Electro-organic synthesis: an environmentally benign alternative for heterocycle synthesis DOI
Suman Devi,

Jyoti,

KIRAN KIRAN

et al.

Organic & Biomolecular Chemistry, Journal Year: 2022, Volume and Issue: 20(26), P. 5163 - 5229

Published: Jan. 1, 2022

In recent years, there has been a gradual shift from traditional methodologies to electrochemically mediated organic synthesis. The present review outlines the utility of strategies in heterocylic

Language: Английский

Photo-/electrocatalytic functionalization of quinoxalin-2(1H)-ones DOI
Kai Sun, Fang Xiao, Bing Yu

et al.

CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION), Journal Year: 2021, Volume and Issue: 42(11), P. 1921 - 1943

Published: Aug. 30, 2021

Language: Английский

Citations

137
Visible-light-initiated 4CzIPN catalyzed multi-component tandem reactions to assemble sulfonated quinoxalin-2(1H)-ones DOI
Zhiwei Wang, Qishun Liu,

Ruisheng Liu

et al.

Chinese Chemical Letters, Journal Year: 2021, Volume and Issue: 33(3), P. 1479 - 1482

Published: Aug. 12, 2021

Language: Английский

Citations

132
Recent developments in the difunctionalization of alkenes with C–N bond formation DOI
Xiang Chen, Fang Xiao, Wei‐Min He

et al.

Organic Chemistry Frontiers, Journal Year: 2021, Volume and Issue: 8(18), P. 5206 - 5228

Published: Jan. 1, 2021

Various alkene difunctionalization reactions involving nitridization, diamination, azidation, oxyamination, carboamination, aminohalogenation, and nitration are introduced in this review.

Language: Английский

Citations

128
Choline chloride–ethylene glycol based deep-eutectic solvents as lixiviants for cobalt recovery from lithium-ion battery cathode materials: are these solvents really green in high-temperature processes? DOI Creative Commons
Nand Peeters, K. Janssens, Dirk De Vos

et al.

Green Chemistry, Journal Year: 2022, Volume and Issue: 24(17), P. 6685 - 6695

Published: Jan. 1, 2022

Deep-eutectic solvents (DESs) are often considered to be safe, eco-friendly and non-toxic solvents. Due these green credentials, they increasingly being studied for application in metal recycling processes. One example is their use as lixiviants the recovery of cobalt from lithium oxide (LiCoO

Language: Английский

Citations

87
EtOH-catalyzed electrosynthesis of imidazolidine-fused sulfamidates fromN-sulfonyl ketimines,N-arylglycines and formaldehyde DOI
Yuhan Lu,

Si‐Yu Mu,

Hongxia Li

et al.

Green Chemistry, Journal Year: 2023, Volume and Issue: 25(14), P. 5539 - 5542

Published: Jan. 1, 2023

With formaldehyde as an atom-economical carbonyl synthon, the EtOH-catalyzed electrochemical multicomponent synthesis of various imidazolidine-fused sulfamidates under organic oxidant-free, energy-saving and mild conditions was developed.

Language: Английский

Citations

50
Recent Advances and Perspectives on Coupled Water Electrolysis for Energy‐Saving Hydrogen Production DOI Creative Commons
Jiachen Li,

Yuqiang Ma,

Xiaogang Mu

et al.

Advanced Science, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 7, 2025

Abstract Overall water splitting (OWS) to produce hydrogen has attracted large attention in recent years due its ecological‐friendliness and sustainability. However, the efficiency of OWS been forced by sluggish kinetics four‐electron oxygen evolution reaction (OER). The replacement OER alternative electrooxidation small molecules with more thermodynamically favorable potentials may fundamentally break limitation achieve production low energy consumption, which also be accompanied value‐added chemicals than or electrochemical degradation pollutants. This review critically assesses latest discoveries coupled various OWS, including alcohols, aldehydes, amides, urea, hydrazine, etc. Emphasis is placed on corresponding electrocatalyst design related mechanisms (e.g., dual hydrogenation N–N bond breaking hydrazine C═N regulation urea inhibit hazardous NCO − NO productions, etc.), along emerging reactions (electrooxidation tetrazoles, furazans, iodide, quinolines, ascorbic acid, sterol, trimethylamine, etc.). Some new decoupled electrolysis self‐powered systems are discussed detail. Finally, potential challenges prospects highlighted aid future research directions.

Language: Английский

Citations

3
Electrochemical regioselective synthesis of N-substituted/unsubstituted 4-selanylisoquinolin-1(2H)-ones DOI

Zhilin Wu,

Jinyang Chen,

Xian-Zhi Tian

et al.

Chinese Chemical Letters, Journal Year: 2021, Volume and Issue: 33(3), P. 1501 - 1504

Published: Aug. 19, 2021

Language: Английский

Citations

79
TBAI/H2O-cooperative electrocatalytic decarboxylation coupling-annulation of quinoxalin-2(1H)-ones with N-arylglycines DOI
Yuhan Lu,

Zhuo-Tao Zhang,

Hongyu Wu

et al.

Chinese Chemical Letters, Journal Year: 2022, Volume and Issue: 34(7), P. 108036 - 108036

Published: Dec. 5, 2022

Language: Английский

Citations

64
Visible‐Light Photosynthesis of CHF2/CClF2/CBrF2‐Substituted Ring‐fused Quinazolinones in Dimethyl Carbonate DOI
Qingwen Gui, Fan Teng, Hao Yang

et al.

Chemistry - An Asian Journal, Journal Year: 2021, Volume and Issue: 17(1)

Published: Nov. 26, 2021

With eco-friendly and sustainable CO2 -derived dimethyl carbonate as the sole solvent, visible-light-induced cascade radical reactions have been established a green efficient tool for constructing various CHF2 /CClF2 /CBrF2 -substituted ring-fused quinazolinones.

Language: Английский

Citations

59
Direct para-C–H heteroarylation of anilines with quinoxalinones by metal-free cross-dehydrogenative coupling under an aerobic atmosphere DOI
Jun Xu, Lin Huang, Lei He

et al.

Green Chemistry, Journal Year: 2021, Volume and Issue: 23(17), P. 6632 - 6638

Published: Jan. 1, 2021

This study demonstrates a metal-free cross-dehydrogenative coupling for direct para -C–H heteroarylation of anilines with quinoxalinones using air as the sole oxidant and H 2 O/DMSO solvent.

Language: Английский

Citations

57