Inorganic Chemistry,
Journal Year:
2024,
Volume and Issue:
63(12), P. 5295 - 5314
Published: March 15, 2024
"Homoleptic"
tetracoordinate
boron
compounds,
in
which
the
central
atom
links
to
four
identical
atoms,
are
a
special
and
important
family
of
compounds.
During
past
decades,
they
have
been
extensively
employed
inorganic,
organic,
macromolecular,
materials
chemistry.
Many
them
exhibit
diverse
range
outstanding
properties,
therefore,
synthesis
application
those
compounds
emerged
as
hot
research
topic
modern
This
review
summarizes
discusses
"homoleptic"
organized
according
kinds
atoms
coordinated
boron.
Organic Letters,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Dec. 17, 2024
The
development
of
chiral
BODIPYs
attracts
remarkable
interest
due
to
their
unique
properties,
structural
diversity,
and
good
photochemical
stability,
whereas
achieving
the
construction
maintains
scarce.
Herein,
we
present
an
enantioselective
synthesis
axially
through
Suzuki-Miyaura
coupling.
newly
synthesized
coassembly
showed
desirable
photophysical
including
high
fluorescence
quantum
yields
intense
CPL,
both
in
solution
solid
state.
Organic Letters,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 2, 2025
Domino
cascade
reactions,
which
can
construct
multiple
bonds
in
one
pot,
are
efficient
methods
to
synthesize
N-heterocycles
and
other
useful
skeletons.
Herein,
we
report
an
expedient
synthesis
of
polysubstituted
benzo[b][1,5]naphthyridine
via
Mn(III)-mediated
C–C
bond
cleavage
cyclopropanols.
These
reactions
were
initiated
by
addition
β-carbonyl
radicals,
generated
from
cyclopropyl
alcohols
the
presence
Mn(III),
2-(2-isocyanophenyl)acetonitriles
give
quinolin-3-amines,
went
through
intramolecular
cyclizations
dehydrogenation
final
products.
JACS Au,
Journal Year:
2025,
Volume and Issue:
5(4), P. 1965 - 1973
Published: April 2, 2025
The
precise
construction
of
boron
stereogenic
centers
represents
a
significant,
yet
challenging
frontier
in
asymmetric
catalysis,
garnering
growing
attention
recent
years.
However,
feasible
catalysis
has
primarily
been
limited
to
transition-metal-catalyzed
desymmetrization
pro-chiral
BODIPY
molecules,
while
enantioselective
synthesis
via
organocatalysis
remains
unexplored.
Herein,
we
achieve
an
organocatalyzed
C-N
bond-forming
SNAr
reaction
3,5-dihalogen
BODIPYs
phase-transfer
enabling
the
efficient
broad
range
boron-stereogenic
with
excellent
enantioselectivities
(>40
examples,
up
99%
ee).
significance
and
potential
this
catalytic
approach
are
further
underscored
by
versatile
applications
enantioenriched
3-amide
synthesis,
optical
activity
regulation,
bioimaging,
sensing,
promoting
development
fluorophores.
Advanced Optical Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 4, 2025
Abstract
Circularly
polarized
luminescence
(CPL)
materials
have
attracted
significant
attention
owing
to
their
unique
luminescent
properties
and
broad
range
of
applications.
However,
challenges
remain,
including
controlling
helical
assembly,
mitigating
aggregation‐caused
quenching,
balancing
quantum
yield
(
Φ
PL
)
with
g
values.
Here,
the
study
reports
synthesis
a
novel
asymmetric,
spiranic
O‐organoboranes
bearing
isoindolyl‐indolenine
scaffold
(BBI)
axial
chirality
through
BINOL
substitution,
as
well
its
supramolecular
assembly
surfactant‐regulated
tunable
CPL
behaviors.
The
newly
designed
BBI
dye
shows
relative
weak
10%
in
toluene.
Supramolecular
acetonitrile/water
co‐solvents
exhibit
an
obvious
aggregation‐induced
emission
(AIE)
process,
leading
formation
spherical
nanostructures
red‐shifted
orange‐yellow
(554
nm,
=
0.012,
7%).
Moreover,
surfactant
sodium
dodecyl
sulfonate
(SDS)
can
promote
aggregation
pure
deionized
water,
producing
nanofibers
blue‐shifted
yellow
(536
0.006,
13%).
Crystal
growth
toluene/hexane
SDS
aqueous/acetonitrile
systems
reveals
chiral
crystals
P
212121
space
group,
offering
insights
into
amplification.
This
demonstrates
ability
precisely
control
parameters,
X‐ray
single‐crystal
analysis
providing
additional
understanding
regulation.
Chemical Science,
Journal Year:
2024,
Volume and Issue:
15(19), P. 7130 - 7135
Published: Jan. 1, 2024
Chiral
phosphorus-containing
compounds
find
applications
across
various
fields,
including
asymmetric
catalysis,
medicinal
chemistry,
and
materials
science.
Angewandte Chemie International Edition,
Journal Year:
2024,
Volume and Issue:
unknown
Published: July 19, 2024
Abstract
Heteroatom‐embedded
helical
nanographenes
(NGs)
constitute
an
important
and
appealing
class
of
intrinsically
chiral
materials.
In
this
work,
a
series
B,N‐embedded
NGs
(BN‐HNGs)
bearing
azepines
was
synthesized
via
stepwise
regioselective
cyclodehydrogenation.
First,
the
phenyl‐
or
nitrogen‐bridged
dimers
were
efficiently
clipped
into
highly
congested
model
compounds
1
2
.
Later,
controllable
Scholl
reactions
tetraphenyl‐tethered
precursor
generated
1,
7
8
new
C−C
bonds,
thereby
establishing
robust
method
for
preparation
nonalternant
BN‐HNGs
with
up
to
31
fused
rings.
The
bilayer
nature
unambiguously
verified
by
X‐ray
diffraction
analysis.
chirality
transferred
stereogenic
boron
centers
upon
fluoride
coordination,
concave‐concave
structure
comply
skeleton.
Notably,
largest
BN‐HNG
(
6
)
spontaneously
resolved
homochiral
4
helix
as
molecular
spiral
staircase
during
crystallization
conglomerate
formation
at
single‐crystal
scale.
large
twisted
C
‐symmetric
π‐surface
dynamic
skeleton
induced
curved
might
have
synergistic
effects
on
self‐recognition
enantiomers
achieve
intriguing
spontaneous
resolution
behavior.
chiroptical
properties
enantiomer
further
investigated,
revealing
that
had
strong
response
in
visible
range
(400–700
nm).
