Cited by Synthesis, structure, spectral and Hirshfeld surface analysis of bis((pyridin-1-ium-4-yl)methanaminium) hexahalostannate(IV) dihalide

Two dimensional coordination polymer of pb(II) complex with m-sulfanilic acid: synthesis, characterization, electrical conductivity, adsorption properties and Hirshfeld surface analysis DOI

Abdullaev Ahrorjon Khabibjonovich,

Yuldash Yu. Yakubov,

Adizov Bobirjon Zamirovich

et al.

Adsorption, Journal Year: 2025, Volume and Issue: 31(2)

Published: Jan. 25, 2025

Language: Английский

Citations

Thermally Activated Delayed Fluorescence of Organic–Inorganic Hybrid Menshutkin-Type Cu–Sb Halides DOI

Yitong Lin,

Yang‐Peng Lin, Hao-Wei Lin

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 19, 2025

Organic-inorganic hybrid metal halides have attracted much attention due to their excellent optoelectronic properties. The heterometallic structure is expected achieve more complex luminescence centers, thereby improving the tunability of fluorescent materials. This paper reports synthesis crystals [Cu(2,2'-bpy)(PPh3)2][CuCl2(PPh3)2Sb2OCl4] (1, 2,2'-bpy = 2,2'-bipyridine, PPh3 triphenylphosphine) and (Mim)2[Sb2OCl6] (2, Mim 1-methylimidazole). Crystal 1 a new Menshutkin-type compound with double-layer hamburger-type structure, which characterized by main group (lone pair)···π (arene) supramolecular interactions. shows bright yellow light emission at room temperature has thermally activated delayed fluorescence (TADF) characteristic than twice increase PL intensity from 170 320 K. crystal arises charge transfer cation unit, as confirmed comparison study 2. Density functional theory (DFT) calculations further clarify that enhanced performance narrower bandgap are additional Cu(I) unit. good thermal stability air stability, ensuring its anti-counterfeiting application. work provides strategy for construction Cu-Sb compound.

Language: Английский

Citations

High-Efficiency Luminescence of Mn2+-Doped Two-Dimensional Hybrid Metal Halides and X-Ray Detection DOI

Yue Fan,

Yingyun Wang,

Bai Yunlong

et al.

Nanomaterials, Journal Year: 2025, Volume and Issue: 15(10), P. 713 - 713

Published: May 9, 2025

Mn2+ doping in metal halide perovskites enables host-to-dopant energy transfer, creating new emission pathways for optoelectronic applications. However, achieving high-efficiency luminescence 2D systems remains challenging. We synthesized Mn2+-doped PEA2CdCl4 via the hydrothermal method, characterizing its properties through PL spectroscopy, quantum yield measurements, and DFT calculations. Flexible films were fabricated using PDMS PMMA matrices. The 15% crystal showed orange–red with 90.85% PLQY, attributed to efficient host-to-Mn2+ transfer 4T1→6A1 transition. Prototype LEDs exhibited stable emission, while demonstrated flexibility excellent X-ray imaging capability. This work demonstrates as an effective strategy enhance perovskites, potential applications flexible optoelectronics scintillators.

Language: Английский

Citations

Optical Property Regulation through Host–Guest Interaction in a Zero-Dimensional Zr Chloride DOI

Jiawei Lin,

Xuexia Lu,

Zhen Liu

et al.

Chemistry of Materials, Journal Year: 2024, Volume and Issue: 36(9), P. 4600 - 4606

Published: April 23, 2024

Halide perovskites, particularly zero-dimensional (0D) A2BX6-type structures, have garnered significant attention in diverse fields due to their exceptional photoelectric properties. This study focuses on the optical property regulation of 0D A2ZrCl6 through nonprotonated cation substitution (A = [(CH3)3SO]+ and [(CH3)4N]+) combined with different guest ions (i.e., Sb3+, Bi3+, Mn2+). The varied host–guest interaction is regarded as reason for luminescent behaviors. Sb3+ dopant has a weaker host [(CH3)3SO]2ZrCl6 than Mn2+ does. As result, Sb3+@[(CH3)3SO]2ZrCl6 shows an excitation-dependent photoluminescence ranging from blue orange, while Mn2+@[(CH3)3SO]2ZrCl6 exhibits only emission under excitation wavelengths. Besides effect interaction, organic can impact behavior well. [(CH3)4N]2ZrCl6 preferences ions. are favorable [(CH3)3SO]2ZrCl6, Bi3+ adopted [(CH3)4N]2ZrCl6. Due colors dopants, possesses behaviors engineering. Inside [(CH3)4N]2ZrCl6, weak showing PL centers excitations.

Language: Английский

Citations

Lattice distortion dependent photoluminescence in two-dimensional hybrid manganese halides by regulating penetration depth of organic amine DOI

Yingyun Wang,

Shuai Zhang, Haowen Hou

et al.

Journal of Luminescence, Journal Year: 2024, Volume and Issue: 273, P. 120674 - 120674

Published: May 10, 2024

Language: Английский

Citations

Synthesis, structure, spectral and Hirshfeld surface analysis of bis((pyridin-1-ium-4-yl)methanaminium) hexahalostannate(IV) dihalide DOI

P.K. Kodamboev,

I.I. Abdullaev,

Aziz B. Ibragimov

et al.

Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: unknown, P. 140546 - 140546

Published: Oct. 1, 2024

Language: Английский

Citations