Synthesis of fluorinated spiro-1,3-oxazines and spiro-1,3-thiazines via Selectfluor-mediated intramolecular spirocyclization
Chinu Gogoi,
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Ujwal Pratim Saikia,
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Priyam Borah
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et al.
Organic & Biomolecular Chemistry,
Journal Year:
2024,
Volume and Issue:
22(32), P. 6485 - 6489
Published: Jan. 1, 2024
A
fluorination-induced
intramolecular
cyclization
for
the
synthesis
of
fluoro-substituted
spiro-1,3-oxazine
and
spiro-1,3-thiazine
derivatives
is
described.
Language: Английский
Direct synthesis of spirooxindoles enabled by palladium-catalyzed allylic alkylation and DBU-mediated cyclization: concept, scope and applications
Fen Tan,
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Xiaoyu He,
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Qiao-Qiao Zhou
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et al.
Organic Chemistry Frontiers,
Journal Year:
2024,
Volume and Issue:
11(19), P. 5443 - 5453
Published: Jan. 1, 2024
A
concise
construction
of
spiro[indoline-3,2′-pyrrol]-2-one
skeletons
is
reported.
This
reaction
proceeded
through
a
palladium-catalyzed
decarboxylative
allylic
alkylation
followed
by
DBU-mediated
intramolecular
cyclization.
Language: Английский