Nature Communications,
Journal Year:
2025,
Volume and Issue:
16(1)
Published: March 12, 2025
Fully
triggering
the
deep-seated
potential
of
traditional
nanomaterials,
such
as
classic
spinel
family,
is
paramount
importance
in
field
materials
science,
which
yet
believed
to
heavily
depend
on
advanced
conceptual
designs
and
synthetic
strategies.
Herein,
a
type
inorganic–organic
hybrid
oxide
designed
using
π-conjugated
azobenzene
single-tooth
coordination
method
overcome
their
stubborn
problems
moderate
activity
phase
instability
electrocatalytic
reactions.
Taking
Co3O4
nanocubes
pre-catalyst,
after
subtle
etching
cube
surfaces,
some
oxygen
atoms
tetrahedral
Co–O
are
replaced
selectively
linked
weakly
polar
azo-extended
units
(π*–N=N–π*)
via
electrophilic
carboxyl
groups.
The
π-conjugation
structure
suppresses
covalency
competition
between
octahedral
fields,
successfully
preventing
transition
during
process
improving
durability.
This
study
not
only
expands
family
but
also
provides
useful
guidelines
for
developing
functional
materials.
Unlocking
nanomaterials
like
oxides
crucial
catalytic
evolution
reaction.
Here,
authors
report
an
that
enhances
both
structural
stability
through
method.
Advanced Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 21, 2025
Abstract
New
types
of
metal–organic
framework
(MOF)
materials
have
great
potential
in
solving
the
current
global
dilemma
on
energy,
environment,
and
medical
care.
Herein,
based
two
kinds
biomolecule‐MOFs
(Bio‐MOFs)
with
favorable
biocompatibility
degradation‐reconstruction
characteristics,
we
established
a
self‐powered
muti‐functional
device
to
achieve
an
efficient
broad‐spectrum
environmental
energy
collection
biomedical
applications.
Combining
Zn(II)
carnosine‐based
Zn‐Car_MOF
possessing
high
piezoelectric
response
(
d
33
=
11.17
pm
V
−1
)
patterned
polydimethylsiloxane
(PDMS)
film,
tribo‐piezoelectric
hybrid
nanogenerator
(TPHG)
is
constructed
synergy
output
triboelectric
effects.
The
Zn‐Car_TPHG
demonstrates
performance
(131
at
100
kPa)
wide
range
pressure
(1
Pa–100
kPa),
applications
sensors.
To
expand
application
wearable
device,
conductive
hexagonal
prism
MOF
(Cu
3
(2,3,6,7,10,11‐hexahydroxytriphenylene)
2
(Cu‐HHTP))
synthesized
employed
load
thymol
(Thy).
Cooperating
Zn‐Car_TPHG,
resulting
Cu‐HHTP/Thy
can
ROS
(singlet
oxygen
1
O
hydroxyl
radical
(·OH))
generation
drug
synergistic
sterilization
effect
(efficiency
≥
98%).
In
word,
flexible
Bio‐MOFs
sustainable
environmentally
friendly,
fields
collection,
biosensors,
antibacterial.
Chemical Reviews,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 18, 2025
The
electrocatalytic
technique,
as
an
efficient
energy
storage
and
conversion
technology,
has
attracted
significant
attention
to
address
exhaustion
environmental
pollution.
Usually,
the
activity
selectivity
of
reactions
are
largely
dominated
by
dynamic
process
occurring
on
electrocatalysts.
Therefore,
high-performance
electrocatalysts,
which
can
dominate
pathway
barrier
reactions,
great
significance
for
advancement
technique.
Metal-organic
frameworks
(MOFs),
emerging
crystalline
porous
materials,
present
structural
component
advantages
including
well-defined
structure,
high
surface
area,
large
porosity,
diverse
components,
easy
tailorability,
demonstrating
fantastic
potential
precise
fabrication
In
this
Review,
strategies
in
electrocatalysts
based
MOF-related
materials
specifically
introduced
from
aspects
catalytic
site
design
microenvironment
modulation
around
sites.
Furthermore,
representative
progress
achieved
various
applications
employing
MOF-based
is
systematically
summarized,
with
special
emphasis
MOFs
performance
optimization.
Finally,
remaining
challenges
future
perspectives
further
highlighted.
Advanced Functional Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Oct. 7, 2024
Abstract
High‐performance
microwave
absorption
materials
(MAM)
are
often
accompanied
by
synergistic
effects
of
multiple
loss
mechanisms,
but
the
contribution
share
various
mechanisms
has
been
neglected
to
provide
a
template
and
reference
for
design
MAM.
Here,
highly
conductive
2D
structure
is
designed
through
functional
group‐induced
modulation
strategy,
composite
L‐Ni@C
can
reach
an
effective
bandwidth
6.45
GHz
at
15%
fill
rate,
with
maximum
efficiency
99.9999%.
Through
layer‐by‐layer
analysis
mechanism,
it
found
that
strong
originates
from
polarization
heterogeneous
interface.
The
movement
space
charge
between
two‐phase
interface
forms
interfacial
electric
field,
in
situ
doping
nitrogen
cleverly
achieved
introduction
amino
groups,
which
significantly
enhances
rate
transfer
greatly
facilitates
electron
migration
polarization.
motion
law
field
also
simulated
using
COMSOL
simulation
software
illustrate
mechanism
interfaces.
This
work
fills
gap
structural
presents
new
theories
into
Deleted Journal,
Journal Year:
2024,
Volume and Issue:
1(2), P. 181 - 206
Published: Aug. 4, 2024
Abstract
Metal–organic
frameworks
(MOFs)
have
emerged
as
promising
materials
in
the
realm
of
electrocatalysis
due
to
their
high
surface
area,
tunable
porosity,
and
versatile
chemical
functionality.
However,
practical
application
has
been
hampered
by
inherent
limitations
such
low
electrical
conductivity
a
limited
number
active
metal
sites.
Researchers
addressed
these
challenges
through
various
strategies,
including
enhancing
incorporating
conductive
nanoparticles,
modifying
structure
composition
MOFs
replacing
nodes
functionalizing
linkers,
preparing
catalysts
thermal
processes
decarburization
conversion
into
oxides,
phosphides
(MPs),
sulfides
(MSs).
This
review
provided
comprehensive
summary
strategies
that
were
employed
enhance
electroactivity
for
improved
electrocatalytic
performance
recent
years.
It
also
explored
future
directions
potential
innovations
design
synthesis
MOF‐based
electrocatalysts,
offering
valuable
insights
advancing
sustainable
energy
technologies.
Langmuir,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Aug. 13, 2024
Heavy
metal
ion
wastewater
is
a
pressing
and
inescapable
issue
that
closely
related
to
human
health
ecological
security
due
its
toxicity,
carcinogenicity,
the
unmanageable
property
of
this
type
wastewater.
Metal–Organic
Frameworks
(MOFs)
are
class
crystalline
nanoporous
materials
with
flexible
designability
controllability,
showing
great
potential
in
field
adsorption
purification
heavy
metals
In
Perspective,
we
first
discuss
harm
different
ions
briefly
expound
virtues
MOFs
for
pollutant
adsorption.
Then,
mainly
summarize
recent
advances
construction
metal-based
(Zr-based,
Zn-based,
Co-based,
Al-based,
etc.)
their
research
progress
Furthermore,
various
types
MOF
additives
can
often
be
effectively
applied
by
functional
modification
or
other
composition.
Additionally,
several
commonly
used
kinetics
isotherm
models
also
detailed
help
an
in-depth
understanding
mechanism.
Finally,
challenges
opportunities
additionally
discussed,
review
may
provide
new
insight
water
applications.
