Cited by Heterometal–organic frameworks as highly sensitive and highly selective luminescent probes to detect Cu2+, H2PO4− ions and CTC in aqueous solutions

Tuning Circularly Polarized Afterglow Color via Modulation of Energy and Chirality Transfer in Co‐Doped Films DOI

Lingzhong Wei, Song Guo, Beibei Zhang

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: July 21, 2024

Abstract Circularly polarized luminescence (CPL) materials offer exciting potential due to their unique light properties. However, controlling the color of afterglow emission, a key feature for many applications remains challenge. Here, co‐doping strategy is presented precise control multicolor CPL in films. This approach utilizes chiral naphthylphosphoric acid derivatives as energy and chirality transfer donors, commonly used fluorescent dye rhodamine B (RB) PVA are selected acceptor polymeric matrix, respectively. Remarkably, co‐doped films exhibit ultra‐long green circular polarization phosphorescence lasting several seconds with high efficiency (14.23%), lifetime (1025.5 ms), dissymmetry factor (8.44 × 10 −3 ). Crucially, by adjusting content, it can precisely tune phosphorescence‐to‐fluorescence ratio achieve afterglow. stems from combination Förster resonance transfer, color‐mixing effects. Furthermore, this significantly improves asymmetry an order magnitude (5.17 −2 It anticipated that straightforward regulating will provide invaluable insights future design highly efficient innovative materials.

Language: Английский

Citations

Pt Single-Atom-Functionalized 2D Al-TCPP MOF Nanosheets for Enhanced Photodynamic Antimicrobial Therapy DOI

Shiyang He, Dandan Chu,

Zhixin Pang

et al.

Acta Physico-Chimica Sinica, Journal Year: 2025, Volume and Issue: unknown, P. 100046 - 100046

Published: Jan. 1, 2025

Language: Английский

Citations

Hydrogen‐Bonded Organic Framework Nanoscintillators for X‐Ray‐Induced Photodynamic Therapy in Hepatocellular Carcinoma DOI

Lihui Gu,

Han Wu, Xu Li

et al.

Advanced Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 10, 2025

Abstract X‐ray induced photodynamic therapy (X‐PDT) leverages penetrating to generate singlet oxygen ( 1 O 2 ) for treating deep‐seated tumors. However, conventional X‐PDT typically relies on heavy metal inorganic scintillators and organic photosensitizers produce , which presents challenges related toxicity energy conversion efficiency. In this study, highly biocompatible phosphorescent nanoscintillators based hydrogen‐bonded frameworks (HOF) are designed engineered, termed BPT‐HOF@PEG, enhance in hepatocellular carcinoma (HCC) treatment. BPT‐HOF@PEG functions simultaneously as both scintillator photosensitizer, effectively absorbing transferring abundant . Both vitro vivo investigations demonstrate that internalized efficiently produces significant quantities of upon irradiation. Additionally, exposure directly inflicts DNA damage, the synergistic effects these mechanisms result pronounced cell death substantial tumor growth inhibition, with a inhibition rate up 90.4% assessments. RNA sequencing analyses reveal induces apoptosis Hepa1‐6 cells while inhibiting proliferation, culminating death. Therefore, work highlights considerable potential efficient HOF nanoscintillators‐based promising therapeutic approach HCC, providing effective alternative negligible patients unresectable

Language: Английский

Citations

Low thermal quenching of metal halide-based metal–organic framework phosphor for light-emitting diodes DOI

Xiao‐Gang Yang, Ying‐Jun Chen,

Pei-Pei Yin

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: 15(35), P. 14202 - 14208

Published: Jan. 1, 2024

A green MOF phosphor can maintain 84% of its initial emission intensity after being heated to 150 °C, exceeding several commercial inorganic phosphors.

Language: Английский

Citations

Synergic effect between La-MOF and MXene: Revolutionizing TPU with improved mechanical strength and fire safety DOI

Fuhao Yu,

Xiaoli Yu,

Pengfei Jia

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 156145 - 156145

Published: Sept. 1, 2024

Language: Английский

Citations

Chiral Co‐assembly Based on a Stimuli‐Responsive Polymer towards Amplified Full‐Color Circularly Polarized Luminescence DOI

Wenlong Zhao, Wei‐Chen Guo, Kai Tan

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 10, 2024

Abstract Stimuli‐responsive circularly polarized luminescence (CPL) materials have been attaching wide attention in the field of optical information storage and encryption, while still facing challenge realization high dissymmetry factors ( g lum ). This work presents a pair stimuli‐responsive chiral co‐assemblies P7R3 P7S3 by combining polymer PFIQ containing iso ‐quinoline units with inducers. The obtained can reversibly undergo significant modification CPL behavior under trifluoroacetic acid (TFA) fumigation annealing treatment, |g | values exhibiting reversible shift between 0.2 0.3. Moreover, before TFA fumigating effectively induce achiral emitters to generate intense full‐color signals through energy transfer (CPL‐ET), corresponding larger than 0.2. encryption decryption as well multi‐level logic gates application are achieved leveraging activity co‐assembly. provides new perspective for construction luminescent large activation emitters.

Language: Английский

Citations

Thermo‐Guest Programmable Structural Adaptability with Bistable Empty States and Photothermal Conversion in a Coordination Framework DOI

Zhouling Wu,

Xing Li, Zhikun Liu

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 19, 2025

Abstract Stimuli‐responsive programmable materials exhibit remarkable potential for smart applications due to their ability attain multi‐stable states through structural adaptability upon guest molecule removal or exchange. However, achieving designability remains challenging, particularly in maintaining the crystallinity single‐crystal‐to‐single‐crystal (SCSC) transformations and ensuring tunable activation. In this study, it is demonstrated that SCSC between an empty monoclinic framework triclinic can be manipulated stimuli combining various activations molecules. Reversible switching facilitated by MeOH adsorption heating‐induced transformations, whereas H 2 O alone cannot directly induce transformation. Instead, must first adsorb N,N ‐Dimethylformamide (DMF) molecules form a new DMF‐adsorbed subsequently undergoes mild activation yield framework. These interconvertible frameworks differ photothermal conversion performance selectively cause discoloration of CuSO 4 ·5H dehydration. Photothermal temperatures ultimately transformation framework, attaining up 640 K within 15 s under 808 nm laser irradiation (1.7 W cm −2 ). Potential energy calculations single‐crystal data reveal driven varying affinities pore environments different

Language: Английский

Citations

Chiral cocrystals with circularly polarized persistent phosphorescence and large second harmonic generation DOI

Yongbo Peng,

Guoxing Zhou,

Rongyan Zhang

et al.

Surfaces and Interfaces, Journal Year: 2025, Volume and Issue: unknown, P. 106114 - 106114

Published: Feb. 1, 2025

Language: Английский

Citations

Recent Advances in the Construction and Application of Anion‐Induced Cucurbit[n]uril‐Based Supramolecular Assemblies via Outer‐Surface Interactions DOI

Fei-Yang Tian,

Rui-xue Cheng,

Kai Chen

et al.

Small Methods, Journal Year: 2025, Volume and Issue: unknown

Published: March 3, 2025

Abstract Cucurbit[ n ]urils (abbreviated as Q[ ]s or CB[ ]s) are synthesized through the condensation of formaldehyde and glycoluril in a hydrochloric acid environment. These molecules exhibit three distinctive properties concerning their charge distribution: neutral internal cavity, positively charged outer surface, negatively portal carbonyl oxygen atoms. unique characteristics facilitate formation supramolecular frameworks with range anions metal polyanions. The primary focus this review is on creation anion‐induced ]‐based self‐assemblies exploring potential applications ion sequestration release, gas adsorption, well development fluorescence probes. Additionally, concise current research compounds provided, aiming to stimulate future advancements field innovative framework materials.

Language: Английский

Citations

Engineering Solvent‐Coordinated Heterometallic–Organic Frameworks for Wide‐Range Tuning of Ultralong Room Temperature Phosphorescence toward Time‐Resolved Anticounterfeiting DOI

Juanjuan Xue,

Zhenhong Qi, Dongpeng Yan

et al.

Angewandte Chemie International Edition, Journal Year: 2025, Volume and Issue: unknown

Published: March 12, 2025

Metal-organic frameworks (MOFs) have been proven promising ultralong room temperature phosphorescence (RTP) materials for anti-counterfeit due to their unique optical properties. However, it remains a major challenge achieve the desired phosphorescent properties limited regulatory methods and indistinct mechanism. Herein, coordination solvent second metal ion co-strategy is firstly proposed prepare seven robust heterometallic-organic (HMOFs) with two configurations: ZnMg/Ca-sol [sol = H2O, dimethylformamide (DMF), dimethylacetamide (DMA), formyldiethylamine (DEF)] ZnSr/Ba-H2O, exhibiting different RTP. The tunable lifetimes within 14.5-195.4 ms are achieved gradually by altering type of alkaline earth metals, solvent, hydrogen-bonding in HMOFs. Significantly, theoretical calculations reveal that promotion spin-orbit coupling heavy metals rigid constraint on skeleton result excellent balance between high quantum yield (ФP) long lifetime, especially ZnSr-H2O (6.8%, 195.4 ms). Depending wide-range tuning RTP great stability, HMOFs successfully applied spatial-time resolved anti-counterfeiting multi-level information encryption. This work may provide new approach designing target while resolving contradiction ФP lifetime.

Language: Английский

Citations