Emerging Trends in CdS‐Based Nanoheterostructures: From Type‐II and Z‐Scheme toward S‐Scheme Photocatalytic H2 Production DOI
Ikram Ullah, Pei Zhao, Na Qin

et al.

The Chemical Record, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 17, 2024

Abstract Cadmium sulfide (CdS) based heterojunctions, including type‐II, Z‐scheme, and S‐scheme systems emerged as promising materials for augmenting photocatalytic hydrogen (H 2 ) generation from water splitting. This review offers an exclusive highlight of their fundamental principles, synthesis routes, charge transfer mechanisms, performance properties in improving H production. We overview the crucial roles Type‐II heterojunctions enhancing separation, Z‐scheme promoting redox potentials to reduce electron‐hole (e − /h + pairs recombination, combining merits both type‐II frameworks obtain highly efficient The importance this is demonstrated by its thorough comparison these three configurations, presenting valuable insights into special contributions capability activity. Additionally, key challenges prospects practical applications CdS‐based are addressed, which provides a comprehensive route emerging research achieving sustainable energy goals.

Language: Английский

The paradox of thermal vs. non-thermal effects in plasmonic photocatalysis DOI Creative Commons
Rishi Verma, Gunjan Sharma, Vivek Polshettiwar

et al.

Nature Communications, Journal Year: 2024, Volume and Issue: 15(1)

Published: Sept. 12, 2024

The debate surrounding the roles of thermal and non-thermal pathways in plasmonic catalysis has captured attention researchers sparked vibrant discussions within scientific community. In this review, we embark on a thorough exploration intriguing discourse, starting from fundamental principles culminating detailed understanding divergent viewpoints. We probe into core by elucidating behavior excited charge carriers illuminated nanostructures, which serves as foundation for two opposing schools thought. present key arguments evidence put forth proponents both pathways, providing perspective their respective positions. Beyond theoretical divide, discussed evolving methodologies used to unravel these mechanisms. discuss use Arrhenius equations variations, shedding light ensuing debates about applicability. Our review emphasizes significance localized surface plasmon resonance (LSPR), investigating its role collective oscillations decay dynamics that influence catalytic processes. also talked nuances activation energy, exploring relationship with nonlinearity temperature intensity dependence reaction rates. Additionally, address intricacies catalyst measurements implications light-triggered dynamics. further discusses wavelength-dependent rates, kinetic isotope effects, competitive electron transfer reactions, offering an all-inclusive view field. This not only maps current landscape photocatalysis but facilitates future explorations innovations unlock full potential plasmon-mediated catalysis, where synergistic approaches could lead different vistas chemical transformations.

Language: Английский

Citations

14
Bimetallic Ni–Fe nanoparticles encapsulated with biomass-derived N-doped graphitic carbon core-shell nanostructures an efficient bifunctional electrocatalyst for enhanced overall seawater splitting and human urine electrolysis DOI
Rajathsing Kalusulingam, Krishnan Ravi,

Selvam Mathi

et al.

Materials Today Sustainability, Journal Year: 2024, Volume and Issue: 27, P. 100864 - 100864

Published: May 30, 2024

Language: Английский

Citations

5
Facile synthesis of mesoporous Co3O4 anchoring on the g-C3N4 nanosheets for high performance supercapacitor DOI
Mahalakshmi Subbiah,

Abinaya Radhakrishnan,

Manoja Tharmaraj

et al.

Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 1008, P. 176689 - 176689

Published: Sept. 26, 2024

Language: Английский

Citations

4
Advances in hybrid strategies for enhanced photocatalytic water splitting: Bridging conventional and emerging methods DOI
Sandeep Kumar Lakhera,

K. Priyanga Kangeyan,

Crescentia Yazhini S

et al.

Applied Physics Reviews, Journal Year: 2024, Volume and Issue: 11(4)

Published: Oct. 8, 2024

Significant efforts have been dedicated to hydrogen production through photocatalytic water splitting (PWS) over the past five decades. However, achieving commercially viable solar-to-hydrogen conversion efficiency in PWS systems remains elusive. These face intrinsic and extrinsic challenges, such as inadequate light absorption, insufficient charge separation, limited redox active sites, low surface area, scalability issues practical designs. To address these issues, conventional strategies including heterojunction engineering, plasmonics, hybridization, lattice defects, sensitization, upconversion processes extensively employed. More recently, innovative hybrid like photonic crystal-assisted polarization field-assisted emerged, which improve absorption separation by harnessing slow photon effect, multiple scattering, piezoelectric, pyroelectric, ferroelectric properties of materials. This review article aims provide a comprehensive examination summary new synergistic approaches, integrating plasmonic effects, processes, crystal photocatalysis. It also explores role temperature suppressing exciton recombination during photothermic highlights emerging effects magnetic fields, periodic illumination, many-body large-hole polaron, anapole excitations, hold significant potential advance technology facilitate renewable generation.

Language: Английский

Citations

4
Heterogeneous Nickel Molybdenum Oxide Nanorods Conjugated Graphitic Carbon Nitride: A Bifunctional Electrocatalyst for Overall Water Splitting DOI

Shubham Mishra,

Vartika Sharma, Vaibhav Kulshrestha

et al.

Langmuir, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 3, 2025

The pursuit of sustainable energy solutions has driven extensive research into efficient and cost-effective water-splitting techniques. This study introduces a straightforward method employing nickel molybdenum oxide NiMoO4 (NMO) nanorods integrated with graphitic carbon nitride (g-CN) sheets as promising catalysts for water splitting. coupling between NMO g-CN leverages the distinctive properties both materials to boost robustness well effectiveness in catalysis oxygen evolution reaction (OER) hydrogen (HER). We systematically optimized nanostructure by adjusting reduction annealing temperature during calcination improve HER OER activities. NMO@g-CN-600 nanostructured catalyst demonstrates exceptional electrochemical activity acidic media, an overpotential 148 mV at 10 mA cm–2 current density, which is approximately 2.72 times lower than that bare 2.97 pristine catalysts. Under alkaline conditions, exhibited superior 252 reach density cm–2, outperforming Additionally, demonstrated excellent long-term stability chronoamperometric testing over 50 h basic environments, showing low Tafel slopes 97 98 dec–1, respectively. Various analytical methods confirmed successful synthesis structural prepared outstanding electrocatalytic position it feasible choice platinum-group-based overall electrolysis.

Language: Английский

Citations

0
PLNPs /SCN heterojunction composite with green afterglow for photocatalytic hydrogen production DOI

Abuduaini Abulimiti,

Yan Peng,

Mengfan Niu

et al.

New Journal of Chemistry, Journal Year: 2024, Volume and Issue: 48(22), P. 10304 - 10313

Published: Jan. 1, 2024

A ZnGa 5 Si O 18 /sulfur-doped carbon nitride composite with a green afterglow exhibited excellent photocatalytic hydrogen evolution activity, which is higher than that of PLNPs and SCN.

Language: Английский

Citations

2
Emerging Trends in CdS‐Based Nanoheterostructures: From Type‐II and Z‐Scheme toward S‐Scheme Photocatalytic H2 Production DOI
Ikram Ullah, Pei Zhao, Na Qin

et al.

The Chemical Record, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 17, 2024

Abstract Cadmium sulfide (CdS) based heterojunctions, including type‐II, Z‐scheme, and S‐scheme systems emerged as promising materials for augmenting photocatalytic hydrogen (H 2 ) generation from water splitting. This review offers an exclusive highlight of their fundamental principles, synthesis routes, charge transfer mechanisms, performance properties in improving H production. We overview the crucial roles Type‐II heterojunctions enhancing separation, Z‐scheme promoting redox potentials to reduce electron‐hole (e − /h + pairs recombination, combining merits both type‐II frameworks obtain highly efficient The importance this is demonstrated by its thorough comparison these three configurations, presenting valuable insights into special contributions capability activity. Additionally, key challenges prospects practical applications CdS‐based are addressed, which provides a comprehensive route emerging research achieving sustainable energy goals.

Language: Английский

Citations

2