History repeats itself again: Will the mistakes of the past for ILs be repeated for DESs? From being considered ionic liquids to becoming their alternative: the unbalanced turn of deep eutectic solvents

Green Chemistry, Journal Year: 2022, Volume and Issue: 25(1), P. 59 - 105

Published: Nov. 29, 2022

Comparing properties of ionic liquids, (deep) eutectic solvents and traditional organic solvents, as well their applicability in lignocellulosic biomass processing.

Language: Английский

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Depolymerization within a Circular Plastics System

Chemical Reviews, Journal Year: 2024, Volume and Issue: 124(5), P. 2617 - 2650

Published: Feb. 22, 2024

The societal importance of plastics contrasts with the carelessness which they are disposed. Their superlative properties lead to economic and environmental efficiency, but linearity puts climate, human health, global ecosystems at risk. Recycling is fundamental transitioning this linear model into a more sustainable, circular economy. Among recycling technologies, chemical depolymerization offers route virgin quality recycled plastics, especially when valorizing complex waste streams poorly served by mechanical methods. However, exists in interlinked system end-of-life fates, complementarity each approach key environmental, economic, sustainability. This review explores recent progress made five commercial polymers: poly(ethylene terephthalate), polycarbonates, polyamides, aliphatic polyesters, polyurethanes. Attention paid not only catalytic technologies used enhance efficiencies also interrelationship other systemic constraints imposed Novel polymers, designed for depolymerization, concisely reviewed terms their underlying chemistry potential integration current plastic systems.

Language: Английский

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An overview of deep eutectic solvents: Alternative for organic electrolytes, aqueous systems & ionic liquids for electrochemical energy storage

Journal of Energy Chemistry, Journal Year: 2023, Volume and Issue: 82, P. 592 - 626

Published: April 7, 2023

Language: Английский

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Citric Acid: Properties, Microbial Production, and Applications in Industries

Molecules, Journal Year: 2023, Volume and Issue: 29(1), P. 22 - 22

Published: Dec. 19, 2023

Citric acid finds broad applications in various industrial sectors, such as the pharmaceutical, food, chemical, and cosmetic industries. The bioproduction of citric uses microorganisms, but most commonly employed ones are filamentous fungi Aspergillus niger yeast Yarrowia lipolytica. This article presents a literature review on properties acid, microorganisms substrates used, different fermentation techniques, its utilization, global market. emphasizes that there is still much to explore, both terms production process techniques emerging new acid.

Language: Английский

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Toxicity test profile for deep eutectic solvents: A detailed review and future prospects

Chemosphere, Journal Year: 2024, Volume and Issue: 350, P. 141097 - 141097

Published: Jan. 1, 2024

Language: Английский

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Towards the sustainable production of biomass-derived materials with smart functionality: A tutorial review

Green Chemistry, Journal Year: 2024, Volume and Issue: 26(16), P. 9075 - 9103

Published: Jan. 1, 2024

Towards the sustainable production of biomass-derived materials with smart functionality.

Language: Английский

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Biocatalysis for the Synthesis of Active Pharmaceutical Ingredients in Deep Eutectic Solvents: State-of-the-Art and Prospects

Catalysts, Journal Year: 2024, Volume and Issue: 14(1), P. 84 - 84

Published: Jan. 19, 2024

Biocatalysis holds immense potential for pharmaceutical development as it enables synthetic routes to various chiral building blocks with unparalleled selectivity. Therein, solvent and water use account a large contribution the environmental impact of reactions. In spirit Green Chemistry, transition from traditional highly diluted aqueous systems intensified non-aqueous media overcome limitations (e.g., shortages, recalcitrant wastewater treatments, low substrate loadings) has been observed. Benefiting spectacular advances in enzyme stabilization techniques, plethora biotransformations non-conventional have established. Deep eutectic solvents (DESs) emerge sort (potentially) greener medium increasing biocatalysis. This review discusses state-of-the-art DESs focus on biocatalytic pathways synthesis active ingredients (APIs). Representative examples different classes are discussed, together critical vision discussing prospects using

Language: Английский

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Applications of ionic liquids and deep eutectic solvents for the extraction of phenolic compounds from coal-based crude oils

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 337, P. 126383 - 126383

Published: Jan. 18, 2024

Language: Английский

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Efficient and environmentally friendly techniques for extracting lignin from lignocellulose biomass and subsequent uses: A review

Cleaner Materials, Journal Year: 2024, Volume and Issue: 13, P. 100253 - 100253

Published: June 13, 2024

The development of sustainable and effective methods for extracting lignin is crucial achieving the advantages promoting shift towards a more circular bioeconomy. This study addresses use environmentally friendly processes, including organosolv technique, supercritical fluid (SCF), non-thermal plasma (NTP), ionic liquids (ILs), deep eutectic solvents (DES), microwave assisted extraction (MAE) techniques extraction. Organosolv treatment offers high selectivity purity make this process economically feasible. Using water, carbon dioxide, or ethanol to extract without harmful successful customizable. NTP technologies break down lignin, simplifying processing increasing its value. Whereas ILs may boost synthesis change properties via solvent design. DES-based can efficiently specifically lignin. rapid MAE method employs radiation reduce times yields These feature selectivity, little environmental impact, capacity target fractions. describes fundamentals, benefits, drawbacks each process, focusing on their ability large scale future usage. Additionally, review explores most recent advancements in application sector, as well challenges potential valorizing streams derived from extraction, thereby fostering solutions. research concludes that overcome challenges, need address concerns, cost, emissions, efficient use.

Language: Английский

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Sustainable Synthesis of Functional Materials Assisted by Deep Eutectic Solvents for Biomedical, Environmental, and Energy Applications

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 2, 2025

Abstract The rapid expansion of the global economy has led to a surge in energy demand, resulting significant environmental pollution and scarcity due concomitant increase greenhouse gas emissions. advancement deep eutectic solvents (DESs) introduced viable substitute for traditional processing methods, boasting numerous intrinsic benefits, such as superior eco‐compatibility, outstanding thermal stability, desirable electrochemical properties. Consequently, DESs have garnered attention from research community, demonstrating broad spectrum prospective applications variety fields instance energy, biomass degradation, materials synthesis, biomedicine. This review aims offer comprehensive methodical overview DESs, encompassing their historical development, classification, preparation methodologies, fundamental physicochemical Furthermore, this explores synthesis various functional examines multifunctional roles. Crucially, economic viability is thoroughly examined, including an assessment cost‐effectiveness market potential. Finally, concludes by outlining future directions development challenges that remain.

Language: Английский

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