Cu-Catalysed sustainable synthesis of formamide with glycerol derivatives as a carbonyl source via a radical-relay mechanism DOI
Xingchao Dai, Xinzhi Wang, Carsten Kreyenschulte

et al.

Green Chemistry, Journal Year: 2023, Volume and Issue: 25(4), P. 1464 - 1472

Published: Jan. 1, 2023

N -Formylation of amines to formamides was achieved at a low temperature by total utilization the carbon atoms glycerol derivatives as C 1 feedstock over CuZr/5A via ˙OH–˙OOH radical mechanism.

Language: Английский

Ruthenium Complexes with NNN-Pincer Ligands for N-Methylation of Amines Using Methanol DOI

Mengxuan Bai,

Shengxin Zhang,

Zhengguo Lin

et al.

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(25), P. 11821 - 11831

Published: June 7, 2024

A series of ruthenium complexes (Ru1–Ru4) bearing new NNN-pincer ligands were synthesized in 58–78% yields. All the are air and moisture stable characterized by IR, NMR, high-resolution mass spectra (HRMS). In addition, structures Ru1–Ru3 confirmed X-ray crystallographic analysis. These Ru(II) exhibited high catalytic efficiency broad functional group tolerance N-methylation reaction amines using CH3OH as both C1 source solvent. Experimental results indicated that electronic effect substituents on considerably affects reactivity which Ru3 an electron-donating OMe showed highest activity. Deuterium labeling control experiments suggested dehydrogenation methanol to generate hydride species was rate-determining step reaction. Furthermore, this protocol also provided a ready approach versatile trideuterated N-methylamines under mild conditions CD3OD deuterated methylating agent.

Language: Английский

Citations

5
Direct use of methanol instead of formaldehyde or paraformaldehyde: Acceptorless dehydrogenative coupling for the synthesis of arylhydrazones catalyzed by a metal–ligand iridium bifunctional catalyst DOI
Beixuan Dong,

Yiqian He,

Xiangchao Xu

et al.

Journal of Catalysis, Journal Year: 2024, Volume and Issue: 438, P. 115685 - 115685

Published: Aug. 3, 2024

Language: Английский

Citations

5
Methanol as a greener C1 synthon under non-noble transition metal-catalyzed conditions DOI

S.P. Anjali Devi,

Pushkar Mehara, Pralay Das

et al.

Coordination Chemistry Reviews, Journal Year: 2022, Volume and Issue: 475, P. 214851 - 214851

Published: Oct. 14, 2022

Language: Английский

Citations

21
Life cycle water footprint and carbon footprint analysis of municipal sludge plasma gasification process DOI
Peizhe Cui,

Zaifeng Xu,

Dong Yao

et al.

Energy, Journal Year: 2022, Volume and Issue: 261, P. 125280 - 125280

Published: Aug. 30, 2022

Language: Английский

Citations

20
Iridium-, Ruthenium-, and Nickel-Catalyzed C–C Couplings of Methanol, Formaldehyde, and Ethanol with π-Unsaturated Pronucleophiles via Hydrogen Transfer DOI
Cole C. Meyer, Michael J. Krische

The Journal of Organic Chemistry, Journal Year: 2022, Volume and Issue: 88(8), P. 4965 - 4974

Published: Nov. 30, 2022

In this Perspective, the use of methanol and ethanol as C1 C2 feedstocks in metal-catalyzed C-C couplings to π-unsaturated pronucleophiles via hydrogen auto-transfer is surveyed. these processes, alcohol oxidation form an aldehyde electrophile balanced by reduction hydrocarbon a transient organometallic nucleophile. Mechanistically related reductive paraformaldehyde mediated reductants or formic acid also are described. These processes encompass first catalytic enantioselective and, more broadly, illustrate how native reducing ability alcohols enable departure from premetalated reagents carbonyl addition.

Language: Английский

Citations

19
Aerobic Oxidative Synthesis of Formamides from Amines and Bioderived Formyl Surrogates DOI Creative Commons
Xingchao Dai, Yunyan Han, Haijun Jiao

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(26)

Published: April 3, 2024

Herein we present a new strategy for the oxidative synthesis of formamides from various types amines and bioderived formyl sources (DHA, GLA GLCA) molecular oxygen (O

Language: Английский

Citations

4
3d Transition Metal Complexes as Homogeneous Catalysts in N-Alkylation Reactions Using Alcohols: A Recent Update DOI

Jharna Mahato,

Rima Das,

Tanmoy Saha

et al.

Tetrahedron, Journal Year: 2024, Volume and Issue: 165, P. 134192 - 134192

Published: Aug. 13, 2024

Language: Английский

Citations

4
NNN-Ru complexes catalyzed β-methylation of alcohols using methanol via borrowing hydrogen approach DOI

Mengxuan Bai,

Ziying Zhong, Zhiqiang Hao

et al.

Journal of Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 116026 - 116026

Published: Feb. 1, 2025

Language: Английский

Citations

0
Mild oxidative N-formylation of amines with biobased glycolaldehyde over C3N4 supported Cu catalyst under green solvent DOI
Xingchao Dai, Yunyan Han, Haijun Jiao

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: 508, P. 160963 - 160963

Published: Feb. 27, 2025

Language: Английский

Citations

0
Recent advances on non-precious metal-catalyzed C–H functionalization of N-heteroarenes DOI
Atanu Bera, Lalit Mohan Kabadwal, Sourajit Bera

et al.

Chemical Communications, Journal Year: 2021, Volume and Issue: 58(1), P. 10 - 28

Published: Nov. 18, 2021

N-Heteroarenes are widely used for numerous medicinal applications, lifesaving drugs and show utmost importance as intermediates in chemical synthesis. This feature article highlights the recent advances, from 2015 to August 2021, on sp2 sp3 C-H bond functionalization reactions of various N-heteroarenes catalyzed by non-precious transition metals (Mn, Co, Fe, Ni, etc.). The salient features report are: (i) development newer catalysis Csp2-H activation categorized into alkylation, alkenylation, borylation, cyanation, annulation reactions, (ii) advances Csp3-H considering approaches alkylation well alkenylation processes, (iii) synthetic applications practical utility catalytic protocols utilized late-stage drug development; (iv) scope along with mechanistic studies detail findings important processes.

Language: Английский

Citations

27