High entropy oxides as a rising star in pollutant disposal and resource recycling: Emerging advancements and future challenges DOI

Yukang Hua,

Guijin Su,

Qianqian Li

et al.

Critical Reviews in Environmental Science and Technology, Journal Year: 2024, Volume and Issue: unknown, P. 1 - 24

Published: July 21, 2024

Language: Английский

Engineering a High-Entropy Driven and Nuclear-Targeted Bioorthogonal Catalyst for Cancer Therapy DOI

Wenjie Wang,

Lu Zhang,

Anjun Song

et al.

Chemistry of Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 8, 2025

Bioorthogonal catalysis mediated by Pd-based catalysts has drawn widespread attention for the treatment of diseases. However, catalytic performance and durability current Pd0 are unsatisfactory. Herein, a high-entropy driven nuclear-targeted bioorthogonal system with superior been engineered to enhance activity prevent deactivation Pd improved antitumor therapy. The coordination environment alloys (HEAs) stabilizes Pd, endowing durability. Meanwhile, multicomponent interactions HEAs synergistically provide ligand effect supply electrons thereby improving performance. Furthermore, we discovered first time that exhibit glutathione peroxidase-like eliminating antioxidant within intracellular environments. Importantly, synthesis drugs at nucleus can further amplify therapeutic Pd0-based in environment. Additionally, photothermal properties effect. This work potential broaden applications contribute design catalysts.

Language: Английский

Citations

1

Advances in rare earth catalysts for small molecule electrosynthesis☆ DOI

Junfeng Du,

Jing Yu,

Chaohui Guan

et al.

Journal of Rare Earths, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 1, 2025

Language: Английский

Citations

1

High-Entropy Electrode Materials: Synthesis, Properties and Outlook DOI Creative Commons
Dongxiao Li, Chang Liu,

Shusheng Tao

et al.

Nano-Micro Letters, Journal Year: 2024, Volume and Issue: 17(1)

Published: Sept. 27, 2024

Abstract High-entropy materials represent a new category of high-performance materials, first proposed in 2004 and extensively investigated by researchers over the past two decades. The definition high-entropy has continuously evolved. In last ten years, discovery an increasing number led to significant advancements their utilization energy storage, electrocatalysis, related domains, accompanied rise techniques for fabricating electrode materials. Recently, research emphasis shifted from solely improving performance toward exploring reaction mechanisms adopting cleaner preparation approaches. However, current remains relatively vague, method is based on single metal/low- or medium-entropy It should be noted that not all methods applicable can directly applied this review, development are briefly reviewed. Subsequently, classification presented, followed discussion applications storage catalysis perspective synthesis methods. Finally, evaluation advantages disadvantages various production process different provided, along with proposal potential future directions

Language: Английский

Citations

8

Comprehensive Insight Into Electronic Modulation of Rare‐Earth Elements for Enhancing Electrocatalytic Performance of Atomically Dispersed Materials DOI Open Access
Yanhui Cao, Xuerong Zheng, Yida Deng

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 2, 2025

Abstract Atomically dispersed materials have been a thriving research field due to their maximum atomic utilization and remarkable performance in energy conversion storage systems. Owing the large radius, strong oxophilicity, unique electronic properties, rare‐earth (RE) elements widely investigated as oxide carriers promoters atomically manipulate regulate structure of active species. Single‐atom state with an adjustable coordination environment on N‐doped carbon endows RE metals special states outstanding catalytic performances. A thorough comprehension modulation mechanism paves way for construction advanced RE‐based electrocatalysts high activity, stability, selectivity. This review provides widespread insight into roles modulating properties combined structure–performance relationship electrocatalysis processes. The characteristic physical chemical are highlighted, synthetic strategy is discussed. Finally, summary perspectives rational design development highly efficient catalysts proposed. aims provide guideline promoting effective functional materials.

Language: Английский

Citations

0

Synthesis, characterization and photoluminescence of high-entropy oxide (Y0.2Eu0.2Gd0.2La0.2Er0.2)2O3 nanopowders for lighting applications DOI
Yu. A. Kuznetsova, A. N. Kiryakov, Е. А. Бунтов

et al.

Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: unknown, P. 179098 - 179098

Published: Feb. 1, 2025

Language: Английский

Citations

0

A high-entropy carbonate hydroxide as a high-efficient tri-functional electrocatalyst for OER/ORR/MOR DOI

Haoqi Qiu,

Jiafang Jian,

Jiasheng Huang

et al.

Materials Today Energy, Journal Year: 2025, Volume and Issue: unknown, P. 101847 - 101847

Published: Feb. 1, 2025

Language: Английский

Citations

0

High-entropy oxide optical nanoceramics prepared by thermobaric synthesis DOI
A. N. Kiryakov, Yu. A. Kuznetsova, Е. А. Бунтов

et al.

Journal of the European Ceramic Society, Journal Year: 2025, Volume and Issue: unknown, P. 117316 - 117316

Published: Feb. 1, 2025

Language: Английский

Citations

0

Overview of Recent Advances in Rare-Earth High-Entropy Oxides as Multifunctional Materials for Next-Gen Technology Applications DOI Creative Commons
Stjepan Šarić, Jelena Kojčinović, Dalibor Tatar

et al.

Molecules, Journal Year: 2025, Volume and Issue: 30(5), P. 1082 - 1082

Published: Feb. 27, 2025

Rare-earth high-entropy oxides are a new promising class of multifunctional materials characterized by their ability to stabilize complex, multi-cationic compositions into single-phase structures through configurational entropy. This feature enables fine-tuning structural properties such as oxygen vacancies, lattice distortions, and defect chemistry, making them for advanced technological applications. While initial research primarily focused on catalytic performance in energy environmental applications, recent demonstrated potential optoelectronics, photoluminescent materials, aerospace technologies. Progress synthesis techniques has provided control over particle morphology, composition, engineering, enhancing electronic, thermal, mechanical properties. exhibit tunable bandgaps, exceptional thermal stability, superior resistance phase degradation, which positions next-generation materials. Despite these advances, challenges remain scaling up production, optimizing specific understanding the fundamental mechanisms governing multifunctionality. review provides comprehensive analysis developments rare-earth relatively still underrated material future.

Language: Английский

Citations

0

Synthesis and electrical properties of (Ba0.2Bi0.2K0.2Ln0.2Na0.2)TiO3 high-entropy perovskite oxides DOI
Qiang He, Tianyu Liu, Han Yu

et al.

Ceramics International, Journal Year: 2025, Volume and Issue: unknown

Published: March 1, 2025

Language: Английский

Citations

0

Iminodiacetic acid stabilized 3d-4f clusters: Synthesis, structure, and magnetism DOI

Ming-Qiang Qi,

Hongtai Zhang,

X. Diao

et al.

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 534, P. 216585 - 216585

Published: March 5, 2025

Language: Английский

Citations

0