Organometallics, Journal Year: 2024, Volume and Issue: 43(20), P. 2557 - 2564
Published: Aug. 11, 2024
The generation and functionalization of carbon- or nitrogen-centered radicals are great interest for their potential synthetic utility. Here, we report the anaerobic electrocatalytic oxidation two primary benzylic amines, benzylamine 2-picolylamine, in presence a catalytic quantity an electron deficient ferrocene derivative as single-electron redox mediator. use appropriate mediator prevented fouling electrode surface significantly decreased at which reaction occurred. Simulation electrochemical results revealed E
Language: Английский