Considerate instability factors in mono and divalent metal ion batteries: from fundamentals to approaches DOI
Elmira Kohan, Azra Ghiasi Moaser, Mir Ghasem Hosseini

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(44), P. 30190 - 30248

Published: Jan. 1, 2024

Degradation phenomena in different components (cathode, anode, current collectors (CCs)) of mono- and divalent metal-based batteries affect their performance.

Language: Английский

Research development on electrolytes for magnesium-ion batteries DOI

Yuehua Man,

Pauline Jaumaux, Yifan Xu

et al.

Science Bulletin, Journal Year: 2023, Volume and Issue: 68(16), P. 1819 - 1842

Published: July 20, 2023

Language: Английский

Citations

86

Improvement of cycle life for layered oxide cathodes in sodium-ion batteries DOI
Huan Yang, Dong Wang, Yalan Liu

et al.

Energy & Environmental Science, Journal Year: 2024, Volume and Issue: 17(5), P. 1756 - 1780

Published: Jan. 1, 2024

In this review, research progress on layered oxide cathodes for SIBs in recent years is summarized, with emphasis the problems of poor cycle life caused by irreversible phase transition, Jahn–Teller effect and interface deterioration, several strategies are proposed to alleviate these issues.

Language: Английский

Citations

71

Gel polymer electrolytes for rechargeable batteries toward wide-temperature applications DOI Creative Commons
Xiaoyan Zhou,

Yifang Zhou,

Le Yu

et al.

Chemical Society Reviews, Journal Year: 2024, Volume and Issue: 53(10), P. 5291 - 5337

Published: Jan. 1, 2024

Design principles, engineering strategies, challenges, and opportunities of gel polymer electrolytes for rechargeable batteries toward wide-temperature applications are thoroughly reviewed.

Language: Английский

Citations

61

Challenges and Strategies on Interphasial Regulation for Aqueous Rechargeable Batteries DOI
Xin Geng, Xu Hou, Xin He

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: 14(12)

Published: Jan. 22, 2024

Abstract The practical application of aqueous rechargeable batteries faces several challenges due to the limited stability window electrolytes and parasitic side reactions, such as corrosion, passivation, gas evolution, co‐intercalations. solid electrolyte interphase (SEI) formed at electrode/electrolyte interface plays a critical role in determining interfacial properties battery performance. Efforts are being made develop effective SEIs, functionalize layers, explore various hybrid that facilitate SEI formation. This review highlights interphasial structures batteries. First, common issues encountered by specific characteristics lithium‐ion, sodium‐ion, zinc‐ion, aluminum‐ion outlined. Then tactics used improve cycle introduced compared working principles key parameters from context modification discussed. Finally, constructive insights suggestions for developing high‐performance offered, with focus on formation layer design.

Language: Английский

Citations

35

Electrolyte Additive for Interfacial Engineering of Lithium and Zinc Metal Anodes DOI
Guanyao Wang, Qiankui Zhang, Xue‐Qiang Zhang

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: unknown

Published: March 4, 2024

Abstract Electrolytes play a crucial role in facilitating the ionic movement between cathode and anode, which is essential for flow of electric current during charging discharging process rechargeable batteries. In particular, electrolyte additives are considered as effective economical approaches into advancements battery technologies both conventional non‐aqueous burgeoning aqueous systems. Herein, systematic comprehensive review reported interfacial engineering Li Zn metal anodes electrolytes, respectively. The types their corresponding functionalities protection these two discussed along with electrochemical features solid interphase (SEI) derived from additives. recent progress on systems also addressed perspectives electrode, electrolyte, associated SEI. Finally, outlook perspective issues future directions field additive presented next‐generation beyond Li‐ion

Language: Английский

Citations

22

Understanding the Cathode‐Electrolyte Interfacial Chemistry in Rechargeable Magnesium Batteries DOI
Hucheng Shi, Guixin Wang,

Zhechen Wang

et al.

Advanced Science, Journal Year: 2024, Volume and Issue: 11(25)

Published: April 6, 2024

Abstract Rechargeable magnesium batteries (RMBs) have garnered significant attention due to their potential provide high energy density, utilize earth‐abundant raw materials, and employ metal anode safely. Currently, the lack of applicable cathode materials has become one bottleneck issues for fully exploiting technological advantages RMBs. Recent studies on Mg cathodes reveal divergent storage performance depending electrolyte formulation, posing interfacial as a previously overlooked challenge. This minireview begins with an introduction representative cathode‐electrolyte phenomena in RMBs, elaborating unique solvation behavior 2+ , which lays foundation chemistries. It is followed by presenting recently developed strategies targeting promotion desolvation alternative cointercalation approaches circumvent step. In addition, efforts enhance compatibility via development engineering are highlighted. Based abovementioned discussions, this finally puts forward perspectives challenges establishment stable interface fast chemistry

Language: Английский

Citations

20

Prussian Blue and Its Analogues for Commercializing Fast-Charging Sodium/Potassium-Ion Batteries DOI Creative Commons

Ping Hong,

Changfan Xu, Chengzhan Yan

et al.

ACS Energy Letters, Journal Year: 2025, Volume and Issue: unknown, P. 750 - 778

Published: Jan. 13, 2025

Fast-charging technology, which reduces charging time and enhances convenience, is attracting attention. Sodium-ion batteries (SIBs) potassium-ion (PIBs) are emerging as viable alternatives to lithium-ion (LIBs) due their abundant resources low cost. However, during fast discharging, the crystal structures of cathode materials in SIBs/PIBs can be damaged, negatively impacting performance, lifespan, capacity. To address this, there a need explore electrode with ultrahigh rate capabilities. Prussian Blue its analogues (PB PBAs) have shown great potential for both SIBs PIBs unique excellent electrochemical properties. This Review examines use PBAs PIBs, focusing on fast-charging (rate) performance commercialization potential. Through systematic analysis discussion, we hope provide practical guidance developing contributing advancement widespread adoption green energy technologies.

Language: Английский

Citations

5

Solid-state electrolytes for safe rechargeable lithium metal batteries: a strategic view DOI Creative Commons
Leire Meabe, Itziar Aldalur, Simon Lindberg

et al.

Materials Futures, Journal Year: 2023, Volume and Issue: 2(3), P. 033501 - 033501

Published: April 18, 2023

Abstract Despite the efforts devoted to identification of new electrode materials with higher specific capacities and electrolyte additives mitigate well-known limitations current lithium-ion batteries, this technology is believed have almost reached its energy density limit. It suffers also a severe safety concern ascribed use flammable liquid-based electrolytes. In regard, solid-state electrolytes (SSEs) enabling lithium metal as anode in so-called batteries (SSLMBs) are considered most desirable solution tackle aforementioned limitations. This emerging has rapidly evolved recent years thanks striking advances gained domain materials, where SSEs can be classified according their core chemistry organic, inorganic, hybrid/composite strategic review presents critical analysis design strategies reported field SSEs, summarizing main advantages disadvantages, providing future perspective toward rapid development SSLMB technology.

Language: Английский

Citations

43

Asymmetric Electrolytes Design for Aqueous Multivalent Metal Ion Batteries DOI Creative Commons
Xiaochen Yang, Xinyu Wang, Yue Xiang

et al.

Nano-Micro Letters, Journal Year: 2023, Volume and Issue: 16(1)

Published: Dec. 15, 2023

With the rapid development of portable electronics and electric road vehicles, high-energy-density batteries have been becoming front-burner issues. Traditionally, homogeneous electrolyte cannot simultaneously meet diametrically opposed demands high-potential cathode low-potential anode, which are essential for high-voltage batteries. Meanwhile, is difficult to achieve bi- or multi-functions different requirements electrodes. In comparison, asymmetric with multi-layer disparate components can satisfy distinct by playing roles each layer meanwhile compensates weakness individual electrolyte. Consequently, not only suppress by-product sedimentation continuous decomposition at anode while preserving active substances long cyclic lifespan. this review, we comprehensively divide electrolytes into three categories: decoupled liquid-state electrolytes, bi-phase solid/liquid solid-state electrolytes. The design principles, reaction mechanism mutual compatibility also studied, respectively. Finally, provide a comprehensive vision simplification structure reduce costs increase device energy density, optimization solvation anolyte/catholyte interface realize fast ion transport kinetics.

Language: Английский

Citations

41

Electrolyte Engineering Toward High Performance High Nickel (Ni ≥ 80%) Lithium‐Ion Batteries DOI Creative Commons
Tiantian Dong,

Shenghang Zhang,

Zhongqin Ren

et al.

Advanced Science, Journal Year: 2023, Volume and Issue: 11(7)

Published: Dec. 3, 2023

Abstract High nickel (Ni ≥ 80%) lithium‐ion batteries (LIBs) with high specific energy are one of the most important technical routes to resolve growing endurance anxieties. However, because their extremely aggressive chemistries, high‐Ni LIBs suffer from poor cycle life and safety performance, which hinder large‐scale commercial applications. Among varied strategies, electrolyte engineering is very powerful simultaneously enhance LIBs. In this review, pivotal challenges faced by oxide cathodes conventional LiPF 6 ‐carbonate‐based electrolytes comprehensively summarized. Then, functional additives design guidelines for ‐carbonate ‐based principles voltage resistance/high novel systematically elaborated these challenges. Moreover, proposed thermal runaway mechanisms also reviewed provide useful perspectives high‐safety electrolytes. Finally, potential research directions toward high‐performance provided. This review will have an impact on innovation as well evolution LIBs, be significant breakthrough density ceiling

Language: Английский

Citations

35