Ionics, Journal Year: 2024, Volume and Issue: 30(4), P. 2375 - 2385
Published: Feb. 6, 2024
Language: Английский
Ionics, Journal Year: 2024, Volume and Issue: 30(4), P. 2375 - 2385
Published: Feb. 6, 2024
Language: Английский
The Journal of Physical Chemistry Letters, Journal Year: 2025, Volume and Issue: unknown, P. 2914 - 2919
Published: March 11, 2025
Metal-organic frameworks (MOFs) have emerged as promising templates and precursors that can be converted to a series of functional materials. Probing the dynamic conversion processes within individual MOF crystal particles in real-time is key understanding structure-activity relationship, but this remains challenging, particularly for anisotropic crystals. Here, using dark-field optical microscopy, we visually situ image quantify oxidation single bismuth-based metal-organic framework (Bi-MOF) into bismuth oxides by NaClO. The reactivity rod-shaped Bi-MOFs anisotropic, its two ends higher activity than those middle regions, which depend on aspect ratio. Through analysis channel directions theoretical diffusion coefficients, behavior may attributed inherently low barrier NaClO oxidant due larger accessible rectangular channels at both along c-axis. Our findings unveil comprehensive kinetic information about reaction subparticle level, favoring design future MOF-derived
Language: Английский
Citations
0Polymer Degradation and Stability, Journal Year: 2025, Volume and Issue: unknown, P. 111349 - 111349
Published: March 1, 2025
Language: Английский
Citations
0Microstructures, Journal Year: 2025, Volume and Issue: 5(3)
Published: April 25, 2025
Photocatalysis plays a pivotal role in sustainable technology, driving pollutant degradation and energy conversion through solar-driven chemical reactions. However, conventional photocatalysts are limited by their structural tunability, hindering adaptability to evolving photocatalytic applications. This underscores the urgent need for innovative approaches overcome these challenges. Metal-organic frameworks (MOFs), with tunable structures, offer promising solution overcoming limitations. Here, we demonstrate comprehensive overview of regulation strategies MOFs, emphasizing evolution across multiple scales enhance performance. review begins detailing photoelectric characteristics MOFs development effectiveness. An in-depth analysis is undertaken into - macroscale, mesoscale, atomic-scale, electronic-scale. The synergistic interactions among levels further explored, revealing collective contribution improved efficiency. These insights emphasize that adaptable design serve as pathways advancements photocatalyst engineering. Finally, examine current applications structures provide perspectives on future challenges this field. offers critical MOF regulation, highlighting its innovations expanding technologies.
Language: Английский
Citations
0Environmental Science and Pollution Research, Journal Year: 2024, Volume and Issue: 31(6), P. 9764 - 9783
Published: Jan. 9, 2024
Language: Английский
Citations
3Ionics, Journal Year: 2024, Volume and Issue: 30(4), P. 2375 - 2385
Published: Feb. 6, 2024
Language: Английский
Citations
3