Advances in Chiral Pincer Complexes: Insights and Applications in Catalytic Asymmetric Reactions DOI Open Access
Sanaa Musa,

Yuval Peretz,

Gil Dinnar

et al.

International Journal of Molecular Sciences, Journal Year: 2024, Volume and Issue: 25(19), P. 10344 - 10344

Published: Sept. 26, 2024

Chiral pincer complexes, characterized by their rigid tridentate coordination framework, have emerged as powerful catalysts in asymmetric synthesis. This review provides a comprehensive overview of recent advancements the development chiral pincer-type ligands and corresponding transition metal complexes. We highlight latest progress application across range catalytic reactions, including (transfer) hydrogenation polar non-polar bonds, hydrophosphination, alkynylation, Friedel-Crafts enantioselective reductive cyclization alkynyl-tethered cyclohexadienones, hydrosilylation, well Aza–Morita–Baylis–Hillman reactions. The structural rigidity tunability complexes enable precise control over stereoselectivity, resulting high enantioselectivity efficiency complex molecular transformations. As field advances, innovations ligand design exploration new centers are expected to expand scope utility these catalysts, bearing significant implications for synthesis enantioenriched compounds pharmaceuticals, materials science, beyond.

Language: Английский

Enantioselective biosynthesis of vicinal diamines enabled by synergistic photo/biocatalysis consisting of an ene-reductase and a green-light-excited organic dye DOI

Fengming Shi,

Bin Chen, Jinhai Yu

et al.

CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION), Journal Year: 2025, Volume and Issue: 68, P. 223 - 229

Published: Jan. 1, 2025

Language: Английский

Citations

2
Recent progress in the organoselenium-catalyzed difunctionalization of alkenes DOI
Pei Qu, Gong‐Qing Liu

Organic & Biomolecular Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Selenium-based catalysts have recently been utilized to facilitate a variety of new organic transformations, owing their intrinsic advantages, including low cost, toxicity, stability in both air and water, strong compatibility with diverse functional groups. The difunctionalization alkenes-the process incorporating two groups onto carbon-carbon double bond-has garnered particular interest within the chemical community its significant applications synthesis. Recently, organoselenium-catalyzed alkenes has emerged as an ideal powerful route obtain high-value vicinal difunctionalized molecules. This review emphasizes recent advancements this rapidly evolving field, focusing on scope, limitations, mechanisms various reactions.

Language: Английский

Citations

1
Recent Advances in the Utilization of Chiral Covalent Organic Frameworks for Asymmetric Photocatalysis DOI Creative Commons
Peng Liu, Weijun Dai, Xianfu Shen

et al.

Molecules, Journal Year: 2024, Volume and Issue: 29(21), P. 5006 - 5006

Published: Oct. 23, 2024

The use of light energy to drive asymmetric organic transformations produce high-value-added compounds is attracting increasing interest as a sustainable strategy for solving environmental problems and addressing the crisis. Chiral covalent frameworks (COFs), porous crystalline chiral materials, have become an important platform on which explore new photocatalytic materials due their precise tunability, structure, function. This review highlights recent research progress COFs composites, evaluating application catalysts in terms structure. Finally, limitations challenges photocatalysis are discussed, with future opportunities being identified.

Language: Английский

Citations

2
Advances in Chiral Pincer Complexes: Insights and Applications in Catalytic Asymmetric Reactions DOI Open Access
Sanaa Musa,

Yuval Peretz,

Gil Dinnar

et al.

International Journal of Molecular Sciences, Journal Year: 2024, Volume and Issue: 25(19), P. 10344 - 10344

Published: Sept. 26, 2024

Chiral pincer complexes, characterized by their rigid tridentate coordination framework, have emerged as powerful catalysts in asymmetric synthesis. This review provides a comprehensive overview of recent advancements the development chiral pincer-type ligands and corresponding transition metal complexes. We highlight latest progress application across range catalytic reactions, including (transfer) hydrogenation polar non-polar bonds, hydrophosphination, alkynylation, Friedel-Crafts enantioselective reductive cyclization alkynyl-tethered cyclohexadienones, hydrosilylation, well Aza–Morita–Baylis–Hillman reactions. The structural rigidity tunability complexes enable precise control over stereoselectivity, resulting high enantioselectivity efficiency complex molecular transformations. As field advances, innovations ligand design exploration new centers are expected to expand scope utility these catalysts, bearing significant implications for synthesis enantioenriched compounds pharmaceuticals, materials science, beyond.

Language: Английский

Citations

1