ChemSusChem,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 17, 2025
Solvent-free
techniques
have
gained
considerable
attention
in
recent
years
due
to
their
environmental
advantages
and
potential
enable
chemical
reactivities
beyond
the
reach
of
traditional
solution-based
methods.
Mechanochemistry
has
emerged
as
a
groundbreaking
approach
drive
sustainable
processes.
Despite
its
promise,
some
challenges
still
need
be
explored,
including
overlooked
issue
material
leaching
during
grinding,
phenomenon
which
components
from
milling
media
or
reaction
vessels,
such
stainless
steel,
unintentionally
alter
outcomes.
This
study
investigates
role
metal
reducing
arylnitrosamines
by
using
poorly
soluble
solid
reagent,
thiourea
dioxide
(TDO),
focusing
on
steel
vessels.
By
comparing
conventional
mechanochemical
methods
with
innovative
solvent-free
vibratory
techniques,
we
assess
extent
contamination
impact
efficiency.
These
findings
provide
new
insights
into
how
influences
processes
offer
valuable
guidance
for
optimizing
these
forward-looking
green
methodologies.
Journal of the American Chemical Society,
Journal Year:
2022,
Volume and Issue:
144(34), P. 15413 - 15430
Published: July 26, 2022
Since
its
inception,
atom
transfer
radical
polymerization
(ATRP)
has
seen
continuous
evolution
in
terms
of
the
design
catalyst
and
reaction
conditions;
today,
it
is
one
most
useful
techniques
to
prepare
well-defined
polymers
as
well
notable
examples
catalysis
polymer
chemistry.
This
Perspective
highlights
fundamental
advances
ATRP
reactions
catalysts,
focusing
on
crucial
role
that
mechanistic
studies
play
understanding,
rationalizing,
predicting
outcomes.
A
critical
summary
traditional
systems
provided
first;
we
then
focus
recent
developments
improve
selectivity,
control
polymerizations
via
external
stimuli,
employ
new
photochemical
or
dual
catalytic
with
an
outlook
future
research
directions
open
challenges.
Global Challenges,
Journal Year:
2023,
Volume and Issue:
8(2)
Published: Dec. 30, 2023
Abstract
Metal‐organic
frameworks
(MOFs)
that
are
the
wonder
material
of
21st
century
consist
metal
ions/clusters
coordinated
to
organic
ligands
form
one‐
or
more‐dimensional
porous
structures
with
unprecedented
chemical
and
structural
tunability,
exceptional
thermal
stability,
ultrahigh
porosity,
a
large
surface
area,
making
them
an
ideal
candidate
for
numerous
potential
applications.
In
this
work,
recent
progress
in
design
synthetic
approaches
MOFs
explore
their
applications
fields
gas
storage
separation,
catalysis,
magnetism,
drug
delivery,
chemical/biosensing,
supercapacitors,
rechargeable
batteries
self‐powered
wearable
sensors
based
on
piezoelectric
triboelectric
nanogenerators
summarized.
Lastly,
work
identifies
present
challenges
outlines
future
opportunities
field,
which
can
provide
valuable
references.
Progress in Polymer Science,
Journal Year:
2024,
Volume and Issue:
151, P. 101805 - 101805
Published: Feb. 22, 2024
Polyurethanes
(PU)
are
ranked
amongst
the
6th
most
manufactured
worldwide
polymers
and
widely
used
in
a
variety
of
applications
due
to
diversity
properties
they
offer.
Nevertheless,
PUs
raising
questions
around
environmental,
legislative,
health,
recycling
concerns.
In
this
context,
high
isocyanate
toxicity,
blocked
isocyanates,
waterborne
PU
systems,
non-isocyanate
polyurethane
(NIPU)
were
introduced
prevent
handling
risks.
Moreover,
sustainable
feedstocks
stood
out
synthetize
greener
PU.
particular,
bio-based
polyfunctional
short
alcohol
compounds
have
emerged
design
fully
materials
with
targeted
chemical
mechanical
properties.
Finally,
large
amounts
that
been
placed
on
market
now
leading
environmental
issues
regarding
its
accumulation
environment.
Several
methods
thus
recently
developed
facilitate
their
end-of-life
management
recyclability.
This
review
provides
complete
overview
recent
advances
synthesis
focus
replacement
toxic
isocyanates
petroleum-based
resources,
use
processes,
methods.
After
quick
summary
history
situation,
different
alcohols
academic
industrial
sides,
corresponding
outlined.
Furthermore,
pathways
produce
NIPUs
discussed.
enzymatic
Angewandte Chemie International Edition,
Journal Year:
2023,
Volume and Issue:
62(44)
Published: April 28, 2023
Mechanochemistry
provides
an
environmentally
benign
platform
to
develop
more
sustainable
chemical
processes
by
limiting
raw
materials,
energy
use,
and
waste
generation
while
using
physically
smaller
equipment.
A
continuously
growing
research
community
has
steadily
showcased
examples
of
beneficial
mechanochemistry
applications
at
both
the
laboratory
preparative
scale.
In
contrast
solution-based
chemistry,
mechanochemical
have
not
yet
been
standardized,
thus
scaling
up
is
still
a
nascent
discipline.
The
purpose
this
Minireview
highlight
similarities,
differences
challenges
various
approaches
that
successfully
applied
for
range
scales.
We
hope
provide
discussion
starting
point
those
interested
in
further
developing
commercial
use
and/or
industrialisation.
Advanced Synthesis & Catalysis,
Journal Year:
2023,
Volume and Issue:
365(24), P. 4359 - 4391
Published: Nov. 7, 2023
Abstract
Amide
bond
construction
has
garnered
significant
interest
in
recent
decades
due
to
amides
being
one
of
the
most
prevalent
functional
groups
among
bioactive
molecules.
Out
thirty‐seven
new
drugs
approved
by
FDA
2022,
eleven
are
small
molecules
containing
at
least
amide
bond.
Additionally,
there
nineteen
large
as
drugs,
some
which
have
peptide
structures,
and
therefore,
also
bear
bonds.
In
years,
multiple
teams
embraced
challenge
developing
more
efficient
methods
for
formation.
This
dedication
led
numerous
publications
appearing
monthly
prestigious
journals,
showcasing
advancements
this
field.
The
primary
goal
review
is
present
viable
strategies
constructing
It
crucial
differentiate
between
formation
synthesis;
hence,
focus
on
describing
specific
forming
C(O)−N
particular,
concentrates
developed
within
last
six
years.
There
a
particular
emphasis
approaches
that
consider
thought
process
when
selecting
starting
materials
groups.
approach
ensures
coverage
all
common
chemical
transformations
yield
Green Chemistry,
Journal Year:
2024,
Volume and Issue:
26(5), P. 2476 - 2504
Published: Jan. 1, 2024
Hypercrosslinked
polymers
and
the
resultant
carbon
materials
are
promising
platforms
for
CO
2
capture
conversion,
because
of
their
high
specific
surface
areas,
modifiable
accessible
functionalities.
Progress in Materials Science,
Journal Year:
2024,
Volume and Issue:
145, P. 101299 - 101299
Published: April 16, 2024
Electrochemistry-driven
techniques
for
advanced
energy
storage/conversion
and
environmental
protection
play
a
crucial
role
in
achieving
sustainable
development
goals.
As
an
indispensable
component
diverse
electrochemical
systems,
electroactive
materials
gain
soaring
interest
terms
of
rational
design
synthesis.
Notably,
mechanochemistry-based
green
powerful
synthesis
has
been
widely
employed
to
fabricate
materials,
given
their
scalability
tunability.
Recently,
mechanochemically
synthesized
have
applied
various
fields,
leading
significant
progress.
However,
systematic
analysis
these
advancements
is
still
missing.
Herein,
we
comprehensively
discuss
recent
achievements
mechanosynthesized
applications.
The
mechanochemical
introduced,
along
with
different
types
materials.
Subsequently,
the
review
delves
into
applications
conversion/storage
systems
remediation.
structure-performance
correlation
are
illustrated
by
discussing
effects
process
on
internal
external
properties
performance.
Lastly,
key
perspectives
this
field
discussed,
including
monitoring,
field-assisted
synthesis,
material
performance
optimization,
practical
applications,
mechanochemistry-driven
fuels/chemicals
By
illustrating
current
advances
related
aims
shed
some
light
upcoming
research
synthesis-driven
sustainability.
Angewandte Chemie International Edition,
Journal Year:
2024,
Volume and Issue:
63(14)
Published: Jan. 5, 2024
Abstract
Mechanochemical
reactions
offer
methodological
and
environmental
advantages
for
chemical
synthesis,
constantly
attracting
attention
within
the
scientific
community.
Besides
unmistakable
sustainability
advantages,
conditions
under
which
mechanochemical
occur,
namely
solventless
conditions,
sometimes
facilitate
isolation
of
otherwise
labile
or
inaccessible
products.
Despite
these
limited
knowledge
exists
regarding
mechanisms
types
intermediates
involved.
Nevertheless,
in
an
expanding
number
cases,
ex
situ
monitoring
techniques
have
allowed
observation,
characterization,
reaction
transformations.
In
this
Minireview,
we
present
a
series
examples
reactive
been
detected
spanning
organic,
organometallic,
inorganic,
materials
chemistry.
Many
were
stabilized
by
non‐covalent
interactions,
played
pivotal
role
guiding
We
believe
that
uncovering
understanding
such
instances,
growing
mechanochemistry
community
could
find
novel
opportunities
catalysis
discover
new
while
achieving
simplification
design.
Polymer Journal,
Journal Year:
2024,
Volume and Issue:
56(4), P. 249 - 268
Published: Jan. 12, 2024
Abstract
Over
8
billion
tons
of
plastic
have
been
produced
to
date,
and
a
100%
reclamation
recycling
strategy
is
not
foreseeable.
This
review
summarizes
how
the
mechanochemistry
polymers
may
contribute
sustainable
polymer
future
by
controlling
degradation
only
de
novo
developed
designer
but
also
plastics
in
existing
waste
streams.
The
historical
development
presented
while
highlighting
current
examples
mechanochemically
induced
degradation.
Additionally,
theoretical
computational
frameworks
are
discussed
that
lead
discovery
better
understanding
new
mechanochemical
reactions
future.
takes
into
account
technical
engineering
perspectives
converging
fields
trituration
with
particular
focus
on
fate
commodity
potential
technologies
monitor
they
occur.
Therefore,
unique
perspective
multiple
communities
presented,
need
for
transdisciplinary
research
tackle
high-leverage
parameters
governing
an
eventually
successful
approach
circular
economy.
