Recent advances in all-solid-state batteries for commercialization

Materials Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 8(8), P. 1861 - 1887

Published: Jan. 1, 2024

Challenges in the commercialization of all solid-state and next-generation batteries including strategies, key points, application batteries.

Language: Английский

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Size-controlled wet-chemical synthesis of sulfide superionic conductors for high-performance all-solid-state batteries

Energy storage materials, Journal Year: 2024, Volume and Issue: 67, P. 103253 - 103253

Published: Feb. 18, 2024

Language: Английский

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A comprehensive overview of wet chemistry methodologies and their application in the fabrication of materials for PEM fuel cell

International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 58, P. 1190 - 1203

Published: Jan. 31, 2024

Language: Английский

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Toward Scalable Liquid-Phase Synthesis of Sulfide Solid Electrolytes for All-Solid-State Batteries

Batteries, Journal Year: 2023, Volume and Issue: 9(7), P. 355 - 355

Published: July 4, 2023

All-solid-state batteries (ASSBs) are promising to be next-generation battery that provides high energy density and intrinsic safety. Research in the field of ASSBs has so far focused on development highly conductive solid electrolytes (SEs). The commercialization requires well-established large-scale manufacturing for sulfide SEs with ionic conductivity. However, synthesis remains at laboratory scale limited scalability owing their air sensitivity. liquid-phase would an economically viable technology SEs. Herein, we review a chemical perspective offers scalability, low cost, reaction kinetics. This guideline desirable solvent selection based solubility polarity characterized by donor number dielectric permittivity solvents. Additionally, offer deeper understanding recent works scalable using solubilizers reactant agents. We present outlook universal toward sulfide-based ASSBs.

Language: Английский

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Next generation sustainable lithium-ion batteries: Micro and nanostructured materials and processes

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161337 - 161337

Published: March 1, 2025

Language: Английский

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Hybrid Liquid–Solid Composite Electrolytes for Sulfide‐Based Solid‐State Batteries: Advantages and Limitation

Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 33(46)

Published: Sept. 1, 2023

Abstract All‐solid‐state batteries (SSBs) represent one of the most promising avenues for surpassing energy density limitations conventional lithium‐ion batteries. However, unstable interfacial contact between solid‐state electrolyte and electrode poses a critical challenge practical applications. To tackle this issue, hybrid system incorporating both liquid electrolytes (LEs) sulfide may serve as viable alternative. In system, LE facilitates in situ formation solid interphase layer, thereby enhancing physical interface contact. Consequently, electrochemical lifetime all‐SSBs is significantly improved, evidenced by stable lithium plating behavior observed through analytical techniques such X‐ray imaging. Nonetheless, exhibits clear limitations, several issues that need to be addressed its implementation are identified. conclusion, potential solutions could employed overcome these challenges proposed.

Language: Английский

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Mechanochemical Synthesis of Solid-State Electrolytes

Inorganics, Journal Year: 2024, Volume and Issue: 12(2), P. 54 - 54

Published: Feb. 6, 2024

In recent decades, the field of materials research has put significant emphasis on developing innovative platforms that have potential to address increasing global energy demand. Batteries demonstrated their enormous effectiveness in context storage and consumption. However, safety issues associated with liquid electrolytes combined a low abundance lithium Earth’s crust gave rise development solid-state cations other than lithium. The commercial production batteries demands scaling up electrolyte syntheses as well mixing electrode composites containing solid electrolytes. This review is motivated by literature, it gives thorough overview highlights significance employed milling dispersing procedures for resulting ionic transport properties.

Language: Английский

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Infiltration-driven performance enhancement of poly-crystalline cathodes in all-solid-state batteries

NPG Asia Materials, Journal Year: 2024, Volume and Issue: 16(1)

Published: Oct. 18, 2024

Abstract All-solid-state batteries (ASSBs) with adequately selected cathode materials exhibit a higher energy density and better safety than conventional lithium-ion (LIBs). Ni-rich layered cathodes are benchmark for traditional LIBs owing to their high density. Recent studies have highlighted the advantages of using crack-free, single-crystalline in ASSBs. In this study, scalable infiltration sheet-type process was used fabricate composite electrodes different cathode-material morphologies Typically, crack-free retention performance lower rate capability (i.e., slower kinetics charge‒discharge processes) polycrystalline materials. Li 6 PS 5 Cl-infiltrated showed excellent capability. Galvanostatic intermittent titration technique analysis transmission electron microscopy electrode confirmed severe polarization presence rock-salt-structure layer particles; these results indicated side reactions within structure material. contrast, consisting infiltrated solid electrolyte Cl electrochemical intimate electrode–electrolyte interfacial contact. The result from study critical influence interface engineering material morphology on overall stability ASSBs could facilitate development high-performance future.

Language: Английский

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Toward High‐Quality Sulfide Solid Electrolytes: A Liquid‐Phase Approach Featured with an Interparticle Coupled Unification Effect

Small, Journal Year: 2023, Volume and Issue: 20(23)

Published: Dec. 26, 2023

Sulfide solid electrolytes (SSEs) are highly wanted for solid-state batteries (SSBs). While their liquid-phase synthesis is advantageous over solid-phase strategy in scalable production, it confronts other challenges, such as low-purity products, user-unfriendly solvents, energy-inefficient solvent removal, and unsatisfactory performance. This article demonstrates that a suspension-based solvothermal method using single oxygen-free solvents can solve those problems. Experimental observations theoretical calculations together show the basic function of suspension-treatment "interparticle-coupled unification", is, even individually insoluble precursors mutually adsorb amalgamate to generate uniform composites nonpolar solvents. anti-intuitive concept established when investigating origins impurities SSEs made by conventional tetrahydrofuran-ethanol then searching new Its generality supported four eligible alkane types SSEs. The electrochemical assessments on former three they competitive with counterparts literature. Moreover, synthesized presents excellent battery performance, showing great potential practical applications.

Language: Английский

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Infiltration -driven performance enhancement of poly-crystalline cathodes in all-solid-state batteries

Research Square (Research Square), Journal Year: 2024, Volume and Issue: unknown

Published: Feb. 14, 2024

All-solid-state batteries (ASSBs) with adequately selected cathode materials exhibit a higher energy density and better safety than conventional lithium-ion (LIBs ). Ni-rich layered cathodes are benchmark for traditional LIBs owing to their high density. Recent studies have highlighted the advantages of using crack-free, single-crystalline in ASSBs . In this study, scalable infiltration sheet-type process was used fabricate composite electrodes different cathode-material morphologies Typically, crack-free retention performance lower rate capability polycrystalline materials. Li₆PS₅Cl-infiltrated showed an excellent capability. Galvanostatic intermittent titration technique analysis transmission electron microscopy confirmed severe polarization presence rock-salt-structure layer particles, indicating side reactions within structure material. contrast, comprising infiltrated solid electrolyte Li₆PS₅Cl electrochemical intimate electrode–electrolyte interfacial contact. This study confirms critical influence interface engineering material morphology on overall stability ASSBs, could facilitate development high-performance future

Language: Английский

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