Journal of Inorganic and Organometallic Polymers and Materials, Journal Year: 2025, Volume and Issue: unknown
Published: March 21, 2025
Language: Английский
Journal of Inorganic and Organometallic Polymers and Materials, Journal Year: 2025, Volume and Issue: unknown
Published: March 21, 2025
Language: Английский
ACS Sustainable Chemistry & Engineering, Journal Year: 2024, Volume and Issue: 12(28), P. 10363 - 10375
Published: June 28, 2024
The valorization of chitinous biomass from underutilized renewable carbon feedstock offers alternative routes for bioproduct development, reducing our dependence on nonrenewable and nonbiodegradable materials composed fossil carbon. This work utilizes crustacean waste consisting inedible shells to isolate chitin its derivatives, nanocrystals chitosan, lobster (Homarus gammarus) spider crab (Maja squinado) shells. Chitin (ChNCs) with a degree acetylation >93% crystallinity >90% were obtained by demineralization, deproteinization acid-hydrolysis, while chitosan was deacetylation. Free-standing chitosan/ChNCs films then fabricated after dissolution casting using 1.5% v/v formic acid. Lobster-derived exhibited good balance between UV-shielding ability, blocking >96% UV-C UV-B, being transparent at visible wavelengths. Neat are semiductile, elongations break >13% Young's modulus values 2.3 ± 0.7 3.4 1.2 GPa crab-derived respectively. Besides, the incorporation ChNCs increases 5.5 0.8 2 wt % lobster-derived films. Life cycle assessment (LCA) conducted quantify environmental impact film production identify process hotspots future optimization. A footprint 79.8 kg CO2 equiv·kg–1 is chitosan/ChNC processed 100% energy mix. Results demonstrate that relevant contenders toward defossilization developing renewable-carbon containing bioproducts competitive performance against fossil-based due their optical mechanical properties, as well potential biodegradability.
Language: Английский
Citations
7International Journal of Biological Macromolecules, Journal Year: 2024, Volume and Issue: 277, P. 134170 - 134170
Published: July 26, 2024
Language: Английский
Citations
7Sustainable Chemistry and Pharmacy, Journal Year: 2025, Volume and Issue: 44, P. 101942 - 101942
Published: Feb. 7, 2025
Language: Английский
Citations
1Green Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
Transforming furfural waste into biofuels and biochar with outstanding PFOA adsorption capacity, offering sustainable solutions for environmental remediation.
Language: Английский
Citations
1Journal of Inorganic and Organometallic Polymers and Materials, Journal Year: 2025, Volume and Issue: unknown
Published: March 21, 2025
Language: Английский
Citations
1