Luminescent sensing platforms based on lanthanide metal-organic frameworks: Current strategies and perspectives

Coordination Chemistry Reviews, Journal Year: 2023, Volume and Issue: 497, P. 215454 - 215454

Published: Sept. 27, 2023

Language: Английский

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Kirkendall Effect‐Induced Ternary Heterointerfaces Engineering for High Polarization Loss MOF‐LDH‐MXene Absorbers

Small, Journal Year: 2024, Volume and Issue: 20(48)

Published: Aug. 29, 2024

Heterogeneous interfacial engineering has garnered widespread attention for optimizing polarization loss and enhancing the performance of electromagnetic wave absorption. A novel Kirkendall effect-assisted electrostatic self-assembly method is employed to construct a metal-organic framework (MOF, MIL-88A) decorated with Ni-Fe layered double hydroxide (LDH), forming multilayer nano-cage coated Ti

Language: Английский

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Fabrication of Oriented Polycrystalline MOF Superstructures

Advanced Materials, Journal Year: 2023, Volume and Issue: 36(1)

Published: Nov. 28, 2023

Abstract The field of metal‐organic frameworks (MOFs) has progressed beyond the design and exploration powdery single‐crystalline materials. A current challenge is fabrication organized superstructures that can harness directional properties individual constituent MOF crystals. To date, progress in methods polycrystalline led to close‐packed structures with defined crystalline orientation. By controlling orientation, pore channels crystals be aligned along specific directions: these systems possess anisotropic including enhanced diffusion directions, preferential orientation guest species, protection functional guests. In this perspective, we discuss status research oriented focusing on directions Three are examined detail: assembly from colloidal solutions, use external fields for alignment particles, heteroepitaxial ceramic‐to‐MOF growth. This perspective aims at promoting inspiring development new protocols preparation channels, enable advanced MOF‐based devices properties.

Language: Английский

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Crosslinking-induced patterning of MOFs by direct photo- and electron-beam lithography

Nature Communications, Journal Year: 2024, Volume and Issue: 15(1)

Published: April 4, 2024

Abstract Metal-organic frameworks (MOFs) with diverse chemistry, structures, and properties have emerged as appealing materials for miniaturized solid-state devices. The incorporation of MOF films in these devices, such the integrated microelectronics nanophotonics, requires robust patterning methods. However, existing methods suffer from some combinations limited material adaptability, compromised resolution scalability, degraded properties. Here we report a universal, crosslinking-induced approach various MOFs, termed CLIP-MOF. Via resist-free, direct photo- electron-beam (e-beam) lithography, ligand crosslinking chemistry leads to drastically reduced solubility colloidal permitting selective removal unexposed developer solvents. This enables scalable, micro-/nanoscale (≈70 nm resolution), multimaterial MOFs on large-area, rigid or flexible substrates. Patterned preserve their crystallinity, porosity, other tailored targeted applications, diffractive gas sensors electrochromic pixels. combined features CLIP-MOF create more possibilities system-level integration electronic, photonic, biomedical

Language: Английский

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Exploring metal-organic frameworks (MOFs) in drug delivery: A concise overview of synthesis approaches, versatile applications, and current challenges

Applied Materials Today, Journal Year: 2024, Volume and Issue: 41, P. 102443 - 102443

Published: Sept. 21, 2024

Language: Английский

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Research progress in structural regulation and applications of HKUST-1 and HKUST-1 based materials

Journal of Alloys and Compounds, Journal Year: 2023, Volume and Issue: 974, P. 172897 - 172897

Published: Nov. 22, 2023

Language: Английский

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MOF-based micro/nanomotors (MOFtors): Recent progress and challenges

Coordination Chemistry Reviews, Journal Year: 2023, Volume and Issue: 495, P. 215372 - 215372

Published: Aug. 10, 2023

Language: Английский

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Ultrafine molybdenum carbide nanocrystals into three-dimensional nitrogen-doped carbon framework for capacitive deionization: with metal-organic framework as a template

Chemical Science, Journal Year: 2024, Volume and Issue: 15(29), P. 11540 - 11549

Published: Jan. 1, 2024

Ultrafine MoC nanocrystals are confined within the MOF-derived NC matrix to generating NC/MoC. The NC/MoC based electrode achieves high CDI performance.

Language: Английский

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Synergistic enhancement of electrochemical performance of NiFe₂O₄@Ni-MOF nanoflake hybrids for high-performance energy storage applications

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(32), P. 21230 - 21242

Published: Jan. 1, 2024

In this study, a novel method is investigated for enhancing the electrochemical performance of MOFs, particularly Ni-MOFs, which have encountered challenges in energy storage applications owing to their limited electrical conductivity and stability.

Language: Английский

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DNA framework-controlled Poly(MOFs) as a visual platform for diagnosis of HER2-positive breast cancer

Nano Today, Journal Year: 2024, Volume and Issue: 54, P. 102143 - 102143

Published: Jan. 3, 2024

Language: Английский

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