Separation and Purification Technology, Journal Year: 2024, Volume and Issue: unknown, P. 129930 - 129930
Published: Sept. 1, 2024
Language: Английский
Chem, Journal Year: 2023, Volume and Issue: 9(7), P. 1768 - 1827
Published: June 21, 2023
Language: Английский
Citations
270
Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 33(43)
Published: June 25, 2023
Abstract Ammonia as an irreplaceable chemical has been widely demanded to keep the sustainable development of modern society. However, its industrial production consumes huge energy and releases extraordinary green‐house gases, leading various environmental issues. To achieve green ammonia is a great challenge that extensively pursued recently. In review, most promising strategy, electrochemical nitrate reduction reaction (e‐NO 3 RR) for purpose comprehensively investigated give full understanding mechanism provide guidance future directions. Particularly, electrocatalysts focused realize high yield rate Faraday efficiency applications. The recent‐developed catalysts, including noble metallic materials, alloys, metal compounds, single‐metal‐atom metal‐free are systematically discussed review effects factors on catalytic performance in e‐NO RR. Accordingly, strategies, defects engineering, coordination environment modulating, surface controlling, hybridization, carefully improve performance, such intrinsic activity selectivity. Finally, perspectives challenges given out. This shall insightful advanced systems efficiently industry.
Language: Английский
Citations
149
Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 506, P. 215723 - 215723
Published: Feb. 26, 2024
Language: Английский
Citations
47
Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 659, P. 432 - 438
Published: Jan. 4, 2024
Language: Английский
Citations
37
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 481, P. 148734 - 148734
Published: Jan. 14, 2024
Language: Английский
Citations
33
ACS Sustainable Chemistry & Engineering, Journal Year: 2024, Volume and Issue: 12(7), P. 2783 - 2789
Published: Feb. 2, 2024
Electrochemical nitrite-to-ammonia reduction (NO2RR) holds great promise for converting harmful NO2– into valuable NH3. Herein, we develop Co single atoms dispersed on a C3N4 substrate (Co1/C3N4) as an efficient catalyst toward the NO2RR. Experimental and theoretical investigations reveal that single-atom sites can effectively active optimize formation energy of key *NOH intermediate to promote → NH3 energetics. Remarkably, Co1/C3N4 equipped in flow cell delivers exceptional NH3–Faradaic efficiency 97.9% yield rate 1080.3 μmol h–1cm–2 at industrial-level current density 355 mA cm–2, along with long-term durability 100 h electrolysis, showing considerable potential practical electrosynthesis.
Language: Английский
Citations
31
Energy & Fuels, Journal Year: 2024, Volume and Issue: 38(8), P. 6701 - 6722
Published: April 8, 2024
Electrochemical nitrate reduction is the process of converting into ammonia or nitrogen using electric energy. This saves energy, protects environment, and an important technology for resource recovery water purification. paper examines recent advances in electrochemical research analyzes reaction mechanism path as well influence various factors on through thermodynamic kinetic principles. Second, catalytic performances transition metal electrocatalysts form single metals, alloys, oxides, composites are analyzed detail, which lays foundation rational development new, efficient, stable electrocatalysts. Finally, future directions prospects envisioned.
Language: Английский
Citations
22
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 489, P. 151410 - 151410
Published: April 17, 2024
Language: Английский
Citations
21
Analytical Chemistry, Journal Year: 2024, Volume and Issue: 96(8), P. 3645 - 3654
Published: Feb. 15, 2024
Accurate measurement of cancer markers in urine is a convenient method for tumor monitoring. However, the concentration so low that it difficult to achieve their measurement. Photoelectrochemical (PEC) sensors are promising technology realize detection trace due high sensitivity. Currently, interference nonspecific biomolecules main reason affecting sensitivity and selectivity PEC detecting markers. In this work, strategy oxygen vacancy (OV) modulation proposed construct fouling-resistant aptamer sensing platform α-fetoprotein (AFP), liver marker. The introduction OVs induces formation intermediate localized states photoelectric material, which not only facilitates separation photogenerated carriers but also leads redshift light absorption edge. More importantly, with positive electrical properties can be employed modify antifouling layer (C-PEG) negatively charged groups through an electrostatic interaction. synergistic effect OVs, layer, resulted TiO2/OVs/C-PEG-based sensor achieves wide linear range from 1 pg/mL 100 ng/mL limit 0.3 AFP. addition, successfully realized determination AFP samples accurately differentiated between normal people patients early advanced stages. This project great significance advancing application photoelectrochemical bioanalytical by investigating construction OVs-regulated interface.
Language: Английский
Citations
19
Journal of Colloid and Interface Science, Journal Year: 2023, Volume and Issue: 647, P. 73 - 80
Published: May 22, 2023
Language: Английский
Citations
26