Journal of the American Chemical Society,
Journal Year:
2023,
Volume and Issue:
145(21), P. 11837 - 11845
Published: May 19, 2023
Ultramicroporous
materials
can
be
highly
effective
at
trace
gas
separations
when
they
offer
a
high
density
of
selective
binding
sites.
Herein,
we
report
that
Nature Communications,
Journal Year:
2023,
Volume and Issue:
14(1)
Published: Nov. 2, 2023
Crystalline
porous
materials
such
as
covalent
organic
frameworks
(COFs),
metal-organic
(MOFs)
and
cages
(POCs)
have
been
widely
applied
in
various
fields
with
outstanding
performances.
However,
the
lack
of
general
effective
methodology
for
large-scale
production
limits
their
further
industrial
applications.
In
this
work,
we
developed
a
approach
comprising
high
pressure
homogenization
(HPH),
which
can
realize
synthesis
crystalline
including
COFs,
MOFs,
POCs
under
benign
conditions.
This
universal
strategy,
illustrated
proof
principle
studies,
has
prepared
4
2
POCs.
It
circumvent
some
drawbacks
existing
approaches
low
yield,
energy
consumption,
efficiency,
weak
mass/thermal
transfer,
tedious
procedures,
poor
reproducibility,
cost.
On
basis
approach,
an
homogenizer
produce
0.96
~
580.48
ton
high-performance
per
day,
is
unachievable
via
other
methods.
Journal of the American Chemical Society,
Journal Year:
2023,
Volume and Issue:
145(21), P. 11837 - 11845
Published: May 19, 2023
Ultramicroporous
materials
can
be
highly
effective
at
trace
gas
separations
when
they
offer
a
high
density
of
selective
binding
sites.
Herein,
we
report
that