Mechanochemical Synthesis of Yttrium Oxide and Hydrogen Peroxide via Planetary Ball Milling With Nickel Catalyst: Structural, Morphological, and Particle Size Analysis DOI Creative Commons
Andika Widya Pramono,

Mohamed Ansari,

Meenaloshini a p Sagutnam

et al.

Research Square (Research Square), Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 31, 2024

Abstract This study investigates the mechanochemical synthesis of Yttrium Oxide (Y₂O₃) and Hydrogen Peroxide (H₂O₂) via planetary ball milling, with a focus on catalytic effect nickel. Hydride (YH₃) was milled under hydrogen atmosphere, both without nickel catalyst, to assess influence various process parameters such as milling time, pressure, catalyst presence phase transformation, crystallite size, particle morphology, size distribution. X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), laser analysis (PSA) were used characterize samples. Results show that catalysis significantly enhances reaction kinetics, reduces promotes uniform morphology compared non-catalyzed Catalyzed samples exhibited faster transformation from YH₃ Y₂O₃, reduction 11.0 nm near-complete formation Y₂O₃ H₂O₂. These findings demonstrate nickel-catalyzed offers an efficient scalable route for synthesis, potential applications in catalysis, storage, environmental remediation. Further research optimizing conditions exploring other catalysts is recommended.

Language: Английский

Navigating Ball Mill Specifications for Theory‐to‐Practice Reproducibility in Mechanochemistry DOI Creative Commons
Orein F. Jafter, Sol Lee, Jongseong Park

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(48)

Published: Aug. 16, 2024

Abstract The rising prospects of mechanochemically assisted syntheses hold promise for both academia and industry, yet they face challenges in understanding and, therefore, anticipating respective reaction kinetics. Particularly, dependencies based on variations milling equipment remain little understood globally overlooked. This study aims to address this issue by identifying critical parameters through kinematic models, facilitating the reproducibility mechanochemical reactions across most prominent mills laboratory settings, namely planetary mixer mills. Through a series selected experiments replicating major classes organic, organometallic, transition metal‐catalyzed, inorganic from literature, we rationalize independence kinetics when accumulated energy criterion is met. As step forward facilitate practicability our findings, provide freely accessible online tool [†] that allows calculation different Our work advances current mechanochemistry lays foundation future rational exploration rapidly evolving field.

Language: Английский

Citations

10
In situ investigation of controlled polymorphism in mechanochemistry at elevated temperature DOI Creative Commons
Kevin Linberg,

Philipp C. Sander,

Franziska Emmerling

et al.

RSC Mechanochemistry, Journal Year: 2024, Volume and Issue: 1(1), P. 43 - 49

Published: Jan. 1, 2024

Through thermo-mechanochemical conditions it is possible to generate metastable crystal forms below equilibrium thermodynamic transition temperatures, making thermo-mechanical an exciting new direction for solid form control.

Language: Английский

Citations

7
Application of Bertagnini's Salts in a Mechanochemical Approach Toward Aza‐Heterocycles and Reductive Aminations via Imine Formation DOI Creative Commons
Sourav Behera, Shyamal Kanti Bera, Francesco Basoccu

et al.

Advanced Synthesis & Catalysis, Journal Year: 2024, Volume and Issue: 366(9), P. 2035 - 2043

Published: Feb. 8, 2024

Abstract Our research has demonstrated that mechanochemical activation is more effective with solid reagents. We have showcased the practicality of Bertagnini's salts, also called aldehyde‐bisulfite adducts, which are crystalline, simplifying preparation and storage. These salts stable substitutes for liquid aldehydes ketones been employed in reductive amination, synthesizing aza‐heterocycles hydrazones within mechanochemistry. The technique‘s effectiveness broadens substrate scopes, simplifies purification, reduces reaction times, yields desired products ranging from 38–91%. Additionally, thermal stability bisulfite adducts confirmed through TGA (Thermogravimetric analysis) analysis.

Language: Английский

Citations

3
Listening to the Formation of Polymorphs in a Ball Mill DOI Creative Commons

Éloïse Marie Samantha Parlier,

Kinann Al Amir,

Thomas‐Xavier Métro

et al.

Analytical Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 27, 2025

In this contribution, we apply our newly developed ball-milling operando platform, which combines Raman spectroscopy and thermal (IR) imaging, as well acoustic high-speed optical video recordings, to the synthesis transformation of citric acid–isonicotinamide (1:2) cocrystal polymorphs in transparent PMMA jars. Particularly, demonstrate how Raman, temperature, acoustic, data are complementary enable detection connection chemical physical events happening during a time-resolved manner. Importantly, show that formation three can be detected through analyses solely. Even more impressively, meticulous sound allowed subtle polymorphic transitions perceived mode when was not conclusive enough. Such changes signatures greatly linked beads' motions milling jar. A new analysis methodology recordings is proposed combination energetic statistical approaches simplifies for potential users. The interpretation signals further validated thanks videos recorded synchronization with all other techniques. Finally, broaden opaque stainless-steel jars, showing relevance method following transformations cocrystals, pure substances, any type

Language: Английский

Citations

0
Description of method DOI
Davor Margetić

Elsevier eBooks, Journal Year: 2025, Volume and Issue: unknown, P. 15 - 51

Published: Jan. 1, 2025

Language: Английский

Citations

0
Capturing and Labeling CO2 in a Jar: Mechanochemical 17O-Enrichment and ssNMR Study of Sodium and Potassium (bi)carbonate Salts DOI Creative Commons
Austin A. Peach, Nicolas Fabrègue,

Célia Erre

et al.

Chemical Science, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

With the rapid increase in temperatures around planet, need to develop efficient means reduce CO2 emissions has become one of greatest challenges scientific community. Many different strategies are being studied worldwide, which consists trapping gas porous materials, either for its short- or long-term capture and storage, re-use production value-added compounds. Yet, further development such systems, there is a real fully understand their structure properties, including at molecular-level following physisorption and/or chemisorption (which can lead various species, carbonate bicarbonate ions). In this context, 17O NMR naturally appears as analytical tool choice, because exquisite sensitivity probe subtle differences oxygen bonding environments. To date, it scarcely been used, due very low natural abundance (0.04%), difficulty purchasing obtaining commercial 17O-labeled compounds adapted investigations (e.g., 17O-CO2(g), 17O-enriched Na- K-(bi)carbonate salts, be readily transformed into CO2). Herein, we demonstrate how, using mechanochemistry, possible enrich with variety salts fast, economical, scalable, user-friendly way. The high enrichment levels enabled recording first high-resolution ssNMR spectra these phases magnetic fields. From these, typical spectral signatures (bi)carbonate ions could obtained, showing strong local environments dynamics. Lastly, show how thanks selective 17O-labeling, other aspects reactivity carbonates materials unveiled situ ssNMR. long run, expected that work will open way more profound properties carbon storage and, generally speaking, functional containing carbonates.

Language: Английский

Citations

0
Ball milling for mechanochemical reactions DOI
Isaiah R. Speight, Karen J. Ardila‐Fierro, José G. Hernández

et al.

Nature Reviews Methods Primers, Journal Year: 2025, Volume and Issue: 5(1)

Published: May 22, 2025

Language: Английский

Citations

0
Supramolecular intermediates in thermo-mechanochemical direct amidations DOI Creative Commons
Tomislav Stolar, Jasna Alić, Gregor Talajić

et al.

Chemical Communications, Journal Year: 2023, Volume and Issue: 59(90), P. 13490 - 13493

Published: Jan. 1, 2023

We present a solvent-free thermo-mechanochemical approach for the direct coupling of carboxylic acids and amines, which avoids activators additives. Non-covalent interactions between reagents guide formation amide bond.

Language: Английский

Citations

8
Efficient Racemization of the Pharmaceutical Compound Levetiracetam using Solvent Free Mechanochemistry DOI Creative Commons
Chrystal Lopes, Lucia Casali, Franziska Emmerling

et al.

RSC Mechanochemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 31, 2024

An effective and fast solvent-free mechanochemical racemization of an API by controlling experimental key parameters.

Language: Английский

Citations

1
Hydrocarbons, Hydrogen, and Organic Acids Generation by Ball Milling and Batch Incubation of Sedimentary Rocks DOI Creative Commons
Alexander Arthur Haluska,

Eva Blendinger,

Hermann Rügner

et al.

Applied Geochemistry, Journal Year: 2024, Volume and Issue: 178, P. 106160 - 106160

Published: Sept. 3, 2024

Pulverized rock samples are widely used in laboratory experiments, e.g., to assess microbial or abiotic processes batch incubation tests. However, it is unclear if ball-milled accurately reflect in-situ conditions and observed affected by by-products artificially generated during the sample preparation procedure. As such, this study examined effects of dry ball milling on release gases, which include C1-C4 hydrocarbons, carbon dioxide (CO2), hydrogen (H2), low molecular weight organic acids (LMWOAs) from different sedimentary rocks. The experiments involved pulverization using a gas-tight zirconium oxide planetary mill followed wet thermal desorption up 200 o C. During milling, all rocks, except sandstone sample, yielded methane (CH4), ethane (C2H6), propane (C3H8), butane (C4H10), H2, CO2, unsaturated ethene (C2H4). Sandstones only CH4, CO2. Stable isotope signatures these products similar thermogenic gases. gases were also detected subsequent (after had been removed). Additionally, formate, acetate, citrate, for sandstone. Pyruvate, malate, succinate some samples. Thermal powdered limestone, shale, pyrite concretion included acids, such as acetate higher milled than crushed particles (∼1 mm). original geological maturity studied was (below "oil window") and, thus, considerably below "gas window", suggesting that most milling. H2 may be derived reduction water fluid inclusion phyllosilicates, involving formation reactive mineral surfaces radicals. Notably, concentrations gaseous hydrocarbons relatively high comparable "wet" At same time, data indicate substantial amounts LWMOAs might with Hence, must caution assessing (bio-)geochemical natural environments.

Language: Английский

Citations

0