Published: Jan. 1, 2024
Language: Английский
Published: Jan. 1, 2024
Language: Английский
Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 142118 - 142118
Published: March 1, 2025
Language: Английский
Citations
0Crystal Growth & Design, Journal Year: 2024, Volume and Issue: 24(11), P. 4810 - 4818
Published: May 22, 2024
A combination of polyoxometalates and viologens to construct discoloration materials with charge transfer has become attractive presently. In this work, four kinds POM–viologen color-changing were successfully synthesized, namely, [Cu(1,4-Mbby)2(HPMoVI10MoV2O40)] (1), [H2(1,4-Mbby)2]·(SiMo12O40) (2, 1,4-Mbby·Cl = (1-(4-methyl-benzyl)-[4,4']bipyridinyl-1-ium)chloridate), [H2(Bypy)2]·(SiMo12O40) (3), [H(Bypy)]·(Bypy-2)1/2·(PMo12O40) (4, Bypy 1-benzyl-4,4′-bipyridyinium chloride, Bypy-2 1,1′-dibenzyl-4,4′-bipyridine chloride). compound 1, a [Cu(1,4-Mbby)2]4+ subunit caps on the Keggin anion build monosupporting cluster. Compounds 2–4 are discrete structures dissociative POMs viologens. All compounds 1–4 show good reversible photochromic properties under xenon lamp (300–400 nm) irradiation. Under stimulation current, also electrochromic within certain range applied voltage. The these due generation free viologen radicals transfer. Based their properties, they can be many fields, such as ultraviolet detectors, inkless printing, visual detection heavy metal ions. These practical applications positive significance for life production.
Language: Английский
Citations
2Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: unknown, P. 178155 - 178155
Published: Dec. 1, 2024
Language: Английский
Citations
1Published: Jan. 1, 2024
Language: Английский
Citations
0Russian Journal of Inorganic Chemistry, Journal Year: 2024, Volume and Issue: unknown
Published: Aug. 13, 2024
Language: Английский
Citations
0Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: unknown, P. 140962 - 140962
Published: Nov. 1, 2024
Language: Английский
Citations
0Published: Jan. 1, 2024
Language: Английский
Citations
0