Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2023, Volume and Issue: 674, P. 131857 - 131857
Published: June 12, 2023
Language: Английский
Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2023, Volume and Issue: 674, P. 131857 - 131857
Published: June 12, 2023
Language: Английский
Inorganic Chemistry Frontiers, Journal Year: 2023, Volume and Issue: 10(5), P. 1543 - 1551
Published: Jan. 1, 2023
Ce-doped and MoS 2−x nanoflower arrays exhibit a high activity for electrocatalytic nitrate-to-ammonia conversion (NO 3 RR), attributed to the synergy of S-vacancy Ce-dopant enhance NO − activation reduce reaction energy barriers.
Language: Английский
Citations
52Applied Catalysis B Environment and Energy, Journal Year: 2023, Volume and Issue: 330, P. 122627 - 122627
Published: March 14, 2023
Language: Английский
Citations
48Journal of Colloid and Interface Science, Journal Year: 2023, Volume and Issue: 652, P. 155 - 163
Published: Aug. 12, 2023
Language: Английский
Citations
44Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 659, P. 432 - 438
Published: Jan. 4, 2024
Language: Английский
Citations
37Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 481, P. 148733 - 148733
Published: Jan. 13, 2024
Language: Английский
Citations
33Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 481, P. 148734 - 148734
Published: Jan. 14, 2024
Language: Английский
Citations
33ACS Sustainable Chemistry & Engineering, Journal Year: 2024, Volume and Issue: 12(7), P. 2783 - 2789
Published: Feb. 2, 2024
Electrochemical nitrite-to-ammonia reduction (NO2RR) holds great promise for converting harmful NO2– into valuable NH3. Herein, we develop Co single atoms dispersed on a C3N4 substrate (Co1/C3N4) as an efficient catalyst toward the NO2RR. Experimental and theoretical investigations reveal that single-atom sites can effectively active optimize formation energy of key *NOH intermediate to promote → NH3 energetics. Remarkably, Co1/C3N4 equipped in flow cell delivers exceptional NH3–Faradaic efficiency 97.9% yield rate 1080.3 μmol h–1cm–2 at industrial-level current density 355 mA cm–2, along with long-term durability 100 h electrolysis, showing considerable potential practical electrosynthesis.
Language: Английский
Citations
31Journal of Energy Chemistry, Journal Year: 2024, Volume and Issue: 92, P. 459 - 483
Published: Jan. 4, 2024
Language: Английский
Citations
25Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 489, P. 151410 - 151410
Published: April 17, 2024
Language: Английский
Citations
21Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 492, P. 152124 - 152124
Published: May 10, 2024
In this work, we report the preparation of one-dimensional (1D) bimetallic zinc-cobalt BTC (BTC = 1,3,5-benzenetricarboxylate) metal–organic frameworks (MOFs) with varying Zn/Co ratios and their conversion to hierarchical porous Co/C hybrids a trace amount Zn (<0.05 wt%). The crystallinity, surface area, degree graphitization resulting hybrid are governed by ratio parent Zn-Co MOF. product derived from Zn-rich MOF (ZC31-BTC precursor 3:1) shows higher area more amorphous structure than that Co-rich (ZC13-BTC 1:3). When used for electrochemical sensing dopamine (DA), glassy carbon electrode (GCE) modified ZC31-BTC700°C carbonized at 700 °C) sensitivity 0.0995nA nM−1 cm−2, wide linear range 0.1–500 µM, low limit detection (LoD) 0.04 µM (signal-to-noise (S/N) 3). superior DA performance is attributed its high density defects (evidenced ID/IG ratio), rich mesopores (including small (<5 nm) large (>5 nm)), leading improved ion/electron transfer (based on EIS analysis), electrochemically active sites (confirmed ECSA measurements) promote greater oxidation molecules. anti-interference test ZC31-BTC700°C-modified GCE (ZC31-BTC700°C/GCE) indicates selectivity toward even in presence interferents, such as glucose, ascorbic acid, uric acid. Moreover, stability good retainment current response ZC31-BTC700°C/GCE over period 2 weeks.
Language: Английский
Citations
21