Efficient hydrogen splitting via single atom catalysts supported on Zn12O12 nanocage for sustainable clean fuel production DOI
Ali Hussain, Muhammad Yar, Rayed S. Alshareef

et al.

International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 58, P. 806 - 821

Published: Jan. 29, 2024

Language: Английский

Rare-earth La-doped VS2−xfor electrochemical nitrate reduction to ammonia DOI
Guohui Wang, Peng Shen, Kai Chen

et al.

Inorganic Chemistry Frontiers, Journal Year: 2023, Volume and Issue: 10(7), P. 2014 - 2021

Published: Jan. 1, 2023

A rare-earth La-doped VS 2−x is reported as an effective catalyst for electrocatalytic nitrate-to-ammonia conversion, which attributed to the synergy of La-dopants and S-vacancies promote NO 3 RR suppress hydrogen evolution.

Language: Английский

Citations

36
PdP2 Nanoparticles on Reduced Graphene Oxide: A Catalyst for the Electrocatalytic Reduction of Nitrate to Ammonia DOI
Guohui Wang, Ying Zhang, Kai Chen

et al.

Inorganic Chemistry, Journal Year: 2023, Volume and Issue: 62(17), P. 6570 - 6575

Published: April 19, 2023

Palladium phosphides are explored as efficient catalysts for the electrocatalytic reduction of nitrate to ammonia (NRA). The PdP2 nanoparticles on reduced graphene oxide exhibit maximum NH3 Faradaic efficiency 98.2% with a corresponding yield rate 7.6 mg h–1 cm–2 at −0.6 V (RHE). Theoretical calculations reveal that (011) surface can not only effectively activate and hydrogenate NO3– via NOH pathway but also retard H adsorption inhibit competitive hydrogen evolution reaction.

Language: Английский

Citations

34
A metal-free catalyst for electrocatalytic NO reduction to NH3 DOI
Guike Zhang,

Yuying Wan,

Hongyan Zhao

et al.

Dalton Transactions, Journal Year: 2023, Volume and Issue: 52(19), P. 6248 - 6253

Published: Jan. 1, 2023

Metal-free boron phosphide (BP) is explored for the first time as an effective catalyst electrocatalytic NO reduction to NH3, showing a high NH3-faradaic efficiency of 83.3% with NH3 yield rate 96.6 μmol h-1 cm-2, surpassing most metal-based catalysts. Theoretical results reveal that B and P atoms BP can serve dual-active centers synergistically activate NO, promote NORR hydrogenation process inhibit competing hydrogen evolution reaction.

Language: Английский

Citations

33
Synergistic double-atom catalysts of metal-boron anchored on g-C2N for electrochemical nitrogen reduction: Mechanistic insight and catalyst screening DOI Creative Commons
Yang Li, Wei An

Journal of Energy Chemistry, Journal Year: 2023, Volume and Issue: 80, P. 350 - 360

Published: Feb. 15, 2023

Language: Английский

Citations

29
Graphene-based iron single-atom catalysts for electrocatalytic nitric oxide reduction: a first-principles study DOI
Haobo Li, Donghai Wu,

Jiarui Wu

et al.

Nanoscale, Journal Year: 2024, Volume and Issue: 16(14), P. 7058 - 7067

Published: Jan. 1, 2024

The electrocatalytic NO reduction reaction (NORR) emerges as an intriguing strategy to convert harmful into valuable NH

Language: Английский

Citations

18
Nucleobases adsorption studies on chair graphane nanosheets – A DFT outlook DOI

V. Nagarajan,

R. Nivedhana,

R. Chandiramouli

et al.

Inorganic Chemistry Communications, Journal Year: 2023, Volume and Issue: 152, P. 110683 - 110683

Published: April 11, 2023

Language: Английский

Citations

23
Interaction studies of propylene and butadiene on tricycle graphane nanosheet – A DFT outlook DOI

V. Nagarajan,

R. Bhuvaneswari,

R. Chandiramouli

et al.

Journal of Molecular Graphics and Modelling, Journal Year: 2023, Volume and Issue: 121, P. 108449 - 108449

Published: March 13, 2023

Language: Английский

Citations

21
Unlocking the potential of alkaline-earth metal active centers for nitrogen activation and ammonia synthesis: the role of s–d orbital synergy DOI
Donghai Wu,

Jiarui Wu,

Haobo Li

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(7), P. 4278 - 4289

Published: Jan. 1, 2024

N 2 can be activated via s–d orbital synergy of AE metal active centers, i.e. , metals's orbitals share electrons with their empty d orbitals, and then the partially occupied exchange σ π* .

Language: Английский

Citations

9
Advancements in Single Atom Catalysts for Electrocatalytic Nitrate Reduction Reaction DOI
Lingyue Liu, Shourong Zheng

ChemCatChem, Journal Year: 2024, Volume and Issue: 16(15)

Published: Jan. 23, 2024

Abstract Due to the urgent demand for nitrate wastewater treatment, quest an efficient and environmentally friendly treatment method has emerged as a new research focus. The utilization of single‐atom catalysts (SACs) in electrocatalytic reduction reaction (NO 3 RR) ammonia production is presently recognized effective strategy address pollution issues obtain high value‐added products. In this review, we summarized recent advancements NO RR based on SACs. This review includes comprehensive analysis identification structural determination techniques SACs, well mechanism over Furthermore, investigates impact regulating single atom structures RR, providing valuable insights enhancing efficiency. It explores application in‐situ technology real‐time monitoring control RR. Finally, perspectives challenges regarding SACs are presented. Overall, extensive offers researchers industry professionals field environmental catalysis.

Language: Английский

Citations

9
Progress, challenges, and prospects with electrocatalyst (From transition metal oxides to dual-atom catalysts) for oxygen reduction reaction DOI
Teddy Mageto, Sanket Bhoyate, Anuj Kumar

et al.

Molecular Catalysis, Journal Year: 2024, Volume and Issue: 562, P. 114196 - 114196

Published: May 7, 2024

Language: Английский

Citations

7