Ptii(C^N)(N-Donor Ligand)Cl-Type Complexes with the Four-Coordinate Organoboron Unit and Their Optoelectronic Properties DOI
Jie Zhang, Siqi Liu, Hongyan Wang

et al.

Published: Jan. 1, 2023

Abstract: In this research, we have developed a series of PtII(C^N)(N-donor ligand)Cl-type phosphorescent complexes with the four-coordinate organoboron unit in C^N ligand. Through shifting coordinating position Pt(II) center from phenyl ring to pyridyl 2-phenylpyridine-type (ppy-type) unit, variation > 50 nm charge-transfer (CT) absorption band and 40 wavelength can be observed synthesized complexes, indicating effective tuning their photophysical properties incurred by unit. Accordingly, obvious electron density on these as well based cyclic voltammetry results. Critically, ppy-type exhibit aggregation enhanced emission (AEPE) behavior. It seems that hydrogen bonding among N-donor ligands water molecules affect AEPE response greatly, representing new way tune behavior PtII(C^N)(N- donor complexes. solution-processed organic light-emitting diodes (OLEDs), peak electroluminescent (EL) efficiencies 15.3%, 10.3 cd A-1 9.8 lm W-1 been achieved EL at ca. 648 nm. These impressive results provided key information for optoelectronic

Language: Английский

Catalytic asymmetric C–N cross-coupling towards boron-stereogenic 3-amino-BODIPYs DOI Creative Commons
Baoquan Zhan, Li‐Qing Ren,

Jiayi Zhao

et al.

Nature Communications, Journal Year: 2025, Volume and Issue: 16(1)

Published: Jan. 7, 2025

3-Amino boron dipyrromethenes (BODIPYs) are a versatile class of fluorophores widely utilized in live cell imaging, photodynamic therapy, and fluorescent materials science. Despite the growing demand for optically active BODIPYs, synthesis chiral 3-amino-BODIPYs, particularly catalytic asymmetric version, remains challenge. Herein, we report boron-stereogenic 3-amino-BODIPYs via palladium-catalyzed desymmetric C–N cross-coupling prochiral 3,5-dihalogen-BODIPYs. This approach features broad substrate scope, excellent functional group tolerance, high efficiency, remarkable enantioselectivities, under mild reaction conditions. Further stereospecific formation 3,5-diamino-BODIPYs, along with an investigation into photophysical properties resulting optical BODIPYs also explored. protocol not only enriches chemical space chiroptical BODIPY dyes but contributes to realm chemistry. (BODIPYs), which useful science, authors first cross-couplings.

Language: Английский

Citations

3
Boron‐Based Enantiomerism DOI Creative Commons
Manfred Braun

European Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 27(14)

Published: March 7, 2024

Abstract Boron‐based enantiomerism is fragile due to the inherent tendency of a dissociation ligand from tetra‐coordinate chiral boron complexes under formation achiral tri‐coordinate species. This review will present different approaches in overcoming racemization boron‐stereogenic compounds. When embedded an environment ligands or substituents, configurationally stable stereogenic centers can form diastereoselective manner. Compounds incorporating as exclusive center are obtained by resolution racemic mixtures. The recently developed – much more efficient methods catalytic, enantioselective creation compounds highlighted this review. Finally chiroptical properties enantiomerically pure that makes them promising materials devices addressed.

Language: Английский

Citations

10
Modular enantioselective assembly of multi-substituted boron-stereogenic BODIPYs DOI
Li‐Qing Ren, Baoquan Zhan,

Jiayi Zhao

et al.

Nature Chemistry, Journal Year: 2024, Volume and Issue: 17(1), P. 83 - 91

Published: Sept. 20, 2024

Language: Английский

Citations

9
Synthesis, properties and emerging applications of multi-boron coordinated chromophores DOI

Chaochao Jin,

Xuan Yang, Wenjing Zhao

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 513, P. 215892 - 215892

Published: May 6, 2024

Language: Английский

Citations

8
Interfacially Confined Dynamic Reaction Resulted to Fluorescent Nanofilms Depicting High-Performance Ammonia Sensing DOI
Jingjing Liang,

Dingfang Hu,

Wenjun Xu

et al.

Analytical Chemistry, Journal Year: 2024, Volume and Issue: 96(5), P. 2152 - 2157

Published: Jan. 27, 2024

Sensing materials innovation plays a crucial role in the development of high-performance film-based fluorescent sensors (FFSs). In our current study, we present innovative fabrication four nanofilms via interfacially confined dynamic reaction specially designed building block, new boron-coordinated compound (NI-CHO), with chosen one, benzene-1,3,5-tricarbohydrazide (BTH). The as prepared are robust, uniform, flexible, and thickness tunable, at least from 40 to 1500 nm. fabricated FFSs based on Film 3, one nanofilms, shows highly selective fully reversible response NH

Language: Английский

Citations

7
Boron‐Stereogenic Compounds: Synthetic Developments and Opportunities DOI

Yonghong Guo,

Bing Zu,

C. Chen

et al.

Chinese Journal of Chemistry, Journal Year: 2024, Volume and Issue: 42(19), P. 2401 - 2411

Published: May 27, 2024

Comprehensive Summary The 21 st century has witnessed a continuous evolution in the development of boron‐stereogenic chemistry. Since 1990s, various innovations for synthesis tetracoordinate compounds, which exhibited great potential applications, have been demonstrated by synthetic chemists. This paper reviews significant progress and recent advances towards assembly enantioenriched hopes to shed light on new perspectives inspire further research this emerging field.

Language: Английский

Citations

7
Steroids Bearing Heteroatom as Potential Drugs for Medicine DOI Creative Commons
Valery M. Dembitsky

Biomedicines, Journal Year: 2023, Volume and Issue: 11(10), P. 2698 - 2698

Published: Oct. 3, 2023

Heteroatom steroids, a diverse class of organic compounds, have attracted significant attention in the field medicinal chemistry and drug discovery. The biological profiles heteroatom steroids are considerable interest to chemists, biologists, pharmacologists, pharmaceutical industry. These compounds shown promise as potential therapeutic agents treatment various diseases, such cancer, infectious cardiovascular disorders, neurodegenerative conditions. Moreover, incorporation heteroatoms has led development targeted delivery systems, prodrugs, other innovative approaches. represent fascinating area research, bridging fields chemistry, pharmacology. exploration their chemical diversity activities holds for discovery novel candidates more effective treatments.

Language: Английский

Citations

11
Catalytic insertion of nitrenes into B-H bonds DOI Creative Commons
Nikita M. Ankudinov, Nikita V. Alexeev, Evgeniya Podyacheva

et al.

Chemical Science, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Catalytic insertion of nitrenes into B–H bonds produces unique compounds with chiral boron atoms.

Language: Английский

Citations

0
Organocatalyzed Enantioselective C–N Bond-Forming SNAr Reactions for Synthesizing Stereogenic-at-Boron BODIPYs DOI Creative Commons
Yonggang Meng, Fang Wei, Z. Y. Pei

et al.

JACS Au, Journal Year: 2025, Volume and Issue: 5(4), P. 1965 - 1973

Published: April 2, 2025

The precise construction of boron stereogenic centers represents a significant, yet challenging frontier in asymmetric catalysis, garnering growing attention recent years. However, feasible catalysis has primarily been limited to transition-metal-catalyzed desymmetrization pro-chiral BODIPY molecules, while enantioselective synthesis via organocatalysis remains unexplored. Herein, we achieve an organocatalyzed C-N bond-forming SNAr reaction 3,5-dihalogen BODIPYs phase-transfer enabling the efficient broad range boron-stereogenic with excellent enantioselectivities (>40 examples, up 99% ee). significance and potential this catalytic approach are further underscored by versatile applications enantioenriched 3-amide synthesis, optical activity regulation, bioimaging, sensing, promoting development fluorophores.

Language: Английский

Citations

0
Structure-Property/Activity Correlations of Coordination Compounds, Supramolecular Molecular Assemblies and Materials, with Possible Industrial and Biological Applications DOI Open Access
H.I. Beltrán, Luis A. Alfonso‐Herrera,

María Fernanda Serrato-Trejo

et al.

Journal of the Mexican Chemical Society, Journal Year: 2025, Volume and Issue: 69(1), P. 123 - 151

Published: Jan. 1, 2025

This work gives an overview of the scientific contributions developed in research group prof. Dr. Hiram Isaac Beltrán during last 22 years his career, mainly at Universidad Autónoma Metropolitana, first Unidad Cuajimalpa and later Azcapotzalco. During this period, was carried out on development of, (i) organic ligands to obtain boron-coordination compounds, (ii) diorganotin(IV) coordination compounds directly obtained by template effect, (iii) applications lines derived from boron tin, (iv) polymers metal-organic frameworks (MOFs), (v) infiltrated MOFs, (vi) band gap modulation luminescence properties (vii) biological (viii) macrocyclic systems their applications, (ix) supramolecular assemblies applications. Conducting more than 90 papers about 20 patents period. All involved design a specific molecular or material system with precise physicochemical achieve goal, fulfill function even be (multi)functional for biologic, industrial purposes. To follow all these directions, some concepts will highlighted compendium presented. Acquiring knowledge experience has allowed us develop functions also helped other groups understand own under investigation furthered field applied chemistry multifunctional level. Resumen. Este trabajo ofrece una visión general de las contribuciones científicas desarrolladas en el grupo investigación del durante los últimos años su carrera, principalmente la primero y luego Durante este periodo, se ha investigado desarrollo ligandos orgánicos para obtención compuestos coordinación con boro, diorganoestaño(IV) obtenidos directamente por efecto templado, aplicaciones líneas derivadas boro estaño desarrollados, polímeros redes metal-orgánicas (MOF), infiltración modulación banda prohibida propiedades luminiscencia (vii ) biológicas sistemas macrocíclicos sus aplicaciones, ensambles supramoleculares aplicaciones.. Realizando más artículos alrededor patentes periodo. Toda esta involucra diseño un sistema o particular fisicoquímicas precisas lograr objetivo, eventualmente cumplir función incluso ser (multi)funcional fines biológicos, científicos industriales. Para seguir todas estas investigación, destacaron algunos conceptos posteriormente presentó compendio. La adquisición conocimiento experiencia permitido diseñar desarrollar moleculares materiales funciones específicas. Esto también ayudado otros grupos comprender propios estudio impulsado campo química aplicada nivel multifuncional.

Citations

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