical properties to application DOI
Xing Feng, Xiaohui Wang, Carl Redshaw

et al.

Chemical Society Reviews, Journal Year: 2023, Volume and Issue: 52(19), P. 6715 - 6753

Published: Jan. 1, 2023

This review not only highlights the progress of emission and electronic behaviour new pyrene-based luminescence molecules in aggregated state, but also provides a perspective for understanding mechanism optoelectronic properties pyrenes.

Language: Английский

Citations

142
3D Covalent Organic Frameworks with Interpenetrated pcb Topology Based on 8-Connected Cubic Nodes DOI
Zhen Shan, Miaomiao Wu, Dongyang Zhu

et al.

Journal of the American Chemical Society, Journal Year: 2022, Volume and Issue: 144(13), P. 5728 - 5733

Published: March 23, 2022

The connectivity of building units for 3D covalent organic frameworks (COFs) has long been primarily 4 and 6, which have severely curtailed the structural diversity COFs. Here we demonstrate successful design synthesis a porphyrin based, 8-connected block with cubic configuration, could be further reticulated into an unprecedented interpenetrated pcb topology by imine condensation linear amine monomers. This study presents first case high-connectivity bearing nodes, thus greatly enriching topological possibilities

Language: Английский

Citations

107
Smart multifunctional direct Z-scheme In2S3@PCN-224 heterojunction for simultaneous detection and photodegradation towards antibiotic pollutants DOI
Feng‐Zao Chen, Yujun Li, Mi Zhou

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2023, Volume and Issue: 328, P. 122517 - 122517

Published: Feb. 24, 2023

Language: Английский

Citations

92
Highly Crystalline Polyimide Covalent Organic Framework as Dual-Active-Center Cathode for High-Performance Lithium-Ion Batteries DOI

Liyi Yao,

Chao Ma, Libo Sun

et al.

Journal of the American Chemical Society, Journal Year: 2022, Volume and Issue: 144(51), P. 23534 - 23542

Published: Dec. 13, 2022

Polyimide covalent organic framework (PI-COF) materials that can realize intrinsic redox reactions by changing the charge state of their electroactive sites are considered as emerging electrode for rechargeable devices. However, highly crystalline PI-COFs with hierarchical porosity less reported due to rapid reaction between monomers and poor reversibility polyimidization reaction. Here, we developed a water-assistant synthetic strategy adjust rate polyimidization, PI-COF (COFTPDA-PMDA) kgm topology consisting dual active centers N,N,N′,N′-tetrakis(4-aminophenyl)-1,4-benzenediamine (TPDA) pyromellitic dianhydride (PMDA) ligands was successfully synthesized high crystallinity porosity. The COFTPDA-PMDA possesses micro-/mesoporous channels largest surface area (2669 m2/g) in PI-COFs, which promote Li+ ions bulky bis(trifluoromethanesulfonyl)imide (TFSI–) electrolyte sufficiently interact on COF skeleton increase specific capacity cathode materials. As material lithium-ion batteries, COFTPDA-PMDA@50%CNT integrated center carbon nanotubes via π–π interactions gave initial 233 mAh/g (0.5 A/g) maintains at 80 even current density 5.0 A/g after 1800 cycles.

Language: Английский

Citations

84
Covalent organic frameworks (COFs) and metal–organic frameworks (MOFs) as electrochemical sensors for the efficient detection of pharmaceutical residues DOI Creative Commons
Brij Mohan,

Ritu Kumari,

Virender Virender

et al.

Environment International, Journal Year: 2023, Volume and Issue: 175, P. 107928 - 107928

Published: April 11, 2023

Pharmaceutical residues are the undecomposed remains from drugs used in medical and food industries. Due to their potential adverse effects on human health natural ecosystems, they of increasing worldwide concern. The acute detection pharmaceutical can give a rapid examination quantity then prevent them further contamination. Herein, this study summarizes discusses most recent porous covalent-organic frameworks (COFs) metal–organic (MOFs) for electrochemical various residues. review first introduces brief overview drug toxicity its living organisms. Subsequently, different materials techniques discussed with materials' properties applications. Then development COFs MOFs has been addressed structural sensing Further, stability, reusability, sustainability MOFs/COFs reviewed discussed. Besides, MOFs' limits, linear ranges, role functionalities, immobilized nanoparticles analyzed Lastly, summarized [email protected] composite as sensors, fabrication strategies enhance potential, current challenges area.

Language: Английский

Citations

78
Preparation and quantitative analysis of multicenter luminescence materials for sensing function DOI
Zongsu Han, Kunyu Wang, Hong‐Cai Zhou

et al.

Nature Protocols, Journal Year: 2023, Volume and Issue: 18(5), P. 1621 - 1640

Published: Feb. 27, 2023

Language: Английский

Citations

77
Magnetic Covalent Organic Framework Composites for Wastewater Remediation DOI Creative Commons
Juan Yang, Lijin Huang, Jungmok You

et al.

Small, Journal Year: 2023, Volume and Issue: 19(37)

Published: May 8, 2023

Abstract Covalent organic frameworks (COFs) with high specific surface area, tailored structure, easy functionalization, and excellent chemical stability have been extensively exploited as fantastic materials in various fields. However, most cases, COFs prepared powder form suffer from the disadvantages of tedious operation, strong tendency to agglomerate, poor recyclability, greatly limiting their practical application environmental remediation. To tackle these issues, fabrication magnetic (MCOFs) has attracted tremendous attention. In this review, several reliable strategies for MCOFs are summarized. addition, recent outstanding adsorbents removal contaminants including toxic metal ions, dyes, pharmaceuticals personal care products, other pollutants is discussed. Moreover, in‐depth discussions regarding structural parameters affecting potential highlighted detail. Finally, current challenges future prospects field provided expectation boost application.

Language: Английский

Citations

74