Recent Advances in Theoretical Studies on Cu-Mediated Bond Formation Mechanisms Involving Radicals DOI
Ji‐Ren Liu,

Guo-Xiong Xu,

Li‐Gao Liu

et al.

ACS Catalysis, Journal Year: 2024, Volume and Issue: 14(4), P. 2429 - 2454

Published: Feb. 1, 2024

Copper-catalyzed radical transformations establish a powerful toolkit to construct versatile complex organic compounds. The copper-mediated bond formation step of radicals plays critical role in controlling chemo- and stereoselectivity copper-catalyzed transformation reactions. This involves three possible pathways: ion-type formation, substitution, reductive elimination. review highlights the recent advances theoretical studies on mechanisms models selectivity Cu-mediated radical-involved providing general mechanistic comprehension this key elementary copper catalysis.

Language: Английский

Recent Advances in Theoretical Studies on Cu-Mediated Bond Formation Mechanisms Involving Radicals DOI
Ji‐Ren Liu,

Guo-Xiong Xu,

Li‐Gao Liu

et al.

ACS Catalysis, Journal Year: 2024, Volume and Issue: 14(4), P. 2429 - 2454

Published: Feb. 1, 2024

Copper-catalyzed radical transformations establish a powerful toolkit to construct versatile complex organic compounds. The copper-mediated bond formation step of radicals plays critical role in controlling chemo- and stereoselectivity copper-catalyzed transformation reactions. This involves three possible pathways: ion-type formation, substitution, reductive elimination. review highlights the recent advances theoretical studies on mechanisms models selectivity Cu-mediated radical-involved providing general mechanistic comprehension this key elementary copper catalysis.

Language: Английский

Citations

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