Introducing Hydrogen-Bonding Microenvironment in Close Proximity to Single-Atom Sites for Boosting Photocatalytic Hydrogen Production DOI
Shuaishuai Hu, Ming‐Liang Gao, Jiajia Huang

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(29), P. 20391 - 20400

Published: July 10, 2024

Inspired by enzymatic catalysis, it is crucial to construct hydrogen-bonding-rich microenvironment around catalytic sites; unfortunately, its precise construction and understanding how the distance between such sites affects catalysis remain significantly challenging. In this work, a series of metal-organic framework (MOF)-based single-atom Ru

Language: Английский

Nanoparticle proximity controls selectivity in benzaldehyde hydrogenation DOI
Kang Rui Garrick Lim, Selina K. Kaiser, Haichao Wu

et al.

Nature Catalysis, Journal Year: 2024, Volume and Issue: 7(2), P. 172 - 184

Published: Feb. 16, 2024

Language: Английский

Citations

26
Large-Area Conductive MOF Ultrathin Film Controllably Integrating Dinuclear-Metal Sites and Photosensitizers to Boost Photocatalytic CO2 Reduction with H2O as an Electron Donor DOI
Yu‐An Kuo,

Ke‐Ying Tao,

Tianqun Song

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(10), P. 6893 - 6904

Published: March 1, 2024

Owing to the electrical conductivity and periodic porosity, conductive metal–organic framework (cMOF) ultrathin films open new perspectives photocatalysis. The space-selective assembly of catalytic sites photosensitizers in/on cMOF is favorable for promoting separation photogenerated carriers mass transfer. However, controllable integration functional units into film rarely reported. Herein, via synergistic effect steric hindrance an electrostatic-driven strategy, dinuclear-metal molecular catalysts (DMC) perovskite (PVK) quantum dot were immobilized channels onto surface films, respectively, affording [DMC@cMOF]-PVK photocatalysts. In this unique heterostructure, not only facilitated charge transfer from PVK DMC but also guaranteed Using H2O as electron donor, realized a 133.36 μmol·g–1·h–1 CO yield in photocatalytic CO2 reduction, much higher than DMC-PVK. excellent light transmission multilayers integrated increase per unit area, 10-layer device 1115.92 μmol·m–2 4 h, which was 8-fold that powder counterpart. This work lightens development cMOF-based composite paves novel avenue photocatalyst.

Language: Английский

Citations

22
Recent advances of polyoxometalate-based materials applied for electron-related devices DOI

Yalun Hu,

Yanying Wang,

Jun‐Wei Zhao

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 506, P. 215724 - 215724

Published: Feb. 24, 2024

Language: Английский

Citations

20
Visible light-mediated intermolecular crossed [2+2] cycloadditions using a MOF-supported copper triplet photosensitizer DOI
Jun Guo, Qi Xia,

Wing Yi Tang

et al.

Nature Catalysis, Journal Year: 2024, Volume and Issue: 7(3), P. 307 - 320

Published: Feb. 23, 2024

Language: Английский

Citations

18
Introducing Hydrogen-Bonding Microenvironment in Close Proximity to Single-Atom Sites for Boosting Photocatalytic Hydrogen Production DOI
Shuaishuai Hu, Ming‐Liang Gao, Jiajia Huang

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(29), P. 20391 - 20400

Published: July 10, 2024

Inspired by enzymatic catalysis, it is crucial to construct hydrogen-bonding-rich microenvironment around catalytic sites; unfortunately, its precise construction and understanding how the distance between such sites affects catalysis remain significantly challenging. In this work, a series of metal-organic framework (MOF)-based single-atom Ru

Language: Английский

Citations

18