Hexamethyldisilazane as a versatile organosilicon reagent for the synthesis of heterocycles (microreview) DOI
Guilherme Arraché Gonçalves, Pablo Machado

Chemistry of Heterocyclic Compounds, Journal Year: 2023, Volume and Issue: 59(8), P. 534 - 536

Published: Aug. 1, 2023

Language: Английский

Synthesis, X-ray, Hirshfeld Surface Analysis, Computational investigations, ADME investigations, and Insecticidal Activities using Docking Simulation of Kite-like 2,4,6-triarylpyridine DOI
Mona A. Shalaby, Mohammad H. BinSabt, Hamad M. Al‐Matar

et al.

Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: unknown, P. 140189 - 140189

Published: Sept. 1, 2024

Language: Английский

Citations

5
A new mixed-linker Fe-MOF as a multifunctional bio-photocatalyst for tandem photo-oxidation condensation reaction DOI
Majid Rouzifar, Sara Sobhani, Alireza Farrokhi

et al.

Journal of Photochemistry and Photobiology A Chemistry, Journal Year: 2023, Volume and Issue: 447, P. 115263 - 115263

Published: Oct. 13, 2023

Language: Английский

Citations

6
Mechanically robust, compressible, and photothermal silane/reduced graphene oxide modified plant fiber sponge for highly efficient cleanup of crude oil spill DOI
Yuhan Tang, Yongfeng Wang, Gang Zhao

et al.

Applied Surface Science, Journal Year: 2023, Volume and Issue: 648, P. 159052 - 159052

Published: Dec. 1, 2023

Language: Английский

Citations

6
Quantum-Chemical Study of the Assembly Mechanism of 1-Pyrrolines from N-Benzylaldimines and Arylacetylenes in KOtBu/DMSO Superbasic Medium DOI
Vladimir B. Orel, A. A. Zubarev, Ivan A. Bidusenko

et al.

The Journal of Organic Chemistry, Journal Year: 2023, Volume and Issue: 88(11), P. 7058 - 7069

Published: May 23, 2023

By using a quantum-chemical approach, B2PLYP-D2/6-311+G**//B3LYP/6-31+G*, we have carried out detailed study of the assembly 1-pyrrolines from N-benzyl-1-phenylmethanimine and phenylacetylene in superbasic medium KOtBu/dimethyl sulfoxide (DMSO). In this way, considered, both theoretically experimentally, mechanisms through concerted stepwise nucleophilic cycloaddition addressed side processes accompanying assembly. It is found that via kinetically more favorable than cycloaddition. At same time, reaction C-vinylation aldimine with occurs similar activation energy as leads to formation 2-aza-1,4-pentadiene. The anion 2-aza-1,4-pentadiene an intermediate for leading triarylpyridines 1,3-diarylpropan-1-ones. Triarylpyridines are formed next molecule 2-aza-1,4-pentadiene, while 1,3-diarylpropan-1-ones result hydrolysis 2-aza-1,4-pentadienes. mild conditions (60 °C, 15 min) relate complexes KOtBu/DMSO medium, where readily accessible attack by molecule.

Language: Английский

Citations

4
Acid-controlled multicomponent selective synthesis of 2,4,6-triaryl pyridines and pyrimidines by using hexamethyldisilazane as a nitrogen source under microwave irradiation DOI Creative Commons
Chieh‐Kai Chan,

Yi-Hsiu Chung,

Cheng‐Chung Wang

et al.

RSC Advances, Journal Year: 2022, Volume and Issue: 12(42), P. 27281 - 27291

Published: Jan. 1, 2022

Synthesis of pyrimidines and pyridines from commercially available ketones aldehydes by using hexamethyldisilazane as a nitrogen source controlled acids under microwave irradiation.

Language: Английский

Citations

6
Environmentally friendly Nafion-catalyzed synthesis of 3-substituted isoquinoline by using hexamethyldisilazane as a nitrogen source under microwave irradiation DOI
Tzu-Chun Lin, Chieh‐Kai Chan,

Yi-Hsiu Chung

et al.

Organic & Biomolecular Chemistry, Journal Year: 2023, Volume and Issue: 21(36), P. 7316 - 7326

Published: Jan. 1, 2023

This study developed an eco-friendly method to synthesize 3-arylisoquinoline from 2-alkynylbenzaldehydes using Nafion® NR50 as acidic catalyst and hexamethyldisilazane (HMDS) a nitrogen source. The reaction proceeded via 6-exo-dig cyclization under microwave irradiation, giving the corresponding isoquinolines in excellent yields. advantages of this protocol include: (1) use recyclable acid catalysts, (2) transition-metal-free catalysis, (3) effective formation target product. These features make methodology promising approach for sustainable efficient synthesis 3-arylisoquinoline. Some structures were also confirmed by single-crystal X-ray diffraction analysis.

Language: Английский

Citations

1
Novel practical stereoselective synthesis of a bicyclic hydantoino-thiolactone as the key intermediate for production of (+)-biotin DOI Creative Commons

L. Shu,

Zhiwei Yang,

Renxu Cao

et al.

RSC Advances, Journal Year: 2023, Volume and Issue: 13(37), P. 26160 - 26168

Published: Jan. 1, 2023

Bicyclic hydantoinothiolactone, as the key intermediate for production of (+)-biotin, has been efficiently and high-stereoselectively synthesized from cheap starting material l -cystine via nine steps in 44% overall yield.

Language: Английский

Citations

1
Engineering iodine decorated azo-bridged porous organic polymer: A brilliant catalyst for the preparation of 2,4,6-trisubstituted pyridines DOI
Morteza Torabi, Mohammad Ali Zolfigol,

Narges Zarei

et al.

Polymer, Journal Year: 2024, Volume and Issue: unknown, P. 127873 - 127873

Published: Nov. 1, 2024

Language: Английский

Citations

0
Hexamethyldisilazane as a versatile organosilicon reagent for the synthesis of heterocycles (microreview) DOI
Guilherme Arraché Gonçalves, Pablo Machado

Chemistry of Heterocyclic Compounds, Journal Year: 2023, Volume and Issue: 59(8), P. 534 - 536

Published: Aug. 1, 2023

Language: Английский

Citations

0