Progress in the Construction of Spirocyclohexadienones via Alkyne-Involving Dearomatization DOI Open Access
Peng Liu,

Fuming Zhong,

Lihao Liao

et al.

Chinese Journal of Organic Chemistry, Journal Year: 2023, Volume and Issue: 43(12), P. 4019 - 4019

Published: Jan. 1, 2023

Spirocyclohexadienones are not only widely present in bioactive molecules, but also act as key synthetic intermediates for the synthesis of natural products.Owing to great importance these compounds, their efficient has drawn considerable attention from chemists.In particular, there many reports about spirocyclohexadienone derivatives via alkyne-involving dearomatization past few years.The success reactions benefits reaction mode: activation alkyne π bond by radicals, electrophiles, or metal catalysts under conditions photocatalysis, electrocatalysis, chemical oxidation, and then subsequent process.The advances electron-deficient, electron-ordinary, electron-rich alkynes-participated phenolic realize construction recent five years systematically summarized.During discussion, used triggering ways subdivided.At last, prospects this field discussed.

Language: Английский

Progress in the Construction of Spirocyclohexadienones via Alkyne-Involving Dearomatization DOI Open Access
Peng Liu,

Fuming Zhong,

Lihao Liao

et al.

Chinese Journal of Organic Chemistry, Journal Year: 2023, Volume and Issue: 43(12), P. 4019 - 4019

Published: Jan. 1, 2023

Spirocyclohexadienones are not only widely present in bioactive molecules, but also act as key synthetic intermediates for the synthesis of natural products.Owing to great importance these compounds, their efficient has drawn considerable attention from chemists.In particular, there many reports about spirocyclohexadienone derivatives via alkyne-involving dearomatization past few years.The success reactions benefits reaction mode: activation alkyne π bond by radicals, electrophiles, or metal catalysts under conditions photocatalysis, electrocatalysis, chemical oxidation, and then subsequent process.The advances electron-deficient, electron-ordinary, electron-rich alkynes-participated phenolic realize construction recent five years systematically summarized.During discussion, used triggering ways subdivided.At last, prospects this field discussed.

Language: Английский

Citations

0