A comprehensive review on the advancements and challenges in perovskite solar cell technology

RSC Advances, Journal Year: 2024, Volume and Issue: 14(8), P. 5085 - 5131

Published: Jan. 1, 2024

This review provides an overview of the progress & developments PSCs, beginning with introduction to their fundamental properties significance. It discusses various types highlighting unique attributes performance metrics.

Language: Английский

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Significance of Formamidinium Incorporation in Perovskite Composition and Its Impact on Solar Cell Efficiency: A Mini‐Review

Advanced Energy and Sustainability Research, Journal Year: 2024, Volume and Issue: 5(8)

Published: April 26, 2024

Perovskite solar cells (PSCs) have gained tremendous research interest recently owing to several advantages, including low material cost, facile solution processability, bandgap tunability, and alluring device efficiency. The organic formamidinium (FA) cation‐based perovskites are mainly considered as one of the potential candidates for charge carrier generation due their excellent properties, such thermal stability than traditional perovskites. However, inevitable unfavorable polymorphism (i.e., α δ ) at room temperature still forms basis numerous works allow fabrication a high‐quality absorber enhances PSCs performance. studies resolve contemporary techniques (e.g., passivation strategy) with recent novel methods presented in this review form essence improvements PSCs. morphology also influences charge‐transfer behavior device's lifetime. Therefore, understanding these properties is essential improve quality avoid many defects. This focuses on structure pure mixed FA various halides, cation's role composition. And comprehensive overview double, triple, quadrupole results proper scientific explanations understand physics.

Language: Английский

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Heterocyclic and heteropolycyclic moieties in organic hole transport materials for perovskite solar cells: Design, synthesis, and performance

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 532, P. 216500 - 216500

Published: Feb. 20, 2025

Language: Английский

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Tailoring interface and morphology of TiO2 electron transport layer with potassium bitartrate for high-performance perovskite solar cells

Applied Surface Science, Journal Year: 2024, Volume and Issue: 662, P. 160139 - 160139

Published: April 21, 2024

Language: Английский

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Danger in the Dark: Stability of Perovskite Solar Cells with Varied Stoichiometries and Morphologies Stressed at Various Conditions

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(21), P. 27450 - 27462

Published: May 16, 2024

The long-term stability of perovskite solar cells (PSCs) remains a bottleneck for commercialization. While studies on the stoichiometry and morphology PSCs with regard to performance are prevalent, understanding influence these factors their is lacking. In this work, we evaluate impact cesium formamidinium-based PSCs. We demonstrate that lead iodide (PbI2) formamidinium (FAI) ratio influences under various stress (elevated temperature light). A high molar (PbI2/FAI > 1.1) in precursor displays drastic degradation ISOS-L1 (100 mW/cm2, 25 °C, maximum power point tracking) conditions. However, postdegradation analysis contradicts results. Devices PbI2/FAI ≤ 1.1 stable light, but intermittent current density-voltage characterizations indicate device decreases during storage dark. Migration (I-) ions electron-transport layer (ETL) iodine vacancies (VI-+) hole-transport (HTL) forms localized shunts absorber layer. Pinhole formation, surrounded by FA+-rich regions, explains extent damage comparably aged films. summary, work emphasizes importance reporting different conditions, coupled dark recovery analyses better understand complexities instability real-life conditions such as expected outdoor operation.

Language: Английский

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Rational Tailored Polyfluorosubstituted Amide Molecule for Stabilizing PbI₆ Framework and Inhibiting Ion Migration Toward Highly Efficient and Stable Perovskite Solar Cells

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 2, 2024

Abstract Perovskite solar cells (PSCs), while highly efficient, face stability challenges that hinder their commercial application. These instability issues mainly arise from the fragile nature of Pb─I bonds in perovskites, which easily break under environmental stresses such as heat and light, leading to breakdown [PbI 6 ] framework irreversible degradation. To address these issues, a multifunctional molecule, N 1 ,N 4 ‐bis(2,3,5,6‐tetrafluoro‐4‐iodophenyl)terephthalamide (FIPh‐A), is designed synthesized enhance perovskite films devices. FIPh‐A molecule possesses carbonyl, amino, iodotetrafluorophenyl groups bind stabilize Pb 2+ ions 4− octahedra structure, preventing ion migration films. The activation energy increases obviously 0.28 eV 0.39 by adding verified experiment results. residual strain also released efficiently introducing into characterized grazing incidence X‐ray diffraction. champion PSC with achieves power conversion efficiency 24.60%. After 500 h continuous illumination (ISOS‐L‐1) 300 thermal aging at 80 °C (ISOS‐D‐2I), PSCs maintained 93% 77% initial efficiency, respectively. results emphasize potential additives overcoming PSCs, thereby facilitating advancement.

Language: Английский

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Rhodamine B as an efficient multifunctional passivator for the improvement of perovskite solar cell performance

Journal of Materials Chemistry C, Journal Year: 2023, Volume and Issue: 11(27), P. 9189 - 9200

Published: Jan. 1, 2023

Multifunctional RhB is applied for the passivation of defects in perovskite films, decreasing defect density, suppressing ionic migration and forming extra interface electric field. The PCE a modified PSC with improved stability increased from 18.79% to 20.70%.

Language: Английский

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Inhibition of ion diffusion/migration in perovskite p–n homojunction by polyetheramine insert layer to enhance stability of perovskite solar cells with p–n homojunction structure

Nanoscale, Journal Year: 2024, Volume and Issue: 16(13), P. 6669 - 6679

Published: Jan. 1, 2024

The introduction of PEA insert layer effectively mitigates the degradation perovskite homojunction caused by diffusion and migration ions between n-type p-type layers.

Language: Английский

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Six‐Month Outdoor Performance Study of Stable Perovskite Solar Cells under Real Operating Conditions

Solar RRL, Journal Year: 2024, Volume and Issue: 8(11)

Published: May 13, 2024

Perovskite solar cells (PSCs) have sparked great excitement in the photovoltaics community due to their remarkable efficiency, flexibility, and ability be synthesized at low cost. However, instability poses a major roadblock widespread adoption. Recognizing this challenge, work describes performance of stable PSCs operating under real‐life conditions Paris area. Two state‐of‐the‐art 2D/3D (HOOC(CH 2 ) 4 NH 3 )2PbI /CH PbI encapsulated are considered—one with maximum power point tracking hourly current–voltage curve measurements, another connected fixed resistive load. Their is compared over six months, detailed analysis conducted on cells’ hysteresis electrical response varying weather conditions. Although first cell starts degrade after few months operation, second one remains remarkably stable, highlighting critical issues outdoor tracking. Given that stability PSC architecture has already been established controlled standard for year, these exciting findings pave way commercialization perovskite‐based photovoltaic devices.

Language: Английский

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Pyridine-Anchored Small Molecule Interlayer Enables Defect Passivation and Enhanced Carrier Transport for Perovskite Solar Cells

The Journal of Physical Chemistry Letters, Journal Year: 2024, Volume and Issue: 15(35), P. 8949 - 8955

Published: Aug. 26, 2024

Engineering of the interface between perovskite and hole transport layer (HTL) has been crucial to achieving high performance. In this study, two interfacial materials, MN-CZ CN-CZ, are designed by systematically regulating group substitution site study relationship spatial conformation passivation effect. The groups CN-CZ molecules exhibit a stronger "vector addition" effect, resulting in larger molecular dipoles enhanced defect energy level regulation effects. Consequently, CN-CZ-based solar cell (PSC) shows efficiency 23.8%, which is much higher than that reference device. Meanwhile, humidity thermal stability unencapsulated device have significantly improved.

Language: Английский

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