Highly crystalline multi-component covalent organic frameworks for photocatalytic organic conversion DOI

Meng Lei,

Yuting Xue, Linfeng Gan

et al.

Molecular Catalysis, Journal Year: 2025, Volume and Issue: 577, P. 114976 - 114976

Published: March 5, 2025

Language: Английский

Advances of MOFs and COFs for photocatalytic CO2 reduction, H2 evolution and organic redox transformations DOI Open Access
Tian Luo, Leisan Gilmanova, Stefan Kaskel

et al.

Coordination Chemistry Reviews, Journal Year: 2023, Volume and Issue: 490, P. 215210 - 215210

Published: May 21, 2023

Language: Английский

Citations

126
Reticular framework materials for photocatalytic organic reactions DOI
Ning‐Yu Huang,

Yu‐Tao Zheng,

Di Chen

et al.

Chemical Society Reviews, Journal Year: 2023, Volume and Issue: 52(22), P. 7949 - 8004

Published: Jan. 1, 2023

Photocatalytic organic reactions, harvesting solar energy to produce high value-added chemicals, have attracted increasing attention as a sustainable approach address the global crisis and environmental issues. Reticular framework materials, including metal-organic frameworks (MOFs) covalent (COFs), are widely considered promising candidates for photocatalysis owing their crystallinity, tailorable pore environment extensive structural diversity. Although design synthesis of MOFs COFs been intensively developed in last 20 years, applications photocatalytic transformations still preliminary stage, making systematic summary necessary. Thus, this review aims provide comprehensive understanding useful guidelines exploration suitable MOF COF photocatalysts towards appropriate reactions. The commonly used reactions categorized facilitate identification reaction types. From practical viewpoint, fundamentals experimental design, active species, performance evaluation external conditions, discussed detail easy experimentation. Furthermore, latest advances COFs, composites, comprehensively summarized according actual sites, together with discussion structure-property relationship. We believe that study will be helpful researchers novel reticular various synthetic applications.

Language: Английский

Citations

104
Regulating Keto–Enol Tautomerism of β-Ketoenamine Covalent–Organic Frameworks for Photocatalytic Oxidative Coupling of Amines DOI

Feng Chu,

Guangtong Hai,

Danfeng Zhao

et al.

ACS Catalysis, Journal Year: 2023, Volume and Issue: 13(20), P. 13167 - 13180

Published: Sept. 28, 2023

Covalent–organic frameworks (COFs), as promising metal-free porous catalysts, have become a hot research topic in the field of (photo)catalysis. Herein, series β-ketoenamine COFs are synthesized using different amino and aldehyde monomers, these exhibit diverse characteristics terms crystallinity, chemical structure, microscopic morphology, optoelectronic properties. TpBD-(CH3)2 from 2,4,6-triformylphloroglucinol o-tolidine exhibits an extended π-conjugated structure higher crystallinity well more suitable redox potential, which greatly enhances photocatalytic activity benzylamine oxidation. Besides, increased number hydroxyl groups on trialdehyde-based monomer contributes to ketoamines TpTAB skeleton, is favorable for photocatalysis. Meanwhile, can rapidly increase their own temperature through internal structural evolution under light irradiation, thus boosting oxidative coupling amines with high efficiency. This work could provide some guidance rational design functional advanced organic transformations.

Language: Английский

Citations

55
Donor-acceptor-based conjugated polymers for photocatalytic energy conversion DOI
Chao Yang, Bei Cheng, Jingsan Xu

et al.

EnergyChem, Journal Year: 2023, Volume and Issue: 6(1), P. 100116 - 100116

Published: Nov. 29, 2023

Language: Английский

Citations

54
Semiconductor cooperative photocatalysis with TEMPO DOI

Fengwei Huang,

Fulin Zhang,

Yuexin Wang

et al.

Trends in Chemistry, Journal Year: 2024, Volume and Issue: 6(3), P. 115 - 127

Published: Feb. 20, 2024

Language: Английский

Citations

21
Thiazole-linked isomeric covalent organic frameworks for divergent photocatalysis: Selective oxidation of organic sulfides DOI

Yuexin Wang,

Fulin Zhang,

Fengwei Huang

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 354, P. 124103 - 124103

Published: April 21, 2024

Language: Английский

Citations

19
Efficient dual-pathway H2O2 production promoted by covalent triazine frameworks with integrated dual active sites DOI
Shasha Liu, Chao Zhu, Junjie Xu

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2023, Volume and Issue: 344, P. 123629 - 123629

Published: Dec. 16, 2023

Language: Английский

Citations

34
Imine-linked 2D covalent organic frameworks based on benzotrithiophene for visible-light-driven selective aerobic sulfoxidation DOI Creative Commons

Fengwei Huang,

Yuexin Wang,

Xiaoyun Dong

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(12), P. 7036 - 7046

Published: Jan. 1, 2024

An imine-linked covalent organic framework based on benzotrithiophene generates superoxide and singlet oxygen to carry out blue-light-driven selective aerobic sulfoxidation.

Language: Английский

Citations

14
Electron-donating five-membered heterocyclic modulated electronic states boosting visible-light-driven H2O2 production DOI
Tao Gao, Yang Chen, Yong Zheng

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 346, P. 123761 - 123761

Published: Jan. 22, 2024

Language: Английский

Citations

11
A critical review on emerging photoactive porous materials for sulfide oxidation and sulfur mustard decontamination DOI
Priyanka Kalita, Ratul Paul, Ankita Boruah

et al.

Green Chemistry, Journal Year: 2023, Volume and Issue: 25(15), P. 5789 - 5812

Published: Jan. 1, 2023

Chemical warfare agents (CWAs) have been classified as fatal weapons of mass destruction because their toxicity and deadly consequences.

Language: Английский

Citations

21