Chemistry - A European Journal,
Journal Year:
2023,
Volume and Issue:
29(63)
Published: Sept. 4, 2023
A
mechanochemistry-driven
practical
and
efficient
synthetic
protocol
for
accessing
diverse
series
of
biologically
relevant
poly-functionalized
5-(arylselanyl)-1H-1,2,3-triazoles
through
copper(I)-catalyzed
click
reaction
between
aryl/heteroaryl
acetylenes,
diaryl
diselenides,
benzyl
bromides,
sodium
azide
has
been
accomplished
under
high-speed
ball-milling.
Advantages
this
method
include
operational
simplicity,
avoidance
using
solvent
external
heating,
one-pot
synthesis,
short
time
in
minutes,
good
to
excellent
yields,
broad
substrate
scope,
gram-scale
applications.
Furthermore,
synthesized
organoselenium
compounds
were
synthetically
diversified
promising
selenones.
Green Chemistry,
Journal Year:
2022,
Volume and Issue:
24(11), P. 4425 - 4431
Published: Jan. 1, 2022
An
electrochemical
protocol
for
the
synthesis
of
2,3-disubstituted
quinolines
by
reacting
benzoxazinones
with
arylsulfonyl
hydrazides
was
established
under
simple
and
mild
conditions
(room
temperature
an
undivided
cell).
New Journal of Chemistry,
Journal Year:
2022,
Volume and Issue:
46(28), P. 13483 - 13497
Published: Jan. 1, 2022
The
essence
of
photo-
and
electrochemistry:
sulfenylation
selenylation
substituted
benzo[
a
]phenazin-5-ols
through
cross-dehydrogenative
C(sp
2
)–H
functionalization.
SynOpen,
Journal Year:
2023,
Volume and Issue:
07(04), P. 511 - 520
Published: Oct. 1, 2023
Abstract
Electrochemical
synthesis,
due
to
its
environmentally
benign,
sustainable,
and
practical
nature,
has
become
an
appealing
powerful
substitute
for
traditional
methods
oxidizing
reducing
organic
compounds.
Thus,
numerous
valuable
changes
have
been
established
in
the
field
of
synthesis
through
utilization
electrochemistry.
Among
these
electrochemical
transformations,
formation
C–Se
bonds
stands
out
as
exceptionally
noteworthy
reaction
type.
In
this
graphical
review,
we
present
a
succinct
summary
progress
utilizing
strategies
synthesizing
organoselenium
Organic Chemistry Frontiers,
Journal Year:
2024,
Volume and Issue:
11(20), P. 5813 - 5819
Published: Jan. 1, 2024
In
this
paper,
we
have
developed
an
efficient
strategy
for
the
concise
synthesis
of
diverse
selenyl
imidazo[2,1-
b
]thiazinones
via
electrochemical
oxidative
three-component
tandem
reactions
in
absence
transition
metals,
and
oxidants.
RSC Advances,
Journal Year:
2025,
Volume and Issue:
15(5), P. 3273 - 3277
Published: Jan. 1, 2025
A
copper-catalyzed
oxygen
trifluoromethylation
of
o
-vinyl-
N
-alkylamide
using
Togni
reagent
as
the
trifluoromethyl
precursor
is
demonstrated
for
efficient
synthesis
trifluoromethyl-containing
iminoisobenzofurans.
The Journal of Organic Chemistry,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 12, 2025
Organoselenium
compounds
and
quinolines
are
widely
used
in
drugs
materials.
Herein,
we
report
an
electro-oxidative
cyclization
between
isocyanides
diselenides
to
effectively
synthesize
2-organoselenyl
a
simple
undivided
cell
without
transition-metal
catalysts
or
toxic
oxidants.
Gram-scale
synthesis
postsynthetic
modifications
highlighted
the
practicality
of
this
electrochemical
strategy.
A
series
produced
with
up
82%
yield,
good
functional
group
tolerance
high
atom
efficiency
under
room
temperature.
Advanced Synthesis & Catalysis,
Journal Year:
2024,
Volume and Issue:
366(5), P. 1152 - 1157
Published: Jan. 9, 2024
Abstract
This
research
presents
a
method
for
the
oxidative
selenylation
and
thiolylation
of
Morita‐Baylis‐Hillman
adducts
through
constant‐current
electrolysis
in
an
undivided
cell
at
room
temperature.
The
reaction
enables
direct
production
trisubstituted
(
Z
)‐allyl
aryl
selenides
sulfides
with
yields
27–98%.
A
wide
variety
different
functionalities
are
well
tolerated
under
these
conditions.
strategy
could
be
carried
out
on
gram
scale
several
synthetic
transformations
were
accomplished
construction
other
allyl
selenide
derivatives.
Control
experiments
mechanistic
studies
indicate
radical
or
ionic
addition
pathway
this
electrochemical
transformation.
ChemistrySelect,
Journal Year:
2024,
Volume and Issue:
9(5)
Published: Feb. 2, 2024
Abstract
A
practical
electrochemical
method
for
the
synthesis
of
β‐hydroxyselenides
has
been
developed
under
an
external
oxidant‐free
condition
at
room
temperature
air
from
alkenes
with
diselenides
and
H
2
O.
radical
mechanism
is
proposed
this
transformation
gram‐scale
reactions
demonstrate
practicability
reaction.
