Photovoltaic performances and morphological adjustment of A-π-D'AD-π-A electron-acceptors with twisted backbone DOI
Jiahao Liu, Shujuan Liu,

Weiping Wang

et al.

Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 142252 - 142252

Published: March 1, 2025

Language: Английский

The literature of heterocyclic chemistry, part XXII, 2022 DOI
Галина А. Газиева, Yu. B. Evdokimenkova, N. O. Soboleva

et al.

Advances in heterocyclic chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Language: Английский

Citations

0
Photovoltaic Performances and Morphological Adjustment of A-Π-D’Ad-Π-A Electron-Acceptors with Twisted Backbone DOI
Jiahao Liu, Shujuan Liu,

Weiping Wang

et al.

Published: Jan. 1, 2025

Language: Английский

Citations

0
Advanced Strategy for High-Performance A-D-A′-D-A Type Non-Fused Ring Electron Acceptors with Nitrogen Heterocyclic Cores DOI
Yang Jiang, Chuang Yao,

Yezi Yang

et al.

The Journal of Physical Chemistry B, Journal Year: 2025, Volume and Issue: 129(11), P. 3109 - 3119

Published: March 6, 2025

The development of nonfused ring electron acceptors (NFREAs) has garnered significant attention due to their simplified molecular design and cost-effectiveness. Recent advancements have pushed the power conversion efficiency (PCE) NFREAs beyond 19%. Despite these advantages, most adopt A-D-A structures, where electron-donating core is typically a benzene substituted with fluorine or alkoxy groups. This restricts tunability energy levels, selection substituents for rings as central units relatively constrained, which hampers further optimization material properties. In this work, we designed three A-D-A′-D-A structured fully featuring distinct nitrogen heterocyclic cores: linear-shaped TT, star-shaped TYT, quad-rotor-shaped TTVP. nitrogen-containing aromatic units, strong electron-withdrawing groups, enable precise tuning levels. Moreover, cores enhance rigidity, facilitating efficient π–π stacking improving mobility. Although share identical π-bridges terminal unique exert divergent effects on photovoltaic performance. Theoretical calculations reveal that TT TTVP exhibit higher affinity, greater absorption intensity, lower exciton binding energy, mobility compared high-performance reference NFREA, TBT-26. Notably, TTVP, an four exhibits exceptional electronic It achieves highest narrowest bandgap 1.76 eV, predicted 4.43 × 10–4 cm2 V–1 s–1, surpassing These findings underscore potential in diversifying NFREA advancing next-generation NFREAs.

Language: Английский

Citations

0
Effects of non-fused and fused substituents in quinoxaline-based central units on conformation, aggregation, and photovoltaic properties of non-fused ring electron acceptors DOI
Kenta Yamada, Wataru Suzuki,

Motohisa Kubota

et al.

Journal of Materials Chemistry C, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Substituents of the quinoxaline core influence aggregation properties S-shaped acceptors.

Language: Английский

Citations

0
Photovoltaic performances and morphological adjustment of A-π-D'AD-π-A electron-acceptors with twisted backbone DOI
Jiahao Liu, Shujuan Liu,

Weiping Wang

et al.

Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 142252 - 142252

Published: March 1, 2025

Language: Английский

Citations

0