Chemical Society Reviews,
Journal Year:
2024,
Volume and Issue:
53(10), P. 5014 - 5053
Published: Jan. 1, 2024
This
review
highlights
the
preparation
and
regulation
strategies
of
alumina
materials
from
different
dimensions
summarizes
preparation,
metal–support
interaction,
application
Pd/Al
2
O
3
catalysts
on
important
industrial
catalysis.
Angewandte Chemie International Edition,
Journal Year:
2024,
Volume and Issue:
63(23)
Published: April 3, 2024
Abstract
Two‐electron
oxygen
reduction
reaction
(2e
−
ORR)
is
a
promising
method
for
the
synthesis
of
hydrogen
peroxide
(H
2
O
).
However,
high
energy
barriers
generation
key
*OOH
intermediates
hinder
process
2e
ORR.
Herein,
we
prepared
copper‐supported
indium
selenide
catalyst
(Cu/In
Se
3
)
to
enhance
selectivity
and
yield
ORR
by
employing
an
electronic
metal–support
interactions
(EMSIs)
strategy.
EMSIs‐induced
charge
rearrangement
between
metallic
Cu
In
conducive
intermediate
generation,
promoting
H
production.
Theoretical
investigations
reveal
that
inclusion
significantly
lowers
barrier
impedes
4e
pathway,
thus
favoring
formation
.
The
concentration
produced
Cu/In
~2
times
than
,
shows
applications
in
antibiotic
degradation.
This
research
presents
valuable
approach
future
utilization
EMSIs
Small,
Journal Year:
2024,
Volume and Issue:
20(44)
Published: July 10, 2024
Single-atom
catalysts
(SACs),
combining
the
advantages
of
multiphase
and
homogeneous
catalysis,
have
been
increasingly
investigated
in
various
catalytic
applications.
Carbon-based
SACs
attracted
much
attention
due
to
their
large
specific
surface
area,
high
porosity,
particular
electronic
structure,
excellent
stability.
As
a
cheap
readily
available
carbon
material,
biochar
has
begun
be
used
as
an
alternative
nanotubes,
graphene,
other
such
expensive
matrices
prepare
SACs.
However,
review
biochar-based
for
environmental
pollutant
removal
energy
conversion
storage
is
lacking.
This
focuses
on
strategies
synthesizing
SACs,
pre-treatment
organisms
with
metal
salts,
insertion
elements
into
biochar,
or
pyrolysis
metal-rich
biomass,
which
are
more
simplistic
ways
Meanwhile,
this
paper
attempts
1)
demonstrate
applications
remediation
based
advanced
oxidation
technology
electrocatalysis;
2)
reveal
mechanism
different
systems;
3)
discuss
stability
SACs;
4)
present
future
developments
challenges
regarding
Nano Letters,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 15, 2025
Establishing
optimized
metal–support
interaction
(MSI)
between
active
sites
and
the
substrate
is
essential
for
modulating
adsorption
properties
of
key
reaction
intermediates
during
catalysis,
thereby
enhancing
catalytic
performance.
In
this
study,
catalyst
composites
with
varying
degrees
MSI
are
constructed
using
ruthenium
(Ru)
different
carbon
nanotubes,
their
performance
alkaline
hydrogen
evolution
(HER)
systematically
investigated.
Detailed
kinetic
assessments
reveal
that
catalysts
a
strong
exhibit
superior
HER
activity.
For
instance,
Ru-O-CNT
composite
demonstrates
an
encouragingly
low
overpotential
11
mV
at
10
mA
cm–2
excellent
stability.
Electrochemical
voltammetry
analysis
indicates
effective
optimizes
binding
strength
both
*H
*OH,
accelerating
process.
Furthermore,
we
showcase
industrial-level
electrolyzer,
assembled
as
cathodic
catalyst,
achieves
impressive
cell
voltage
1.72
V
high
stability
current
density
1
A
cm–2.
Advanced Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 13, 2025
Abstract
Electrosynthesis
of
hydrogen
peroxide
(H
2
O
)
via
two‐electron
oxygen
reduction
reaction
(2e
−
ORR)
is
a
promising
alternative
to
the
anthraquinone
oxidation
process.
To
improve
overall
energy
efficiency
and
economic
viability
this
catalytic
process,
one
pathway
develop
advanced
catalysts
decrease
overpotential
at
cathode,
other
couple
2e
ORR
with
certain
anodic
reactions
full
cell
voltage
while
producing
valuable
chemicals
on
both
electrodes.
The
performance
catalyst
depends
not
only
material
itself
but
also
environmental
factors.
Developing
electrocatalysts
high
selectivity
activity
prerequisite
for
efficient
H
electrosynthesis,
coupling
appropriate
would
further
enhance
efficiency.
Considering
this,
here
comprehensive
review
presented
latest
progress
state‐of‐the‐art
in
different
media,
microenvironmental
modulation
mechanisms
beyond
design,
as
well
electrocatalytic
system
various
reactions.
This
presents
new
insights
regarding
existing
challenges
opportunities
within
rapidly
advancing
field,
along
viewpoints
future
development
electrosynthesis
construction
green
roadmaps.
EES Catalysis,
Journal Year:
2023,
Volume and Issue:
2(1), P. 180 - 201
Published: Sept. 15, 2023
Photocatalytic
nitrogen
reduction
using
inexhaustible
solar
energy
has
been
considered
as
a
promising
strategy
for
NH
3
synthesis.
The
design
of
heterogeneous
photocatalysts
with
tunable
MSIs
is
great
significance.
