Cited by Radical coupling reactions of hydrazines<i>via</i>photochemical and electrochemical strategies

Hexamethyldisilazane Lithium (LiHMDS)-Promoted Hydroboration of Alkynes and Alkenes with Pinacolborane DOI

Jichao Liu,

Caiyan Wu,

Tinghui Hu

et al.

The Journal of Organic Chemistry, Journal Year: 2022, Volume and Issue: 87(5), P. 3442 - 3452

Published: Feb. 10, 2022

Lithium-promoted hydroboration of alkynes and alkenes using commercially available hexamethyldisilazane lithium as a precatalyst HBpin hydride source has been developed. This method will be appealing for organic synthesis because its remarkable substrate tolerance good yields. Mechanistic studies revealed that the proceeds through in situ-formed BH3 species, which acts to drive turnover alkenes.

Language: Английский

Citations

Advances in the photoredox catalysis of S(VI) compounds DOI

V. R. Padma Priya,

N. Karthikeyan,

Ganesh Chandra Nandi

et al.

Tetrahedron, Journal Year: 2022, Volume and Issue: 111, P. 132711 - 132711

Published: March 2, 2022

Language: Английский

Citations

Transition‐Metal‐Free Heterocyclic Carbon‐Boron Bond Formation DOI

Subrata Hazra,

Somenath Mahato,

Kanak Kanti Das

et al.

Chemistry - A European Journal, Journal Year: 2022, Volume and Issue: 28(44)

Published: April 19, 2022

Abstract Heteroaryl boronic acids and esters are extremely important valuable intermediates because of their wide application in the synthesis marketed drugs bioactive compounds. Over last couple decades, construction highly heteroaryl carbon‐boron bonds has created huge attention. The transition‐metal‐free protocols more green, less sensitive to air moisture, also economically advantageous over transition‐metal‐based protocols. C−H borylation heteroarenes C−X (X=halogen) halides represents an excellent approach for synthesis. Also, various cyclization alkyne activation have been recently established goal this review article is summarize existing literature current state art acid esters.

Language: Английский

Citations

Reductive Activation of Aryl Chlorides by Tuning the Radical Cation Properties of N‐Phenylphenothiazines as Organophotoredox Catalysts DOI

Fabian Weick,

Nina Hagmeyer,

M. Giraud

et al.

Chemistry - A European Journal, Journal Year: 2023, Volume and Issue: 29(66)

Published: Aug. 17, 2023

Aryl chlorides as substrates for arylations present a particular challenge photoredox catalytic activation due to their strong C(sp2 )-Cl bond and reduction potential. Electron-rich N-phenylphenothiazines, organophotoredox catalysts, are capable of cleaving aryl simply by photoinduced electron transfer without the need an additional electrochemical setup or any other advanced photocatalysis technique. Due extremely potential in excited state N-phenylphenothiazines substrate scope is high includes both with electron-withdrawing electron-donating substituents. We evidence this reactivity photocatalytic borylations phosphonylations. Advanced time-resolved transient absorption spectroscopy combination electrochemistry was key elucidating comparing unusual photophysical properties not only but also cation radicals central intermediates cycle. The revealed photophysics allowed excited-state radical-cation be fine-tuned molecular design N-phenylphenothiazines; improved activity.

Language: Английский

Citations

Radical coupling reactions of hydrazinesviaphotochemical and electrochemical strategies DOI

Yilin Kong,

Kangning Wei, Guobing Yan

et al.

Organic Chemistry Frontiers, Journal Year: 2022, Volume and Issue: 9(21), P. 6114 - 6128

Published: Jan. 1, 2022

Hydrazines are versatile building blocks in organic synthesis.

Language: Английский

Citations